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Methanol is currently being evaluated as a promising alternative fuel for internal combustion engines, due to being attainable by carbon neutral or negative pathways (renewable energy and carbon capture technology). The low ignitability of methanol has made it attractive mostly as a fuel for spark ignition engines, however the low sooting properties of the fuel could potentially reduce the NOx-soot tradeoff present in compression ignition engines. In this work, using a 4-cylinder engine with compression ratio modified from 16:1 to 19:1, methanol combustion is evaluated under five operating conditions in terms of fuel consumption, criteria pollutants, CO2 emissions and engine efficiency in addition to the qualitative assessment of the combustion stability. It was found that combustion is stable at medium to high loads, with medium load NOx emissions levels at least 30% lower than the original diesel engine and comparable emissions at maximum load conditions.

The urban mobility electrification has been proposed as the main solution to the vehicle emission issues in the next years. However, internal combustion engines have still great potential to decarbonize the transport sector through the use of low/zero-carbon fuels. Alcohols such us methanol, have long been considered attractive alternative fuels for spark ignition engines. They have properties similar to those of gasoline, are easy to transport and store. Recently, great attention has been devoted to gaseous fuels that can be used in existing engine after minor modification allowing to drastically reduce the pollutant emissions. In this regard, this study tries to provide an overview on the use of alternative fuels, both liquid and gaseous in spark ignition engines, highlighting the benefits as well as the criticalities. The investigation was carried out on a small displacement spark ignition engine capable to operate both in port fuel and direct injection mode.

Hydrogen Internal Combustion Engines (H2-ICEs) are subject to increased attention thanks to their extremely low criteria pollutant emission and near-zero CO2 tailpipe emissions. However, to further minimize exhaust emissions and increase the efficiency of a H2-ICE, it is important to carefully control the relative air-fuel ratio of operation, i.e. Lambda (λ), which will lead in turn to an optimal combustion process. The precise λ control mainly relies upon the methodology to calculate λ on board of the engine, where the availability of reliable sensors specifically-developed for hydrogen combustion is currently limited. In this article, a comparative analysis of different methodologies for the calculation of λ is performed, comparing four methodologies: exhaust gas analysis through a Spindt-Brettschneider approach (λEMI), raw Universal Exhaust Gas Oxygen (λR-UEGO), processed Universal Exhaust Gas Oxygen (λP-UEGO) and speed-density (λSD) outputs.

Direct injection spark ignition engines represent an effective technology to achieve the goal of carbon dioxide emission reduction. Further reduction of the carbon footprint can be achieved by using carbon-neutral fuels. Oxygenated alcohols are well consolidated fuels for spark ignition engines providing also the advantages of knock resistance and low soot tendency production. Methanol and ethanol are possible candidates as alternative fuels to gasoline due to their similar properties. In this study a blend at 25 % v/v of ethanol in gasoline (E25) and a blend with 80% gasoline, 5 % v/v ethanol and 15% v/v of methanol (GEM) were tested. These blends were considered since E25 is already available at fuel pump in some countries. The GEM blend, instead, could represent a valid alternative in the next future. Experiments were carried out on a high performance, turbocharged 1.8 L direct injection spark ignition engine over the Worldwide Harmonized Light Vehicles Test Cycle.

De-fossilization is an increasingly important trend in the energy sector. In the transport sector the de-fossilization efforts have been centered in promoting the electrification of vehicles, nonetheless other pathways, like the use of carbon neutral or carbon-offsetting fuels under current vehicle fleets, are also worth considering. Low-carbon fuels (LCF) can be synthetized from sources that can take advantage of the carbon already present in the atmosphere (either by technologies like direct carbon capture or biological processes like photosynthesis in biofuels) and use energy from renewable sources for the necessary industrial processes. Although, LCFs can be compared to fossil fuels as energy sources for internal combustion engines, their composition is not the same and their properties can modify the engine combustion and emissions.

The continuous improvement of internal combustion engines (ICEs) with strategies that can be applied to existing vehicle platforms, either directly or with minor modifications, can improve efficiency and reduce GHG emissions to help achieve Paris climate targets. Low carbon fuels (LCF) as diesel substitutes for light and heavy-duty vehicles are currently being considered as a promising alternative to reduce well-to-wheel (WTW) CO2 emissions by taking advantage of the carbon offset their synthesis pathway can promote, which could capture more CO2 than it releases into the atmosphere. Additionally, some low carbon fuels, like OMEx blends, have non-sooting properties that can significantly improve the NOx-soot tradeoff. The current work studies the calibration optimization of a EU6D-TEMP light-duty engine using various LCFs with different renewable contents with the goal of reduced NOx emissions.

In view of the new emission regulations seeking to lower the particle cut-off size down to the current 23 nm, an extensive comprehension on the nature of sub-23 nm particles is crucial. In this regard, a new challenge lies ahead considering an even more massive use of biofuels. The objective of this research study was to characterize the sub-23 nm particles and to evaluate their volatile organic fraction (VOF) from a high performance, 1.8 L gasoline direct injection (GDI) engine under the Worldwide harmonized Light vehicles Test Cycle (WLTC). Particle emissions were measured through an Engine Exhaust Particle Sizer (EEPS) capable of particle sizing and counting in the range 5.6 - 560 nm. The sampling and conditioning were performed by both a single diluter and the Dekati Engine Exhaust Diluter (DEED) a Particle Measurement Programme (PMP) compliant sample conditioning system.

With the aim of identifying technical solutions to lower the particulate matter emissions, the engine research community made a consistent effort to investigate the root causes leading to soot formation. Nowadays, the computational power increase allows the use of advanced soot emissions models in 3D-CFD turbulent reacting flows simulations. However, the adaptation of soot models originally developed for Diesel applications to gasoline direct injection engines is still an ongoing process. A limited number of studies in literature attempted to model soot produced by gasoline direct injection engines, obtaining a qualitative agreement with the experiments. To the authors’ best knowledge, none of the previous studies provided a methodology to quantitatively match particulate matter, particulate number and particle size distribution function measured at the exhaust without a case-by-case soot model tuning.

Nowadays, the regulation regards only the particles larger than 23 nm. The attention is shifting towards the sub-23 nm particles because of their large presence at the exhaust of the modern engines and their negative impact on human health. The main challenge of the regulation of these particles is the definition of a proper procedure for their measure. The nature of the sub-23 nm particles is not well understood, and their measure is strongly affected by the sampling conditions leading to not reliable measure. The aim of this paper is to provide information on the emissions of sub-23 nm particles from GDI vehicles/engines. At the same time, the presence of volatiles, which mainly contribute to the formation of sub-23 nm particles, was evaluated and the effect of sampling conditions was investigated. The analysis was performed on a 1.8L GDI powered vehicle, widely used both in North America and Europe, and a 4-cylinder GDI engine, whose features are similar to those of the vehicle.

The permanent aim of the automotive industry is the further improvement of the engine efficiency and the simultaneous pollutant emissions reduction. The aim of the study was the optimization of the gasoline combustion by means of a passive prechamber. This analysis allowed the improvement of the engine efficiency in lean-burn operation condition too. The investigation was carried out in a commercial small Spark Ignition (SI) engine fueled with gasoline and equipped with a proper designed passive prechamber. It was analyzed the effects of the prechamber on engine performance, Indicated Mean Effective Pressure, Heat Release Rate and Fuel Consumption were used. Gaseous emissions were measured as well. Particulate Mass, Number and Size Distributions were analyzed. Emissions samples were taken from the exhaust flow, just downstream of the valves. Four different engine speeds were investigated, namely 2000, 3000, 4000 and 5000 rpm.

The growing concerns on the emission of particles smaller than 23 nm, which are harmful to human health, lead to the necessity of introducing a regulation for these particles not yet included in the current emission standards. Considering that measurements of concentration of sub-23 nm particles are particularly sensitive to the sampling conditions, it is important to identify an effective assessment procedure. Aim of this paper is the characterization of the effect of the sampling conditions on sub-23 nm particles, emitted by PFI (port fuel injection) and DI (direct injection) spark ignition engines fueled with gasoline, ethanol and a mixture of ethanol and gasoline (E30). The experimental activity was carried out on a 250 cm3 displacement four stroke GDI and PFI single cylinder engines. The tests were conducted at 2000 rpm and 4000 rpm full load, representative of the homologation urban driving cycle.

With demanding emissions legislations and the need for higher efficiency, new technologies for compression ignition engines are in development. One of them relies on reducing the heat losses of the engine during the combustion process as well as to devise injection strategies that reduce soot formation. Therefore, it is necessary a better comprehension about the turbulent kinetic energy (TKE) distribution inside the cylinder and how it is affected by the interaction between air flow motion and fuel spray. Furthermore, new diesel engines are characterized by massive decrease of NOx emissions. Therefore, considering the well-known NOx-soot trade-off, it is necessary a better comprehension and overall quantification of soot formation and how the different injection strategies can impact it.

The constant aim of the automotive industry is the further improvement of engine efficiency and the simultaneous reduction of the exhaust emissions. In order to optimize the internal combustion engines it is necessary to further improve the basic knowledge of the thermo-fluid dynamic phenomena occurring during the combustion process. In this context, the application of optical diagnostic techniques permits a deep insight into the fundamental processes such as flow development, fuel injection, and combustion process. In this paper the analysis of the combustion process of gaseous fuel ignited by the plasma jets coming from a prechamber was performed. The investigation was carried out in an optically accessible small Direct Injection Spark-Ignition (DI SI) engine fueled with Methane. The ignition was obtained with a properly designed fueled prechamber prototype.

The paper describes the results achieved in developing a new diesel combustion system for passenger car application that, while capable of high power density, delivers excellent fuel economy through a combination of mechanical and thermodynamic efficiencies improvement. The project stemmed from the idea that, by leveraging the high fuel injection pressure of last generation common rail systems, it is possible to reduce the engine peak firing pressure (pfp) with great benefits on reciprocating and rotating components light-weighting and friction for high-speed light-duty engines, while keeping the power density at competitive levels. To this aim, an advanced injection system concept capable of injection pressure greater than 2500 bar was coupled to a prototype engine featuring newly developed combustion system. Then, the matching among these features have been thoroughly experimentally examined.

The aim of the present study is to improve the effectiveness of automotive diesel engine and aftertreatment calibration process through the critical evaluation of several methodologies to estimate the soot mass flow produced by diesel engines fueled by petroleum fuels and filtered by Diesel Particulate Filters (DPF). In particular, its focus has been the development of a reliable simulation method for the accurate prediction of the engine-out soot mass flow starting from Filter Smoke Number (FSN) measurements executed in steady state conditions, in order to predict the DPF loading considering different engine working conditions corresponding to NEDC and WLTP cycles. In order to achieve this goal, the study was split into two main parts: Correlation between ‘wet PM’ (measured by soot filter weighing) and the ‘dry soot’ (measured by the Micro Soot Sensor MSS).

The aim of the present work is to provide further guidance into better understanding the production mechanisms of soot emissions in Spark-Ignition SI engines fueled with compressed natural gas. In particular, extensive experimental investigations were designed with the aim to isolate the contribution of the fuel from that of lubricant oil to particle emissions. This because the common thought is that particulate emerging from the engine derives mainly from fuel, otherwise the contribute of lubricant oil cannot be neglected or underestimated, especially when the fuel itself produces low levels of soot emissions, such as in the case of premixed natural gas. The fuel-derived contribution was studied by analyzing the influence that natural gas composition has on soot emitted from a single cylinder Spark-Ignition (SI) engine. To achieve this purpose, methane/propane mixtures were realized and injected into the intake manifold of a Single-Cylinder SI engine.

Fuel depletion as well as the growing concerns on environmental issues prompt to the use of more eco-friendly fuels. The compressed natural gas (CNG) is considered one of the most promising alternative fuel for engine applications because of the lower emissions. Nevertheless, recent studies highlighted the presence of ultrafine particle emissions at the exhaust of CNG engines. The present study aims to investigate the effect of CNG on particle formation and emissions when it was direct injected and when it was dual fueled with gasoline. In this latter case, the CNG was direct injected and the gasoline port fuel injected. The study was carried out on a transparent single cylinder SI engine in order to investigate the in-cylinder process by real time non-intrusive diagnostics. In-cylinder 2D chemiluminescence measurements from UV to visible were carried out.

In order to meet the increasingly strict emission regulations, several solutions for NOx and PM emissions reduction have been studied. Exhaust gas recirculation (EGR) technology has become one of the more used methods to accomplish the NOx emissions reduction. However, actual control strategies do not consider, in the definition of optimal EGR, its effect on particle size and density. These latter have a great importance both for the optimal functioning of after-treatment systems, but also for the adverse effects that small particles have on human health. Epidemiological studies, in fact, highlighted that the toxicity of particulate particles increases as the particle size decreases. The aim of this paper is to present a Neural Network model able to provide real time information about the characteristics of exhaust particles emitted by a Diesel engine.

This paper aims to correlate the in-cylinder soot formation and the exhaust particle emissions for different methods of gasoline/ethanol fueling in spark ignition engine. In particular, the engine was fueled with gasoline and ethanol separately and not, in this latter case both blended (E30) and dual fueled (EDF). For E30 the bend was direct injected and for EDF, the ethanol was injected in the combustion chamber and the gasoline into the intake duct. For both the injection configurations, the same percentage of ethanol in gasoline was supplied: 30%v/v. The measurements were carried out at 2000 and 4000 rpm, under full load, and stoichiometric condition, in small single cylinder optical engine. 2D-digital imaging was performed to follow the combustion process with a high spatial and temporal resolution through a full-bore optical piston. The two-color pyrometry was applied for the analysis of the in cylinder soot formation in the combustion chamber.

In this paper, the effect of the oxygen addition on engine performance and exhaust emissions was investigated. The experimental study was carried out in a small single-cylinder PFI SI four-stroke engine. The addition of the 5% vol and 10% vol of oxygen was performed in the intake duct. Typical urban driving operating conditions were investigated. The engine emissions were characterized by means of gaseous analyzers and a smokemeter. Particle size distribution function was measured in the size range from 5.6 to 560 nm by means of an Engine Exhaust Particle Sizer (EEPS). An improvement in terms of engine power output, without BSFC penalty, and HC emissions with oxygen addition was observed at all the investigated operating conditions. On the other hand, NOx and PM emissions increase.