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Engine oils contain additives that provide wear protection to prolong engine life. In a previous study using direct acting mechanical bucket valve train components, we found that aged oil provided better wear protection and friction reduction under certain circumstances. To understand this effect further, friction and wear performance of fresh and laboratory-aged oils with 0.1% phosphorus was studied with ball-on-flat and cylinder-on-flat rigs. Test durations were chosen according to the electrical contact resistance (ECR) values observed between the contacting surfaces. Anti-wear films were characterized primarily by UV and visible Raman spectroscopy, and results were corroborated by Auger electron and infrared spectroscopies. The greatest compositional differences occurred between films formed by fresh and aged oils. The degree of ECR response or the length of oil aging generally did not affect the type of component observed in the films.

Future vehicle emission regulations both in the US and Europe will require maintaining catalyst efficiency for longer mileage intervals. In order to achieve this requirement, chemical restrictions are being placed on elements in engine oil that can poison catalysts. Most of phosphorus and a significant amount of sulfur in current engine oils come from zinc dialkyldithiophosphates, ZDDPs, which are a class of cost-effective multifunctional additives providing wear, oxidation and corrosion protection. Reducing ZDDP concentrations raises oxidation and wear concerns. The overall purpose of this research is to look at the antioxidation and antiwear capability of low phosphorus engine oils containing 0.05 wt% phosphorus and the potential of engine oils formulated without phosphorus. In addition to fresh oils, used oils drained from fleet vehicles were also analyzed and evaluated.

The overall purpose of this research is to determine the antiwear capability of low phosphorus engine oils containing 0.05 wt% phosphorus. The antiwear performance of 0.05 wt% phosphorus engine oils was evaluated using a laboratory valvetrain bench test rig coupled with an on-line wear measurement technique and a high frequency reciprocating rig (HFRR). Low phosphorus engine oils were compared with GF-3 engine oils containing 0.1 wt% phosphorus. In addition to fresh oils, long drain used oils from fleet vehicles were also analyzed and investigated. This information is important to develop engine oil formulations to meet the latest government emission and fuel economy requirements. The results indicate that by appropriately selecting and balancing supplemental antiwear and/or antioxidation additives the wear loss due to the reduction of zinc dialkyldithiophosphate (ZDDP) may be compensated or even reduced.

Automotive gear oil development has expanded beyond the historical requirements of emphasizing wear protection to encompass modern needs for fuel economy and limited slip frictional properties. This paper describes the development process of a new generation, fuel efficient gear lubricant for use in light duty vehicles. A systematic formulation approach was used, encompassing fluid viscometrics and additive optimization. Performance testing in both laboratory and vehicle tests is described. Though standard GL-5 tests were used to confirm oxidation, wear and corrosion performance, emphasis is given to those methods used for optimizing fuel economy.

Meeting upcoming stringent emission standards will require that exhaust gas catalyst systems become active very quickly, function at very high efficiencies and maintain those capabilities at high mileages. This means that contamination of the catalysts by engine oil derived poisons must be minimized. Phosphorus compounds, derived from the zinc dialkyldithio-phosphate (ZDTP) additives that provide antiwear and antioxidant activity, are a principal contaminant that can increase catalyst light off times and reduce catalyst efficiency. Therefore, reducing the concentration of, or eliminating, phosphorus in engine oils is desirable. Doing so, however, requires that oils be reformulated to ensure that wear protection will not be compromised and that oxidation stability will be maintained. To address these concerns, laboratory tests for evaluating oil oxidation and wear performance have been developed and used to evaluate developmental low phosphorus oils.