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Forthcoming worldwide emissions regulations will start regulating ammonia emissions from light duty vehicles. At present, most light duty vehicles are powered by gasoline spark ignition engines. Sources of ammonia emission from such engines can be in-cylinder reactions (i.e. combustion) or downstream reactions across aftertreatment devices, particularly three-way catalysts. The latter has been known to be a major source of ammonia emissions from gasoline vehicles and has been extensively investigated. The former (combustion), less so, and thus is the subject of this work. A two-zone thermodynamic spark ignition engine model with a comprehensive chemical kinetics framework (C3MechV3.3 mechanism), after being validated against experimental ammonia emissions data, is used to study ammonia formation during combustion.

Extending the planar Particle Image Velocimetry (PIV) technique to enable measurements on multiple planes simultaneously allows for some of the 3 dimensional nature of unsteady flow fields to be investigated. This requires less hardware and retains the typically higher spatial resolution of planar PIV compared to fully 3-dimensional PIV techniques. Performing multi-plane PIV measurements requires the light scattered from the different measurement planes to be distinguishable. This may be achieved by using different laser wavelengths which adds significantly to the expense and complexity of the system, by using different light sheet polarisations which is challenging for engine measurements through windows due to stress-induced birefringence, or by making alternating measurements of each plane which sacrifices the simultaneity of the flow measurement across multiple planes.

Low temperature heat release (LTHR) has been of interest to researchers for its potential to mitigate knock in spark ignition (SI) engines and control auto-ignition in advanced compression ignition (ACI) engines. Previous studies have identified and investigated LTHR in both ACI and SI engines before the main high temperature heat release (HTHR) event by appropriately curating the in-cylinder thermal state during compression, or in the case of SI engines, timing the spark discharge late to reveal LTHR (sometimes referred to as pre-spark heat release). In this work, LTHR is demonstrated in isolation from HTHR events. Tests were run on motored single-cylinder engines and inlet air temperatures and pressures were adjusted to realise LTHR from n-heptane and iso-octane (2,2,4-trimethylpentane) without entering the HTHR regime. LTHR was observed for a lean n-heptane-air mixture at inlet temperatures ranging from 60°C to 100°C and inlet pressures of 0.9 bar (absolute).

Particulate emissions from gasoline direct injection (GDI) engines continue to be a topic of substantial research interest. Forthcoming regulation both in the USA and the EU will further reduce their emission and drive innovation. Substantial research effort is spent undertaking experiments to understand, characterize, and research particle number (PN) emissions from engines and vehicles. Recent advances in computing power, data storage, and understanding of artificial intelligence algorithms now mean that these are becoming an important tool in engine research. In this work a random forest (RF) algorithm is used for the prediction of PN emissions from a highly boosted (up to 32 bar BMEP) GDI engine. Particle size, concentration, and the accumulation mode geometric standard deviation (GSD) are all predicted by the model. The results are analysed and an in depth study on parameter importance is carried out.

Low temperature combustion (LTC) of diesel fuel offers a path to low engine emissions of nitrogen oxides (NOx) and particulate matter (PM), especially at low loads. Borescopic optical imaging offers insight into key aspects of the combustion process without significantly disrupting the engine geometry. To assess LTC combustion, two-colour pyrometry can be used to quantify local temperatures and soot concentrations (KL factor). High sensitivity photo-multiplier tubes (PMTs) can resolve natural luminosity down to low temperatures with adequate signal-to-noise ratios. In this work the authors present the calibration and implementation of a borescope-based system for evaluating low luminosity LTC using spatially resolved visible flame imaging and high-sensitivity PMT data to quantify the luminous-area average temperature and soot concentration for temperatures from 1350-2600 K.

Accurate modelling for spray vapour fields is critical to enable adequate predictions of spray ignition and combustion characteristics of non-premixed reacting diesel sprays. Spray vapour characteristics are in turn controlled by liquid atomization and the KH-RT liquid jet break-up model is regularly used to predict this: with the KH model used for predicting primary break-up given its definition as a surface wave growth model, and the RT model used for predicting secondary break-up due to it being a drag based, stripping model. This paper investigates how the alteration of the switching position of the KH and RT sub-models within the KH-RT model impacts the resulting vapour field and ignition characteristics. The combustion prediction is handled by the implementation of a 54 species, 269 reaction skeletal mechanism utilising a Well Stirred Reactor model within the Star-CD CFD code.

In this study, the role of turbulence-chemistry interaction in diesel spray auto-ignition, flame stabilization and end of injection phenomena is investigated under engine relevant “Spray A” conditions. A recently developed diesel spray combustion modeling approach, Conditional Source-term Estimation (CSE-FGM), is coupled with Reynolds-averaged Navier-Stokes simulation (RANS) framework to study the details of spray combustion. The detailed chemistry mechanism is included through the Flamelet Generated Manifold (FGM) method. Both unsteady and steady flamelet solutions are included in the manifold to account for the auto-ignition process and the subsequent flame propagation in a diesel spray. Conditionally averaged chemical source terms are closed by the conditional scalars obtained in the CSE routine. Both non-reacting and reacting spray jets are computed over a wide range of Engine Combustion Network (ECN) diesel. “Spray A” conditions.

This study looked into the application of active thermal coatings on the surfaces of the combustion chamber as a method of improving the thermal efficiency of internal combustion engines. The active thermal coating was applied to a production aluminium piston and its performance was compared against a reference aluminium piston on a single-cylinder diesel engine. The two pistons were tested over a wide range of speed/load conditions and the effects of EGR and combustion phasing on engine performance and tailpipe emissions were also investigated. A detailed energy balance approach was employed to study the thermal behaviour of the active thermal coating. In general, improvements in indicated specific fuel consumption were not statistically significant for the coated piston over the whole test matrix. Mean exhaust temperature showed a marginal increase with the coated piston of up to 6 °C.

Combustion recession, an end of injection (EOI) diesel spray phenomenon, has been found to be a robust correlation parameter for UHC in diesel LTC strategies. Previous studies have shown that the likelihood of capturing combustion recession in numerical simulations is highly dependent on the details of the low-temperature chemistry reaction mechanisms employed. This study aims to further the understanding of the effects of different chemical mechanisms in the prediction of a reactive diesel spray and its EOI process: combustion recession. Studies were performed under the Engine Combustion Network’s (ECN) “Spray A” conditions using the Reynolds-Averaged Navier-Stokes simulation (RANS) and the Flamelet Generated Manifold (FGM) combustion model with four different chemical mechanisms for n-dodecane that are commonly used in the engine simulation communities - including recently developed reduced chemistry mechanisms.

In-cylinder flow motion has a significant effect on mixture preparation and combustion. Therefore, it is vital that CFD engine simulations are capable of accurately predicting the in-cylinder velocity fields. High-speed planar Particle Image Velocimetry (PIV) experiments have been performed on a single-cylinder GDI optical engine in order to validate CFD simulations for a range of engine conditions. Novel metrics have been developed to quantify the differences between experimental and simulated velocity fields in both alignment and magnitude. The Weighted Relevance Index (WRI) is a variation of the standard Relevance Index that accounts for the local velocity magnitudes to provide a robust comparison of the alignment between two vector fields. Similarly, the Weighted Magnitude Index (WMI) quantifies the differences in the local magnitudes of the two velocity fields.

In-cylinder temperatures and their cyclic variations strongly influence many aspects of internal combustion engine operation, from chemical reaction rates determining the production of NOx and particulate matter to the tendency for auto-ignition leading to knock in spark ignition engines. Spatially resolved measurements of temperature can provide insights into such processes and enable validation of Computational Fluid Dynamics simulations used to model engine performance and guide engine design. This work uses a combination of Two-Colour Planar Laser Induced Fluorescence (TC-PLIF) and Laser Induced Grating Spectroscopy (LIGS) to measure the in-cylinder temperature distributions of a firing optically accessible spark ignition engine. TC-PLIF performs 2-D temperature measurements using fluorescence emission in two different wavelength bands but requires calibration under conditions of known temperature, pressure and composition.

Accurate measurement of exhaust gas temperature in internal combustion engines is essential for a wide variety of monitoring and design purposes. Typically these measurements are made with thermocouples, which may vary in size from 0.05 mm (for fast response applications) to a few millimetres. In this work, the exhaust of a single cylinder diesel engine has been instrumented both with a fast-response probe (comprising of a 50.8 μm, 127 μm and a 254 μm thermocouple) and a standard 3 mm sheathed thermocouple in order to assess the performance of these sensors at two speed/load conditions. The experimental results show that the measured time-average exhaust temperature is dependent on the sensor size, with the smaller thermocouples indicating a lower average temperature for both speed/load conditions. Subject to operating conditions, measurement discrepancies of up to ~80 K have been observed between the different thermocouples used.

Particulate emissions from Gasoline Direct Injection (GDI) engines have been an important topic of recent research interest due to their known environmental effects. This review paper will characterise the influence of different gasoline direct injection fuel systems on particle number (PN) emissions. The findings will be reviewed for engine and vehicle measurements with appropriate driving cycles (especially real driving cycles) to evaluate effects of the fuel injection systems on PN emissions. Recent technological developments alongside the trends of the influence of system pressure and nozzle design on injector tip wetting and deposits will be considered. Besides the engine and fuel system it is known that fuel composition will have an important effect on GDI engine PN emissions. The evaporation qualities of fuels have a substantial influence on mixture preparation, as does the composition of the fuel itself.

Knowledge of fuel mass injected in an individual cycle is important for engine performance and modeling. At the moment, such measurements are not possible on engine or in real time. In this article, a new method using Coriolis flow meters (CFMs) and a new, patented, signal processing technique, known as the Prism, are introduced. CFMs are extensively used for flow measurement both in the automotive industry and further afield and, when coupled with the Prism, have the potential to make these challenging high-speed measurements. A rig-based feasibility study was conducted injecting very small quantities of diesel (3 mg) at pressures of up to 1000 bar at simulated engine speeds of up to 4000 rpm. The results show that these small quantities can in principle be measured. The results also reveal a previously unknown behavior of CFMs when measuring very low flow rates at high speed.

A new reflected shock tube facility, the Cold Driven Shock Tube (CDST), has been designed, built and commissioned at the University of Oxford for investigating IC engine fuel spray physics and chemistry. Fuel spray and chemical kinetics research requires its test gas to be at engine representative pressures and temperatures. A reflected shock tube generates these extreme conditions in the test gas for short durations (order milliseconds) by transiently compressing it through a reflected shock process. The CDST has been designed for a nominal test condition of 6 MPa, 900 K slug of air (300 mm long) for a steady test duration of 3 ms. The facility is capable of studying reacting mixtures at higher pressures (up to 150 bar) than other current facilities, whilst still having comparable size (100 mm diameter) and optical access to interrogate the fuel spray with high speed imaging and laser diagnostics.

Diesel engine designers often use swirl flaps to increase air motion in cylinder at low engine speeds, where lower piston velocities reduce natural in-cylinder swirl. Such in-cylinder motion reduces smoke and CO emissions by improved fuel-air mixing. However, swirl flaps, acting like a throttle on a gasoline engine, create an additional pressure drop in the inlet manifold and thereby increase pumping work and fuel consumption. In addition, by increasing the fuel-air mixing in cylinder the combustion duration is shortened and the combustion temperature is increased; this has the effect of increasing NOx emissions. Typically, EGR rates are correspondingly increased to mitigate this effect. Late inlet valve closure, which reduces an engine’s effective compression ratio, has been shown to provide an alternative method of reducing NOx emissions.

In-cylinder temperature measurements are vital for the validation of gasoline engine modelling and useful in their own right for explaining differences in engine performance. The underlying chemical reactions in combustion are highly sensitive to temperature and affect emissions of both NOx and particulate matter. The two techniques described here are complementary, and can be used for insights into the quality of mixture preparation by measurement of the in-cylinder temperature distribution during the compression stroke. The influence of fuel composition on in-cylinder mixture temperatures can also be resolved. Laser Induced Grating Spectroscopy (LIGS) provides point temperature measurements with a pressure dependent precision in the range 0.1 to 1.0 % when the gas composition is well characterized and homogeneous; as the pressure increases the precision improves.

The increased efficiency and specific output with Gasoline Direct Injection (GDI) engines are well known, but so too are the higher levels of Particulate Matter emissions compared with Port Fuel Injection (PFI) engines. To minimise Particulate Matter emissions, then it is necessary to understand and control the mixture preparation process, and important insights into GDI engine mixture preparation and combustion can be obtained from optical access engines. Such data is also crucial for validating models that predict flows, sprays and air fuel ratio distributions. The purpose of this paper is to review a number of optical techniques; the interpretation of the results is engine specific so will not be covered here. Mie scattering can be used for semi-quantitative measurements of the fuel spray and this can be followed with Planar Laser Induced Fluorescence (PLIF) for determining the air fuel ratio and temperature distributions.

Modern diesel cars, fitted with state-of-the-art aftertreatment systems, have the capability to emit extremely low levels of pollutant species at the tailpipe. However, diesel aftertreatment systems can represent a significant cost, packaging and maintenance requirement. Reducing engine-out emissions in order to reduce the scale of the aftertreatment system is therefore a high priority research topic. Engine-out emissions from diesel engines are, to a significant degree, dependent on the detail of fuel/air interactions that occur in-cylinder, both during the injection and combustion events and also due to the induced air motion in and around the bowl prior to injection. In this paper the effect of two different piston bowl shapes are investigated.

The introduction of transient test cycles and the focus on real world driving emissions has increased the importance of ensuring the NOx and soot emissions are controlled during transient manoeuvres. At the same time, there is a drive to reduce the number of calibration variables used by engine control strategies to reduce development effort and costs. In this paper, a control orientated combustion model, [1], and model predictive control strategy, [2], that were developed in simulation and reported in earlier papers, are applied to a Diesel engine and demonstrated in a test vehicle. The paper describes how the control approach developed in simulation was implemented in embedded hardware, using an FPGA to accelerate the emissions calculations. The development of the predictive controller includes the application of a simplified optimisation algorithm to enable a real-time calculation in the test vehicle.