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Pre-ignition in a boosted spark-ignition engine can be triggered by several mechanisms, including oil-fuel droplets, deposits, overheated engine components and gas-phase autoignition of the fuel-air mixture. A high pre-ignition resistance of the fuel used mitigates the risk of engine damage, since pre-ignition can evolve into super-knock. This paper presents the pre-ignition propensities of 11 RON 89-100+ gasoline fuel blends in a single-cylinder research engine. Albeit the addition of two high-octane components (methanol and reformate) to a toluene primary reference fuel improved the pre-ignition resistance, one high-RON fuel experienced runaway pre-ignition at relatively low boost pressure levels. A comparison of RON 96 blends showed that the fuel composition can affect pre-ignition resistance at constant RON.

The current transportation fuels have been one of the biggest contributors towards climate change and greenhouse gas emissions. The use of carbon-free fuels has constantly been endorsed through legislations in order to limit the global greenhouse gas emissions. In this regard, ammonia is seen as a potential alternative fuel, because of its carbon-free nature, higher octane number and as hydrogen carrier. Furthermore, many leading maritime companies are doing enormous research and planning projects to utilize ammonia as their future carbon-free fuel by 2050. Flash boiling phenomenon can significantly improve combustion by enhancing the spray breakup process and ammonia possessing low boiling point, has a considerable potential for flash boiling. However, present literature is missing abundant research data on superheated ammonia sprays.

Decarbonization of the automotive industry is one of the major challenges in the transportation sector, according to the recently proposed climate neutrality policies, e.g., the EU 'Fit for 55' package. Hydrogen as a carbon-free energy career is a promising alternative fuel to reduce greenhouse gas emissions. The main objective of the present study is to investigate non-reactive hydrogen jet impingement on a piston bowl profile at different injection angles and under the effect of various pressure ratios (PR), where PR is the relative ratio of injection pressure (IP) to chamber pressure (CP). This study helps to gain further insight into the mixture formation in a heavy-duty hydrogen engine, which is critical in predicting combustion efficiency. In the experimental campaign, a typical high-speed z-type Schlieren method is applied for visualizing the jet from the lateral windows of a constant volume chamber, and two custom codes are developed for post-processing the results.

Distillation properties of gasoline are regulated to ensure the safe and efficient operation of SI-engines. Blending various gasoline components affects the distillation values in a non-linear fashion, making the prediction of these properties challenging. Furthermore, the rise of renewable components necessitates the development of new property prediction methods. In this work, a variety of Machine Learning models were created to predict the distillation points of gasoline blends based on the blending recipe. As input data, real industrial data from a refinery was used together with data from blends created for R&D purposes. The predicted properties were the evaporated volume at the 70 and 100 °C distillation points (E70 and E100). Altogether four different machine learning models were trained, cross-validated and tested using seven different pre-processing methods. It was found that Support Vector Regression (SVR) was the most effective at predicting the distillation points.

Ammonia (NH3), as a carbon-free fuel, has a higher optimization potential to power internal combustion engines (ICEs) compared to hydrogen due to its relatively high energy density (7.1MJ/L), with an established transportation network and high flexibility. However, the NH3 is still far underdeveloped as fuel for ICE application because of its completely different chemical and physical properties compared with hydrocarbon fuels. Among all uncertainties, the dynamics of the NH3 spray at engine conditions is one of the most important factors that should be clarified for optimizing the fuel-air mixing. To characterize the evolution and evaporation process of NH3 spray, a high-speed Z-type schlieren imaging technique is employed to estimate the spray characteristics under different injection pressure and air densities in a constant volume chamber.

Optical soot pyrometry is a mature experimental technique that has been applied to a broad range of combustion systems for measuring soot temperature and concentration. Even though the method is widely used and well documented, the line of sight nature of the technique makes the interpretation of its results challenging. Notably, gradients in temperature and soot concentration along the line of sight or across the field of view can introduce significant levels of uncertainty in the results. This paper presents a numerical study where the signal from the experimental two-color pyrometry technique in a marine diesel engine reference experiment is reconstructed employing computational fluid dynamics (CFD) and a detailed Line-by-Line (LBL) spectral radiation model. The analysis is aimed at qualitatively supporting interpretability of experimental observations.

Gasoline blending is known to be complicated, because individual gasoline fractions with different octane numbers, Research Octane Number (RON) or Motor Octane Number (MON) do not always blend linearly. Instead, they may blend non-linearly, in a synergistic or antagonistic manner. Even though RON and MON are regulated properties, linear and non-linear octane blending is not a broadly understood topic. The target in the developing process of a modern SI engine is to have 100% combustion efficiency which would lead to the reduction of hydrocarbon and carbon monoxide emissions. Therefore, the properties of gasoline, especially RON and MON, need to be optimized to ensure proper ignition in the engine and prevent harmful autoignition reactions. There are hundreds of hydrocarbons in gasoline which have different octane numbers (ON). The explanations for these variations are the structural differences in hydrocarbon molecules that influence on their reactivity.

As CO2 emissions from traffic must be reduced and fossil-based traffic fuels need to phase out, bio-based traffic fuels alone cannot meet the future demand due to their restricted availability. Another way to support fossil phase-out is to include synthetic fuels that are produced from circular carbon sources with renewable energy. Several different fuel types have been proposed, while, methanol only requires little processing from raw materials and could be used directly or as a drop-in fuel for some of the current engine fleet. CO2 emissions arising from fuel production are significantly reduced for synthetic renewable methanol compared to the production of fossil gasoline. Methanol has numerous advantages over the currently used fossil fuels with high RON and flame speed in spark-ignition engines as well as high efficiency and low emissions in combustion ignition engines.

Over the past few years, the growing concerns about global warming and efforts to reduce engine-out emissions have made the dual-fuel (DF) engines more popular in marine and power industries. The use of natural gas as an alternative fuel in DF engines has both the environmental and economic advantages over the conventional diesel combustion. However, the misfire phenomenon at lean conditions limits the operating range of DF combustion and causes emissions of unburned hydrocarbon (UHC) and unburned methane (methane-slip) in the environment. The greenhouse effect of methane is considered 28 times greater than CO2 over a 100-year perspective, which raises concerns for the governments and marine engine manufacturers. In efforts to reduce the UHC and methane-slip from DF engines, this study discusses ethane enrichment of diesel-methane DF combustion in a full-metal single-cylinder research engine under lean condition (λGFB = ~2.0) while keeping the total-fuel energy rather constant.

The present-day transport sector needs sustainable energy solutions. Substitution of fossil-fuels with fuels produced from biomass is one of the most relevant solutions for the sector. Nevertheless, bringing biofuels into the market is associated with many challenges that policymakers, feedstock suppliers, fuel producers, and engine manufacturers need to overcome. The main objective of this research is an investigation of the impact of alternative fuel properties on light vehicle engine performance and greenhouse gases (GHG). The purpose of the present study is to provide decision-makers with tools that will accelerate the implementation of biofuels into the market. As a result, two models were developed, that represent the impact of fuel properties on engine performance in a uniform and reliable way but also with very high accuracy (coefficients of determination over 0.95) and from the end-user point of view.

Marine transportation sector is highly dependent on fossil-based energy carriers. Decarbonization of shipping can be accomplished by implementing biobunkers into an existing maritime fuel supply chain. However, there are many compatibility issues when blending new biocomponents with their fossil-based counterparts. Thus, it is of high importance to predict the effect of fuel properties on marine engine performance, especially for new fuel blends. In the given work, possible future solutions concentrated on liquid fuels are taken into account. Under consideration are such fuels as biodiesel (FAME), hydrotreated vegetable oil (HVO), straight vegetable oil (SVO), pyrolysis oil, biocrude, and methanol. Knowledge about the behavior of new fuel in an existing engine is notably important for decision makers and fuel producers. Hence, the main goal of the present work is to create a model, which can predict the engine performance from the end-user perspective.

State of the art high-pressure fuel injectors offer the ability to inject multiple times per cycle, and can reach very low fuel amounts per injection event. This behaviour allows the application of pilot injections in diesel engine applications or dual fuel engines. In both diesel and dual fuel engines, the amount of pilot fuel affects the engine efficiency. The understanding of the underlying ignition mechanism of the pilot fuel is required to optimize injection parameters and the engines’ fuel consumption. The present work focuses on the differences of ignition mechanisms between long and short injections. The investigation has been performed numerically, using CFD with a well-proven combustion model. The setup used employs a well characterized single orifice injector, injecting into a high temperature, pressurized environment with a composition of 15% oxygen.

In this study, a novel 3D-CFD combustion model employing Flamelet Generated Manifolds (FGM) for dual fuel combustion was developed. Validation of the platform was carried out using recent experimental results from an optically accessible Rapid Compression Expansion Machine (RCEM). Methane and n-dodecane were used as model fuels to remove any uncertainties in terms of fuel composition. The model used a tabulated chemistry approach employing a reaction mechanism of 130 species and 2399 reactions and was able to capture non-premixed auto ignition of the pilot fuel as well as premixed flame propagation of the background mixture. The CFD model was found to predict well all phases of the dual fuel combustion process: I) the pilot fuel ignition delay, II) the Heat Release Rate of the partially premixed conversion of the micro pilot spray with entrained methane/air and III) the sustained background mixture combustion following the consumption of the spray plume.

Dual-fuel natural gas engines are seen as an attractive solution for simultaneous reduction of pollutant and CO2 emissions while maintaining high engine thermal efficiency. However, engines of this type exhibit a tradeoff between misfire as well as high UHC emissions for small pilot injection amounts and higher emissions of soot and NOX for operation strategies with higher pilot fuel proportion. The aim of this study was to investigate POMDME as an alternative pilot fuel having the potential to mitigate the emissions tradeoff, enabling smokeless combustion due to high degree of oxygenation, and being less prone to misfire due to its higher cetane number. Furthermore, POMDME can be synthetized carbon neutrally. First, characteristics of POMDME ignition in methane/air mixture and the transition into premixed flame propagation were investigated optically in a rapid compression-expansion machine (RCEM) by employing Schlieren and OH* chemiluminescence imaging.

The sooting propensity of dual-fuel combustion with n-dodecane pilot injection in a lean-premixed methane-air charge has been investigated using an optically accessible Rapid Compression-Expansion Machine (RCEM) to achieve engine-relevant pressure and temperature conditions at the start of pilot injection. A Diesel injector with a 100 μm single-hole coaxial nozzle, mounted at the cylinder periphery, has been employed to admit the pilot fuel. The aim of this study was to enhance the fundamental understanding of soot formation and oxidation processes of n-dodecane in the presence of methane in the air charge by parametric variation of methane equivalence ratio, charge temperature, and pilot fuel injection duration. The influence of methane on ignition delay and flame extent of the pilot fuel jet has been determined by simultaneous excited-state hydroxyl radical (OH*) chemiluminescence and Schlieren imaging.

Dual fuel (DF) combustion technology as a feasible approach controlling engine-out emissions facilitates the concept of fuel flexibility in diesel engines. The abundance of natural gas (90-95% methane) and its relatively low-price and the clean-burning characteristic has attracted the interest of engine manufacturers. Moreover, with the low C/H ratio and very low soot producing tendency of methane combined with high engine efficiency makes it a viable primary fuel for diesel engines. However, the fundamental knowledge on in-cylinder combustion phenomena still remains limited and needs to be studied for further advances in the research on DF technology. The objective of this study is to investigate the ignition delay with the effect of, 1) methane equivalence ratio, 2) intake air temperature and 3) pilot ratio on the diesel-methane DF-combustion. Combustion phenomenon was visualized in a single cylinder heavy-duty diesel engine modified for DF operations with an optical access.

In the present work numerical simulations were carried out investigating the effect of fuel type, nozzle-geometry variations and back-pressure changes on high-pressure gas injections under application-relevant conditions. Methane, hydrogen and nitrogen with a total pressure of 500 bar served as high-pressure fuels and were injected into air at rest at 200 bar and 100 bar. Different nozzle shapes were simulated and the analysis of the results lead to a recommendation for the most advantageous geometry regarding jet penetration, volumetric growth, mixing enhancement and discharge coefficient. Additionally an artificial inlet boundary conditions was tested for the use with real-gas thermodynamics and was shown to be capable of reducing the simulation time significantly.

Formation of soot in an auto-igniting n-dodecane spray under diesel engine relevant conditions has been investigated numerically. As opposed to research addressing turbulence-chemistry interaction (TCI) by coupling diffusive turbulence models with more sophisticated models in the context of Reynolds-Averaged Navier-Stokes equations (RANS), this study employs the advanced sub-grid scale k-equation model in the framework of a Large Eddy Simulation (LES) together with the uninvolved Direct Integration (DI) approach. A reduced n-heptane chemical mechanism has been employed and artificially accelerated in order to predict the ignition for n-dodecane accurately. Soot processes have been modelled with an extended version of the semi-empirical, two-equation model of Leung, which considers C2H2 as the soot precursor and accounts for particle inception, surface growth by C2H2 addition, oxidation by O2, oxidation by OH and particle coagulation.

The interaction of turbulent premixed methane combustion with the surrounding flow field can be studied using optically accessible test rigs such as a rapid compression expansion machine (RCEM). The high flexibility offered by such a test rig allows its operation at various thermochemical conditions at ignition. However, limitations inherent to such test rigs due to the absence of an intake stroke do not allow turbulence production as found in IC-engines. Hence, means to introduce turbulence need to be implemented and the relevant turbulence quantities have to be identified in order to enable comparability with engine relevant conditions. A dedicated high-pressure direct injection of air at the beginning of the compression phase is considered as a measure to generate adjustable turbulence intensities at spark timing and during the early flame propagation.

Large-bore natural gas engines may use pre-chamber ignition. Despite extensive research in engine environments, the exact nature of the jet, as it exits the pre-chamber orifice, is not thoroughly understood and this leads to uncertainty in the design of such systems. In this work, a specially-designed rig comprising a quartz pre-chamber fit with an orifice and a turbulent flowing mixture outside the pre-chamber was used to study the pre-chamber flame, the jet, and the subsequent premixed flame initiation mechanism by OH* and CH* chemiluminescence. Ethylene and methane were used. The experimental results are supplemented by LES and 0D modelling, providing insights into the mass flow rate evolution at the orifice and into the nature of the fluid there. Both LES and experiment suggest that for large orifice diameters, the flow that exits the orifice is composed of a column of hot products surrounded by an annulus of unburnt pre-chamber fluid.