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Degradation of the deNOx performance has been found in in-use heavy-duty vehicles with a urea-SCR system in Japan. The causes of the degradation were studied, and two major reasons are suggested here: HC poisoning and deactivation of pre-oxidation catalysts. Hydrocarbons that accumulated on the catalysts inhibited the catalysis. Although they were easily removed by a simple heat treatment, the treatment could only partially recover the original catalytic performance for the deNOx reaction. The unrecovered catalytic activity was found to result from the decrease in conversion of NO to NO2 on the pre-oxidation catalyst. The pre-oxidation catalyst was thus studied in detail by various techniques to reveal the causes of the degradation: Exhaust emission tests for in-use vehicles, effect of heat treatment on the urea-SCR systems, structural changes and chemical changes in active components during the deactivation were systematically investigated.

The use of biofuel is essential for the reduction of greenhouse gas emission. This paper highlights the use of biodiesel as a means of reducing greenhouse gas emission from the diesel engine of heavy-duty vehicles. Biodiesel is fatty acid methyl ester (FAME) obtained through ester exchange reaction by adding methanol to oil, such as rapeseed oil, soybean oil, palm oil, etc. The CO₂ emission from combustion of biodiesel is defined to be equivalent to the CO₂ volume absorbed by its raw materials or plants in their course of growth. On the other hand, however, biodiesel is known to increase the NOx emission when compared with operating with conventional diesel fuel, then suppressing this increase is regarded as a critical issue. This study is intended to identify the fuel properties of biodiesel free from increase in the NOx emission.

The use of biomass fuels for vehicles has been a focus of attention all over the world in terms of prevention of global warming, effective utilization of resources and local revitalization. For the purpose of beneficial use of unused biomass resources, the movement of the use of bioethanol and biodiesel made from them has spread in Japan. In Japan, biodiesel is mainly made from waste cooking oil collected by local communities or governments, and in terms of local production for local consumption, it is used as neat fuel (100% biofuel) or mixed with diesel fuel in high concentration for the vehicles. On the other hand, extremely low emission level must be kept for not only gasoline vehicles but also diesel vehicles in the post new long-term regulation implemented from 2009 in Japan.

The application of biodiesel as an alternative fuel for petroleum diesel fuel is very effective for the reduction of CO₂ emission, because biodiesel is produced from renewable biomass resources. In Japan, neat biodiesel derived from waste cooking oil has often been applied to commercial vehicles. However, it is possible that the difference of fuel properties between conventional diesel fuel and biodiesel causes the problems on exhaust emission characteristics of diesel engine. Therefore, it is necessary to clarify the effect of biodiesel fuelling on exhaust emissions from commercial vehicles. Light-duty garbage trucks and heavy-duty diesel buses which were actually fueled with biodiesel in Kyoto, Japan, were used for test vehicles in this study. The exhaust emissions from these vehicles during JE05 mode tests were compared between biodiesel derived from waste cooking oil and conventional diesel fuel.

Lean NOx trap (LNT) and Urea-SCR system are effective aftertreatment systems as NOx reduction device in diesel engines. On the other hand, DPF has already been developed as PM reduction device and it has been used in various vehicles. LNT can absorb and reduce NOx emission in wide range exhaust temperatures, from 150°C to 400°C, and the size of LNT component can be compact in comparison with Urea-SCR system because LNT uses the diesel fuel as a reducing agent and it is needless to install the reducing agent tank in the vehicle. In this study, authors have shown that the NOx conversion rate of LNT is high in the case of extremely low NOx concentration from the engine. Also, the effects of LNT and DPF were examined using the Super Clean Diesel (SCD) Engine, which has low NOx level before aftertreatment and has been finished as Japanese national project.

Real-time analysis of benzene in automobile exhaust gas was performed using the Jet-REMPI (supersonic jet / resonance enhanced multi-photon ionization) method. Real-time benzene concentration of two diesel trucks and one gasoline vehicle driving in Japanese driving modes were observed under ppm level at 1 s intervals. As a result, it became obvious that there were many differences in their emission tendencies, because of their car types, driving conditions, and catalyst conditions. In two diesel vehicle, benzene emission tendencies were opposite. And, in a gasoline vehicle, emission pattern were different between hot and cold conditions due to the catalyst conditions.

The use of biodiesel fuels as an alternative fuel for petroleum diesel fuel is very effective for the reduction of CO2 emission, because biodiesel is produced from renewable biomass resources. Biodiesel is usually blended to conventional diesel fuel in various proportions. It is possible that this biodiesel blending causes the problems on emission characteristics of modern diesel engine, because it could be confirmed that the application of neat biodiesel to modern diesel engines whose control parameters were optimized for conventional diesel fuel deteriorated the emission performances. It is necessary to clarify the effect of biodiesel blending on exhaust emissions of modern diesel engine. Rapeseed oil methyl ester (RME) was selected as a biodiesel used in this study.

A variable valve timing (VVT) mechanism has been applied in a high-speed direct injection (HSDI) diesel engine. The effective compression ratio (εeff) was lowered by means of late intake valve closing (LIVC), while keeping the expansion ratio constant. Premixed charge compression ignition (PCCI) combustion, adopting the Miller-cycle, was experimentally realized and numerically analyzed. Significant improvements of NOx and soot emissions were achieved for a wide range of engine speeds and loads, frequently used in a transient mode test. The operating range of the Miller-PCCI combustion has been expanded up to an IMEP of 1.30 MPa.

The biomass fuel is expected to solve the global warming due to a carbon neutral. A rapeseed oil methyl ester (RME) as biomass fuel was selected, and also a low sulfur diesel fuel is tested as reference fuel in this study. The experiments were carried out to improve diesel emissions and engine performance using high boost and high rate EGR system and a common rail injection system in a single cylinder engine. The diesel emissions and engine performance have been measured under the experimental conditions such as charging boost pressure from atmospheric pressure to 401.3kPa maximum and changing EGR rate from 0% to 40% maximum. RME contain about 10 mass % oxygen in the fuel molecule. Furthermore, RME does not contain aromatic hydrocarbons in the fuel. Due to these chemical properties, RME can be used at 40% high EGR condition.

Supersonic jet / resonance enhanced multi-photon ionization (Jet-REMPI) technique was focused on the analyzing method for gas mixture like exhaust gas from automobiles. In this method, when the mass number and wavelength of excitation laser are determined adequately, the target compound can be monitored selectively. We developed a new analyzer utilizing REMPI method. Using this analyzer, real-time monitoring of exhaust gas from a motorcycle and diesel vehicles was conducted. As a result of real-time monitoring test of the vehicles, concentrations of aromatic compounds like benzene toluene etc. were quantified and real-time changes of their concentrations were observed.

Application of biodiesel fuel (BDF) to diesel engine is very effective to reduce CO2 emission, because bio-diesel is carbon neutral in principle. However, when biodiesel was applied to conventional diesel engines without modification for biodiesel, NOx emission was increased by the change in fuel characteristics. It is necessary to introduce some strategies into diesel engines fuelled with biodiesel for lower NOx emission than conventional diesel fuel case. The purpose of this study is to reveal that exhaust gas recirculation (EGR) is one of the solutions for the reduction of NOx emission and meeting the future emission regulations when using biodiesel. Neat Rapeseed oil methyl ester (RME) as a biodiesel (B100) was applied to diesel engines equipped with high pressure loop (HPL) EGR system and low pressure loop (LPL) EGR system. Cooled HPL EGR was increased during steady-state operations and JE05 transient mode tests.

Application of biodiesel fuel (BDF) to diesel engine is very effective to reduce CO2 emission, because biodiesel is carbon neutral in principle. However, biodiesels yield an increase in NOx emission from conventional diesel engine, compared with diesel fuel case. Therefore, some strategies are needed for meeting the future emission regulations when using biodiesel. In this study, rapeseed oil methyl ester (RME) was applied to diesel engine equipped with exhaust gas recirculation (EGR) system and NOx storage reduction (NSR) catalyst. NOx reduction rate of NSR catalyst was drastically decreased by using RME, even if injection quantity of RME for rich spike was enhanced. However, an increase in EGR rate could reduce NOx emission without the deterioration in smoke and PM emissions.

The Poly-Aromatic Hydrocarbon (PAH) formation process from benzene was studied using a laminar flow reactor and GC-MS. In addition to PAH, acetylene and ethylene were observed. Without oxygen at temperatures over 1070 K, the amount of PAH and C2 species increased as the benzene concentration decreased. Addition of oxygen caused a linear decrease in the benzene concentration, and almost all of the benzene was consumed under stoichiometric conditions at all temperatures. At 1053 K, the concentrations of PAH and C2 species were not affected by the addition of oxygen. On the other hand, when the temperature was greater than 1070 K, the amount of PAH formed increased as the equivalence ratio increased, until the equivalence ratio was about 4. Above this equivalence ratio, the amounts decreased. Amounts of phenanthrene and biphenyl were large compared to those of other PAHs, which indicated that the dominant PAH formation path is the formation of phenanthrene via biphenyl.

A prototype CNG engine for heavy-duty trucks has been developed. The engine had sufficient output in practical use, and the green-house gas emission rate was below that of the base diesel engine. Furthermore, the NOx emission rate was reduced to 0.16 g/kWh in the JE05 mode as results of having fully adjusted air fuel ratio control. The measured emission characteristics of particles from the prototype CNG engine demonstrated that oil consumption was related to the number of particles. Moreover, when oil consumption is at an appropriate level, the accumulation mode particles are significantly reduced, and the nuclei mode particles are fewer than those of diesel-fueled engines.

For reducing exhaust emissions of heavy-duty diesel engines, the authors made an experimental study of diesel combustion using a single cylinder engine. The engine performance and exhaust emissions have been measured using a wide range and high EGR rate under the conditions of high boost intake pressure. The engine test cell has been equipped the external supercharger that is able to raise the boost pressure to 500 kPa, and also equipped the EGR system to increase the EGR rate until 50% under the 500 kPa boost condition. In various test conditions of load and engine speeds the authors have obtained the results, that is, NOx has been reduced drastically without increasing Particulate Matter (PM).

The 1997 Kyoto protocol came into effect in February, 2005 to reduce greenhouse gases within the period 2008-2012 by at least 5 % with respect to 1990 levels. Application of biodiesel fuel (BDF) to diesel engine is very effective to reduce CO2 emission, because BDF is carbon neutral in principle. The purpose of this project is to produce a light-duty biodiesel truck which can be suitable for emission regulation in next generation. The effect of BDF on the performance and emissions of modern diesel engine which was equipped with the aftertreatment for PM and NOx emissions was investigated without modifications of engine components and parameters, as a first step for research and development of biodiesel engine. Rapeseed oil methyl ester (RME) was selected in behalf of BDF, and combustion characteristics, engine performance and exhaust emissions were made a comparison between RME and petroleum diesel fuel by steady operation and Japan transient mode (JE05) tests.

A variable valve timing (VVT) mechanism was applied to achieve premixed diesel combustion at higher load for low emissions and high thermal efficiency in a light duty diesel engine. By means of late intake valve closing (LIVC), compressed gas temperatures near the top dead center are lowered, thereby preventing too early ignition and increasing ignition delay to enhance fuel-air mixing. The variability of effective compression ratio has significant potential for ignition timing control of conventional diesel fuel mixtures. At the same time, the expansion ratio is kept constant to ensure thermal efficiency. Combining the control of LIVC, EGR, supercharging systems and high-pressure fuel injection equipment can simultaneously reduce NOx and smoke. The NOx and smoke suppression mechanism in the premixed diesel combustion was analyzed using the 3D-CFD code combined with detailed chemistry.

The purpose of this study is to improve low-temperature flow-properties of biodiesel fuels (BDF) by blending with ethanol and to analyze the combustion characteristics in a diesel engine fueled with BDF/ethanol blended fuel. Because ethanol has a lower solidifying temperature, higher oxygen content, lower cetane number, and higher volatility than BDF, ethanol blending would have a large effect on cold flow performance, mixture formation, ignition, combustion, and exhaust emissions. The engine experiments in the study were performed with a diesel engine and blends of BDF and ethanol at different blending ratios. The cold flow performance of the blended fuels was evaluated by determining the fuel cloud point. The experimental results show that the ethanol blending lowers the cloud point of the blended fuel and significantly reduces smoke emissions from the engine without deteriorating other emissions or thermal efficiency.

Homogeneous Charge Compression Ignition (HCCI) is effective for the simultaneous reduction of soot and NOx emissions in diesel engine. In general, high octane number fuels (gasoline components or gaseous fuels) are used for HCCI operation, because these fuels briefly form lean homogeneous mixture because of long ignition delay and high volatility. However, it is necessary to improve injection systems, when these high octane number fuels are used in diesel engine. In addition, the difficulty of controlling auto-ignition timing must be resolved. On the other hand, HCCI using diesel fuel (diesel HCCI) also needs ignition control, because diesel fuel which has a low octane number causes the early ignition before TDC. The purpose of this study is the ignition and combustion control of diesel HCCI. The effects of parameters (injection timing, injection pressure, internal/external EGR, boost pressure, and variable valve timing (VVT)) on the ignition timing of diesel HCCI were investigated.

Conditioning of diluted exhaust gas by Thermo-Conditioner prior to measurement has been proposed by the GRPE/PMP Research Council of the United Nation in order to achieve stability in nano-particle measurement. In this study the effect of thermo-conditioner on the thermo-physical behavior of nano-particle under different conditions have been clarified. Stability in measurement was also attempted depending on the characteristics of nano-particles. Quality of the raw exhaust gas, the dilution ratio and temperature, and the thermal conditioning temperature were considered as the main parameters. Exhaust gas from a medium duty DI diesel engine was used for analysis. Scanning Mobility Particle Sizer was used for measuring the concentration of nano-particles. It was concluded that the concentration of nuclei-mode particles within the size range of 15∼30 nm are significantly influenced by the thermal conditioning temperature.