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Technical Paper

Effect of Phenolic Type Antioxidant Additives on Microbial Stability of Biodiesel Fuel

The aim of this study was to investigate the effect of a variety of phenolic type antioxidant additives on the microbial stability of biodiesel and diesel/biodiesel blends. Six synthetic phenolic type antioxidant agents were added in FAME at concentrations up to 1000 ppm. Treated FAME was also blended with Ultra Low Sulfur Diesel (ULSD) fuel at a concentration of 7% v/v in order to examine the activity of the substances in the final blends. The oxidation stability in the presence of the phenolic compounds was determined by carrying out measurements under accelerated oxidation process in the Rancimat unit. The effectiveness of those antioxidant agents against microbial contamination in biodiesel fuel was studied under certain testing protocols for detecting microbiological activity in the fuel supply chain and for evaluating antimicrobials against fuel bio-deterioration.
Technical Paper

A Study on Microbial Contamination of Alcohol-Blended Unleaded Gasoline

The fuel supply chain faces challenges associated with microbial contamination symptoms. Microbial growth is an issue usually known to be associated with middle distillate fuels and biodiesel, however, incidents where microbial populations have been isolated from unleaded gasoline storage tanks have also been recently reported. Alcohols are employed as gasoline components and the use of these oxygenates is rising, especially ethanol, which can be a renewable alternative to gasoline, as well. Despite their alleged disinfectant properties, a number of field observations suggests that biodeterioration could be a potential issue in fuel systems handling ethanol-blended gasoline. For this reason, in this study, the effect of alcohols on microbial proliferation in unleaded gasoline fuel was assessed. Ethanol (EtOH), iso-propyl alcohol (IPA) and tert-butyl-alcohol (TBA) were evaluated as examples of alcohols utilized in gasoline as oxygenates.
Journal Article

Investigating “De Minimis” Level of Fatty Acid Methyl Esters (FAME) in Distillate Marine Gas Oil

According to the existing maritime regulation, the marine diesel equipment will be necessary to operate with low sulfur marine fuels. Low Sulfur Middle Gas Oils (MGOs) often have a viscosity that is lower than that of Heavy Fuel Oil (HFO). The problems in diesel engines are mainly related to high pressure fuel pumps that depend on the fuel oil for their lubrication. A solution to that problem probably will be the addition of Fatty Acid Methyl Esters (FAME) as an additive to the fuel. On the other hand, for the purposes of International Standard ISO 8217:2012 in the case of distillate fuels it is recommended that “de minimis” level of FAME is recommended. “De minimis” level is determined approximately as the 0.1% volume of the fuel. In this study, Distillate Marine Diesel Oil with good lubricity performance was used blended with FAME fuel, according to national and European Standard (ELOT EN 14214), was used as an additive.
Journal Article

Impact of Oxidation on Lubricating Properties of Biodiesel Blends

The lubricating efficiency is an important property of diesel fuel since several diesel engine parts, such as pumps and injectors, are lubricated by the fuel itself only. The evolution of oxidation products during oxidative deterioration may as well affect the lubricating properties of the biodiesel fuel blends and thus the proper functioning of a diesel engine. In this study Fatty Acid Methyl Esters were produced from various types of feedstock that significantly differentiate in their fatty acid profile. Each methyl ester was blended with an Ultra Low Sulphur Automotive Diesel (ULSD) at a concentration of 7% v/v which is currently the maximum acceptable FAME content according to the European Standard EN590. The B7 biodiesel blends were evaluated regarding fundamental physicochemical properties as well as their lubricating efficiency. Oxidation stability was examined on a Rancimat apparatus according to EN 15751 standard.
Journal Article

Microbiological Growth Study of Biodiesel Fuel

The diesel fuel supply chain faces new challenges associated with microbial contamination symptoms in biodiesel fuel. FAME's (Fatty Acid Methyl Esters) chemical composition along with its hygroscopic nature makes it more “biologically active” and as a result the final blends could be more prone to microbiological contamination. Survey of in-field incidents and facts in the Greek supply chain indicate that biodiesel is more prone to microbial growth. Furthermore, several experimental studies which demonstrate the susceptibility of biodiesel fuel for microbial growth have been conducted in the laboratory. The influence of FAME has been evaluated as well as the effect of microbial proliferation on the quality of the blend. Different types of biodiesel have been blended with Ultra Low Sulphur Diesel at various concentrations, and the resulting blends were mixed with bottom-water of known viable microbial colonies and stored.
Technical Paper

Production of Biobased Lubricant Basestocks with Improved Performance

The ability of a catalyst to enhance the performance of synthesized biobased lubricant basestock was investigated in this study. Pomace olive oil, cottonseed oil, used frying oil and methyl oleate were utilized as starting materials for the production of the biobased lubricants and a two stages transesterification methodology was followed. Initially the oils were converted to their corresponding fatty acid methyl esters via methanolysis. The resulting methylesters were subsequently transesterified with TMP producing the desired oleochemical ester. These syntheses were carried out in the presence of either sodium methoxide or Ca/TEA alkoxide as catalysts. Following the purification phase, the synthesized esters were evaluated as potential biolubricants regarding their physicochemical properties such as viscosity index, pour point and acid value.
Journal Article

Tribological Evaluation of Biobased Lubricant Basestocks from Cottonseed and Soybean Oils

The aim of this study was to synthesize environmentally adapted Trimethylolpropane (TMP) esters from cottonseed and soybean oils and to examine their quality parameters and tribological properties as potential lubricant basestocks. A two stage production process was followed. At first the above mentioned vegetable oils were transformed to the corresponding methyl esters via methanolysis in the presence of sodium methoxide. The desired TMP esters were finally synthesized by alkaline transesterification of the previously produced methylesters with TMP using sodium methoxide as catalyst. Following the purification phase the physicochemical characteristics of the synthesized TMP esters were examined. The tribological properties were evaluated by employing a Four-Ball apparatus. An additive-free mineral oil base oil was used as a reference lubricating fluid.