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Renewably sourced hydrogen is seen as promising sustainable carbon-free alternative to conventional fossil fuels for use in hard to decarbonize sectors. As the hydrogen supply builds up, dual-fuel hydrogen-diesel engines have a particular advantage of fuel flexibility as they can operate only on diesel fuel in case of supply shortages, in addition to the simplicity of engine modification. The dual-fuel compression ignition strategy initiates combustion of hydrogen using short pilot-injections of diesel fuel into the combustion chamber. In the context of such engine combustion process, the impact of hydrogen addition on the ignition and combustion behavior of a pilot diesel-spray is investigated in a heavy-duty, single-cylinder, optical engine. To this end, the spatial and temporal evolution of two-stage autoignition of a diesel-fuel surrogate, n-heptane, injected into a premixed charge of hydrogen and air is studied using optical diagnostics.

This work is a comprehensive technical review of existing literature and a synthesis of current understanding of the governing physics behind the interaction of multiple fuel injections, ignition, and combustion behavior of multiple-injections in diesel engines. Multiple-injection is a widely adopted operating strategy applied in modern compression-ignition engines, which involves various combinations of small pre-injections and post-injections of fuel before and after the main injection and splitting the main injection into multiple smaller injections. This strategy has been conclusively shown to improve fuel economy in diesel engines while achieving simultaneous NOX, soot, and combustion noise reduction - in addition to a reduction in the emissions of unburned hydrocarbons (UHC) and CO by preventing fuel wetting and flame quenching at the piston wall.

The enhancement of vortex development, fuel-air mixing and heat release in diesel spray flame by inversed-delta injection rate shaping, having been predicted via LES simulation with detailed chemical kinetics, is experimentally confirmed for the first time. Newly developed 3-injector TAIZAC (TAndem Injector Zapping ACtivation) injector realizing aggressive inversed-delta injection rate shaping was used for single-shot combustion experiments in a constant volume combustion vessel. Simultaneous high-speed (120,000fps) and high-resolution (1,280 x 704 pixels) laser schlieren and UV OH* chemiluminescence imaging combined with subsequent Flame Imaging Velocimetry (FIV) analysis was employed to elucidate the correlation between vortex development and enhanced heat release.

A hydrogen-diesel dual direct injection (H2DDI) combustion strategy in a compression-ignition engine is investigated numerically, reproducing the configuration of previous experimental investigations. These experiments demonstrated the potential of up to 50% diesel substitution by hydrogen while maintaining high engine efficiency; nevertheless, the emission of NOx increased compared with diesel operation and was strongly dependent on the hydrogen injection timing. This implies the efficiency and NOx emission are closely associated with hydrogen charge stratification; however, the underlying mechanisms are not fully understood. Aiming to highlight the hydrogen injection-timing influence on hydrogen/air mixture stratification and engine performance, the present study numerically investigates the mixture formation and combustion process in the H2DDI engine concept using Converge, a three-dimensional fluid dynamics simulation code.

The combustion process of a homogeneous hydrogen charge in a small-bore compression ignition engine with diesel-pilot ignition was simulated using the CONVERGE computational fluid dynamics code. Analysis of the simulation results aimed to understand the processes leading to NOx production and heat loss in this combustion strategy, and their dependence on the hydrogen fuel energy fraction. Previous experimental results demonstrated promising performance, but this comes with a penalty in increased NOx emissions and potentially higher heat losses. The present study aims to enhance understanding of the mechanisms governing these phenomena. The simulated engine was initialised with a lean homogeneous hydrogen-air mixture at BDC and n-dodecane was injected as a diesel surrogate fuel near TDC. The simulations were validated based on experimental results for up to 50% hydrogen energy fraction, followed by an exploratory study with variation of the energy fraction from 0% to 90%.

Implementing triple injection strategies in partially premixed charge-based gasoline compression ignition (GCI) engines has shown to achieve improved engine efficiency and reduced NOx and smoke emissions in many previous studies. While the impact of the triple injections on engine performance and engine-out emissions are well known, their role in controlling the mixture homogeneity and charge premixedness is currently poorly understood. The present study shows correspondence between the triple injection strategies and mixture homogeneity/premixedness through the experimental tests of second/third injection proportion and their timing variations with an aim to explain the observed GCI engine performance and emission trends. The experiments were conducted in a single cylinder, small-bore common-rail diesel engine fuelled with a commercial gasoline fuel of 95 research octane number (RON) and running at 2000 rpm and 830 kPa indicated mean effective pressure conditions.

In this study, a novel 3D-CFD combustion model employing Flamelet Generated Manifolds (FGM) for dual fuel combustion was developed. Validation of the platform was carried out using recent experimental results from an optically accessible Rapid Compression Expansion Machine (RCEM). Methane and n-dodecane were used as model fuels to remove any uncertainties in terms of fuel composition. The model used a tabulated chemistry approach employing a reaction mechanism of 130 species and 2399 reactions and was able to capture non-premixed auto ignition of the pilot fuel as well as premixed flame propagation of the background mixture. The CFD model was found to predict well all phases of the dual fuel combustion process: I) the pilot fuel ignition delay, II) the Heat Release Rate of the partially premixed conversion of the micro pilot spray with entrained methane/air and III) the sustained background mixture combustion following the consumption of the spray plume.

High-speed soot luminosity movies are widely used to visualise flame development in optical diesel engines thanks to its simple setup and relatively low cost. Recent studies demonstrated the high-speed soot luminosity movies are not only effective in showing the overall distribution and temporal evolution of sooting flames but also flow fields within the flame through the application of combustion (or flame) image velocimetry. The present study aims to improve this imaging technique by systematically evaluating key image processing parameters based on high-speed soot luminosity movies obtained from a single-cylinder, small-bore optical diesel engine. The raw soot luminosity movies are processed using PIVlab - a Matlab-based open-source code widely used for particle image velocimetry (PIV) applications.

Dual-fuel natural gas engines are seen as an attractive solution for simultaneous reduction of pollutant and CO2 emissions while maintaining high engine thermal efficiency. However, engines of this type exhibit a tradeoff between misfire as well as high UHC emissions for small pilot injection amounts and higher emissions of soot and NOX for operation strategies with higher pilot fuel proportion. The aim of this study was to investigate POMDME as an alternative pilot fuel having the potential to mitigate the emissions tradeoff, enabling smokeless combustion due to high degree of oxygenation, and being less prone to misfire due to its higher cetane number. Furthermore, POMDME can be synthetized carbon neutrally. First, characteristics of POMDME ignition in methane/air mixture and the transition into premixed flame propagation were investigated optically in a rapid compression-expansion machine (RCEM) by employing Schlieren and OH* chemiluminescence imaging.

The sooting propensity of dual-fuel combustion with n-dodecane pilot injection in a lean-premixed methane-air charge has been investigated using an optically accessible Rapid Compression-Expansion Machine (RCEM) to achieve engine-relevant pressure and temperature conditions at the start of pilot injection. A Diesel injector with a 100 μm single-hole coaxial nozzle, mounted at the cylinder periphery, has been employed to admit the pilot fuel. The aim of this study was to enhance the fundamental understanding of soot formation and oxidation processes of n-dodecane in the presence of methane in the air charge by parametric variation of methane equivalence ratio, charge temperature, and pilot fuel injection duration. The influence of methane on ignition delay and flame extent of the pilot fuel jet has been determined by simultaneous excited-state hydroxyl radical (OH*) chemiluminescence and Schlieren imaging.

Stringent particulate emission regulations are applied to spark-ignition direct-injection (SIDI) engines, calling for a significant in-cylinder reduction of soot particles. To enhance fundamental knowledge of the soot formation and oxidation process inside the cylinder of the engine, a new in-flame particle sampling system has been developed and implemented in a working optical SIDI engine with a side-mounted, wall-guided injection system. Using the sampling probes installed on the piston top, the soot particles are directly sampled from the petrol flame for detailed analysis of particle size distribution, structure, and shape. At the probe tip, a transmission electron microscope (TEM) grid is stored for the soot collection via thermophoresis, which is imaged and post-processed for statistical analysis. Simultaneously, the flame development was recorded using two high-speed cameras to evidence the direct exposure of the sampling grids to the soot-laden diffusion flames and pool fires.

The present study explores the effect of in-cylinder generated non-thermal plasma on hydroxyl and soot development. Plasma was generated using a newly developed Microwave Discharge Igniter (MDI), a device which operates based on the principle of microwave resonation and has the potential to accentuate the formation of active radical pools as well as suppress soot formation while stimulating soot oxidation. Three diagnostic techniques were employed in a single-cylinder small-bore optical diesel engine, including chemiluminescence imaging of electronically excited hydroxyl (OH*), planar laser induced fluorescence imaging of OH (OH-PLIF) and planar laser induced incandescence (PLII) imaging of soot. While investigating the behaviour of MDI discharge under engine motoring conditions, it was found that plasma-induced OH* signal size and intensity increased with higher in-cylinder pressures albeit with shorter lifetime and lower breakdown consistency.

The present study aims to evaluate the effects of engine speed on gasoline compression ignition (GCI) combustion implementing double injection strategies. The double injection comprises of near-BDC first injection for the formation of a premixed charge and near-TDC second injection for the combustion phasing control. The engine performance and emissions testing of GCI combustion has been conducted in a single-cylinder light-duty diesel engine equipped with a common-rail injection system and fuelled with a conventional gasoline with 91 RON. The double injection strategy was investigated for various engine speeds ranging 1200~2000 rpm and the second injection timings between 12°CA bTDC and 3°CA aTDC.

One major drawback of spark-ignition direct-injection (SIDI) engines is increased particulate matter (PM) emissions at high load, due to increased wall wetting and a reduction in available mixture preparation time when compared to port-fuel injection (PFI). It is therefore necessary to understand the mechanics behind injection strategies which are capable of reducing these emissions while also maintaining the performance and efficiency of the engine. Splitting the fuel delivery into two or more injections is a proven way of working towards this goal, however, many different injection permutations are possible and as such there is no clear consensus on what constitutes an ideal strategy for any given objective. In this study, the effect of the timing of the first and second injections for an evenly split dual injection strategy are investigated in an optical SIDI engine running at 1200 RPM with an unthrottled intake.

Ethanol has been selected as a fuel for gasoline compression ignition (GCI) engines realising partially premixed charge combustion, considering its higher resistance to auto-ignition, higher evaporative cooling and oxygen contents than widely used gasoline, all of which could further improve already high efficiency and low smoke/NOx emissions of GCI engines. The in-cylinder phenomena and engine-out emissions were measured in a single-cylinder automotive-size common-rail diesel engine with a special emphasis on double injection strategies implementing early first injection near BDC and late second injection near TDC.

The importance of radiative heat transfer on the combustion and soot formation characteristics under nominal ECN Spray A conditions has been studied numerically. The liquid n-dodecane fuel is injected with 1500 bar fuel pressure into the constant volume chamber at different ambient conditions. Radiation from both gas-phase as well as soot particles has been included and assumed as gray. Three different solvers for the radiative transfer equation have been employed: the discrete ordinate method, the spherical-harmonics method and the optically thin assumption. The radiation models have been coupled with the transported probability density function method for turbulent reactive flows and soot, where unresolved turbulent fluctuations in temperature and composition are included and therefore capturing turbulence-chemistry-soot-radiation interactions. Results show that the gas-phase (mostly CO2 ad H2O species) has a higher contribution to the net radiation heat transfer compared to soot.

This paper presents engine performance and emissions of coconut oil-derived 10% biodiesel blends in petroleum diesel demonstrating simultaneous reduction of smoke and NOx emissions and increased brake power. The experiments were performed in a single-cylinder version of a light-duty diesel engine for three different fuels including a conventional diesel fuel and two B10 fuels of chemical-catalyst-based methyl-ester biodiesel (B10mc) and biological-catalyst-based ethyl-ester biodiesel (B10eb). The engine tests were conducted at fixed speed of 2000 rpm and injection pressure of 130 MPa. In addition to the fuel variation, the injection timing and rate of exhaust gas recirculation (EGR) were also varied because they impact the combustion and thus the efficiency and emissions significantly.

The major challenge of the post-processing of soot aggregates in transmission electron microscope (TEM) images is the detection of soot primary particles that have no clear boundaries, vary in size within the fractal aggregates, and often overlap with each other. In this study, we propose an automated detection code for primary particles implementing the Canny Edge Detection (CED) and Circular Hough Transform (CHT) on pre-processed TEM images for particle edge enhancement using unsharp filtering as well as image inversion and self-subtraction. The particle detection code is tested for soot TEM images obtained at various ambient and injection conditions, and from five different combustion facilities including three constant-volume combustion chambers and two diesel engines.

In this paper, numerical simulations of an automotive-size optical diesel engine have been conducted employing the Reynolds-Averaged Navier-Stokes (RANS) equations with the standard k-ε turbulence model and a reduced n-heptane chemical mechanism implemented in OpenFOAM. The current paper builds on a previous work where the model has been validated for the same engine using optical diagnostic data. The present study investigates numerically the influence of different operating conditions - relevant for modern diesel engines - on the mixture formation development under non-reactive conditions as well as low- and high-temperature ignition behaviour and flame evolution in the presence of strong jet-wall interactions typically encountered in automotive-size diesel engines. Also, emissions of CO and unburned hydrocarbons (UHC) are considered.

The impact of fuel injection pressure on the development of diesel flames has been studied in a light-duty optical engine. Planer laser-induced fluorescence imaging of fuel (fuel-PLIF) and hydroxyl radicals (OH-PLIF) as well as line-of-sight integrated chemiluminescence imaging of cool-flame and OH* were performed for three different common-rail pressures including 70, 100, and 130 MPa. The injection timing and injected fuel mass were held constant resulting in earlier end of injection for higher injection pressure. The in-cylinder pressure was also measured to understand bulk-gas combustion conditions through the analysis of apparent heat release rate. From the cool-flame images, it is found that the low-temperature reaction starts to occur in the wall-interacting jet head region where the fuel-air mixing could be enhanced due to a turbulent ring-vortex formed during jet-wall interactions.