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Unsaturated methyl esters in biodiesel make it susceptible to oxidation and fuel quality degradation upon long-term storage. It is almost impossible to use biodiesel for commercial applications immediately after production. The lead time between biodiesel production and usage is generally high, causing auto-oxidation and fuel quality degradation. Hence any onsite improvement in fuel quality should be tested with aged biodiesel. To avoid the food versus fuel debate, non-edible oil feedstocks are preferable for producing biodiesel. However, biodiesel from non-edible oil sources has more unsaturated methyl ester constituents. The traditional trade-off between oxides of nitrogen (NOx) and soot emissions in conventional diesel combustion is reduced to a more severe NOx problem with biodiesel. In the present study, NOx mitigation through fuel modifications is studied for oxidized biodiesel produced from a non-edible oil, Karanja.

The presence of unsaturated methyl esters in biodiesel makes it susceptible to oxidation and fuel quality degradation upon long-term storage. In the present work, the effects of oxidation of Karanja biodiesel upon long-term storage on the combustion and emission characteristics of a heavy-duty truck diesel engine are studied. The Karanja biodiesel is stored for one year in a 200 litres steel barrel at room conditions to mimic commercial storage conditions. The results obtained show that compared to diesel, the start of injection of fresh and aged biodiesels are advanced by ~2-degree crank angle, and the ignition delay time is reduced. Aged biodiesel showed a slightly smaller ignition delay compares to fresh biodiesel. The fuel injection and combustion characteristics of fresh and aged biodiesels were similar at all the load conditions. Both fresh and aged biodiesels produced higher oxides of nitrogen (NOx) and lower smoke emissions compared to diesel.