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The contribution of fuel adsorption in engine oil and its subsequent desorption following combustion to the engine-out hydrocarbon (HC) emissions of a spark-ignited, air-cooled, V-twin utility engine was studied by comparing steady state and cycle-resolved HC emission measurements from operation with a standard full-blend gasoline, and with propane, which has a low solubility in oil. Experiments were performed at two speeds and three loads, and for different mean crankcase pressures. The crankcase pressure was found to impact the HC emissions, presumably through the ringpack mechanism, which was largely unaltered by the different fuels. The average and cycle-resolved HC emissions were found to be in good agreement, both qualitatively and quantitatively, for the two fuels. Further, the two fuels showed the same response to changes in the crankcase pressure. The solubility of propane in the oil is approximately an order of magnitude lower than for gasoline.

Valve deactivation followed by multiple compression-expansion strokes was employed to remove intake-generated turbulence from the bulk gas in an internal combustion engine. The result was a nearly quiescent flowfield that retains the same time-varying geometry and, to a first approximation, thermodynamic conditions as a standard engine. Mass loss, and more significantly heat loss were found to contribute to a reduction in the peak cylinder pressure in the cycle following two compression-expansion strokes. The reduction of the turbulence was verified both computationally and by performing premixed combustion studies. Mixing studies of both liquid spray jets and gaseous jets were performed. Laser-induced fluorescence images of high spatial resolution and signal-to-noise ratio were acquired, allowing the calculation of the two in-plane components of the scalar dissipation rate.

To experimentally investigate evaporating sprays under conditions experienced in high speed direct-injection (HSDI) diesel engines, the exciplex LIF technique with the TMPD / naphthalene dopant system was applied in a combustion-type constant-volume spray chamber. The chamber allows spark ignition of a slightly rich C2H2-air mixture, and subsequent fuel injection into the high temperature and pressure products. A detailed set of calibration experiments has been performed in order to quantify the TMPD fluorescence signal. It has been demonstrated that the TMPD fluorescence intensity is directly proportional to concentration, is independent of the chamber pressure, and was not sensitive to quenching by either water vapor or carbon dioxide. Therefore, the temperature dependence of the TMPD fluorescence was the only correction factor required for quantitative measurements. Using a dual heated-jet experiment, the temperature dependence of TMPD fluorescence up to 1000 K was measured.

The role of mixture stratification on combustion rate has been investigated in a constant volume combustion vessel in which mixtures of different equivalence ratios can be added in a spatially and temporally controlled fashion. The experiments were performed in a regime of low fluid motion to avoid the complicating effects of turbulence generated by the injection of different masses of fluid. Different mixture combinations were investigated while maintaining a constant overall equivalence ratio and initial pressure. The results indicate that the highest combustion rate for an overall lean mixture is obtained when all of the fuel is contained in a stoichiometric mixture in the vicinity of the ignition source. This is the result of the high burning velocity of these mixtures, and the complete oxidation which releases the full chemical energy.

Planar instantaneous fuel concentration measurements were made by laser-induced fluorescence of 3-pentanone in the spark gap just prior to ignition in a direct-injection spark-ignition engine operating at a light load, highly stratified condition. The distribution of the average equivalence ratio in a circle of 1.9 mm diameter centered on the spark plug showed that a large fraction of the cycles had an equivalence ratio below the lean limit, yet acceptable combustion was achieved in those cycles. Further, weak correlation was found between the local average equivalence ratio near the spark plug and the time required to achieved a 100 kPa pressure rise above the motoring pressure, as well as other parameters which characterize the early stages of combustion. The cause for this behavior is assessed to be mixture motion during the spark discharge which continually convects fresh mixture through the spark gap during breakdown.

Simultaneous fuel distribution images (by shadowgraph and laser-induced fluorescence) and cylinder pressure measurements are reported for a combusting stratified-charge engine with a square cup in the head at 800 RPM and light load for two spark locations with and without swirl. Air-assisted direct-injection occurred from 130°-150° after bottom dead center (ABDC) and ignition was at 148° ABDC. The engine is ported and injection and combustion take place every 6th cycle. The complicated interaction of the squish, fuel/air jet, square cup, spark plug geometry and weak tumble gives rise to a weak crossflow toward the intake side of the engine with no swirl, but toward the exhaust side in the presence of strong swirl, skewing the spray slightly to that side.

Results of experiments performed on a direct-injection two-stroke engine using an air-assisted injector are presented. Pressure measurements in both the engine cylinder and injector body coupled with backlit photographs of the spray provide a qualitative understanding of the spray dynamics from the oscillating poppet system. The temporal evolution of the spatial distribution of both liquid and vapor fuel were measured within the cylinder using the Exciplex technique with a new dopant which is suitable for tracing gasoline. However, a temperature dependence of the vapor phase fluorescence was found that limits the direct quantitative interpretation of the images. Investigation of a number of realizations of the vapor field at a time typical of ignition for a stratified-charge engine shows a high degree of cycle to cycle variability with some cycles exhibiting a high level of charge stratification.