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Ammonia shows promise as an alternative fuel for internal combustion engines (ICEs) in reducing CO2 emissions due to its carbon-free nature and well-established infrastructure. However, certain drawbacks, such as the high ignition energy, the narrow flammability range, and the extremely low laminar flame speed, limit its widespread application. The dual fuel (DF) mode is an appealing approach to enhance ammonia combustion. The combustion characteristics of ammonia-diesel dual fuel mode and ammonia-PODE3 dual fuel mode were experimentally studied using a full-view optical engine and the high-speed photography method. The ammonia energy ratio (ERa) was varied from 40% to 60%, and the main injection energy ratio (ERInj1) and the main injection time (SOI1) were also varied in ammonia-PODE3 mode.

Internal combustion engines, as the dominant power source in the transportation sector and the primary contributor to carbon emissions, face both significant challenges and opportunities in the context of achieving carbon neutral goal. Biofuels, such as biodiesel produced from biomass, and zero-carbon fuel ammonia, can serve as alternative fuels for achieving cleaner combustion in internal combustion engines. The dual-fuel combustion of ammonia-biodiesel not only effectively reduces carbon emissions but also exhibits promising combustion performance, offering a favorable avenue for future applications. However, challenges arise in the form of unburned ammonia (NH3) and N2O emissions. This study, based on a ammonia-biodiesel duel-fuel engine modified from a heavy-duty diesel engine, delves into the impact of adjustments in the two-stage injection strategy on the combustion and emission characteristics.

In the context of carbon neutrality, ammonia is considered a zero-carbon fuel with potential applications in the transportation sector. However, its high ignition energy, low flame speed, and high natural temperature, indicative of low reactivity, make it challenging to be applied as a sole fuel in engines. In such a scenario, the use of another zero-carbon and highly reactive fuel, hydrogen, becomes necessary to enhance the combustion of ammonia. Furthermore, jet ignition, a method known for improving engine combustion performance, may also hold potential for enhancing the combustion performance of ammonia engines. To explore the applicability of jet ignition in engines, this study conducted experimental research on a single-cylinder engine. Two ignition methods were employed: passive jet ignition of premixed ammonia-hydrogen at a compression ratio of 11.5, and active jet ignition of pure ammonia using hydrogen jet flame at a compression ratio of 17.3.

Ammonia and methanol are both future fuels with carbon-neutral potential. Ammonia has a high octane number, a slow flame speed, and a narrow ignition limit, while methanol has a fast flame speed with complementary combustion characteristics but is more likely to lead to pre-ignition and knock. In this paper, the combustion and emission characteristics of ammonia-methanol solution in a high compression ratio spark ignition engine are investigated. The experimental results show that the peak in-cylinder pressure and peak heat release rate of the engine when using ammonia-methanol solution are lower and the combustion phase is retarded compared with using methanol at the same spark timing conditions. Using ammonia-methanol solution in the engine resulted in a more ideal combustion phase than that of gasoline, leading to an increase in indicated thermal efficiency of more than 0.6% and a wider range of efficient operating conditions.

Ammonia (NH3), a zero-carbon fuel, has great potential for internal combustion engine development. However, its high ignition energy, low laminar burning velocity, narrow range of flammability limits, and high latent heat of vaporization are not conducive for engine application. This paper numerically investigates the feasibility of utilizing ammonia in a heavy-duty diesel engine, specifically through low-pressure direct injection (LP-DI) of hydrogen to ignite ammonia combustion. Due to the lack of a well-corresponding mechanism for the operating conditions of ammonia-hydrogen engines, this study serves only as a trend-oriented prediction. The paper compares the engine's combustion and emission performance by optimizing four critical parameters: excess air ratio, hydrogen energy ratio, ignition timing, and hydrogen injection timing. The results reveal that excessively high hydrogen energy ratios lead to an advanced combustion phase, reducing indicated thermal efficiency.

Turbulent jet ignition (TJI) combustion using pre-chamber ignition can accelerate the combustion speed in the cylinder and has garnered growing interest in recent years. However, it is complicated for the optimization of the pre-chamber structure and combustion system. This study investigated the effects of the pre-chamber structure and the intake ports on the combustion characteristics of a gasoline engine through CFD simulation. Spark ignition (SI) combustion simulation was also conducted for comparison. The results showed that the design of the pre-chamber that causes the jet flame colliding with walls severely worsen the combustion, increasing the knocking intendency, and decrease the thermal efficiency. Compared with SI combustion mode, the TJI combustion mode has the higher heat transfer loss and lower unburned loss. The well-optimized pre-chamber can accelerate the flame propagation with knock suppression.

A feasible method was developed to reconstruct the three-dimensional flame surface of SI combustion based on 2D images. A double-window constant volume vessel was designed to simultaneously obtain the side and bottom images of the flame. The flame front was reconstructed based on 2D images with a slicing model, in which the flame characteristics were derived by slicing flame contour modeling and flame-piston collision area analysis. The flame irregularity and anisotropy were also analyzed. Two different principles were used to build the slicing model, the ellipse hypothesis modeling and deep learning modeling, in which the ellipse hypothesis modeling was applied to reconstruct the flame in the optical SI engine. And the reconstruction results were analyzed and discussed. The reconstruction results show that part of the wrinkled and folded structure of the flame front in SI engines can be revealed based on the bottom view image.

Particulate matter emissions from internal combustion engines have become an increasingly important area of focus for development teams in recent years. This is due to greater regulatory scrutiny on vehicles globally, and especially on particulate emissions. The chemical composition and bulk physical properties of the fuel have been shown to influence the particulate number emissions characteristics. Although some predictive models have been proposed, the causality of specific properties or constituents has not been demonstrated due to the co-linearity of the variables considered in previous studies. In this work, fuels were formulated to capture the expected variation in three key properties of United States (US) market gasoline fuels. Specifically, total aromatics, volatility, and particulate matter index (PMI) were varied across market extremes within regulatory limits--while holding other properties constant.

A computational fluid dynamics (CFD) guided design optimization was conducted for the piston bowl geometry for a heavy-duty diesel engine. The optimization goal was to minimize engine-out NOx emissions without sacrificing engine peak power and thermal efficiency. The CFD model was validated with experiments and the combustion system optimization was conducted under three selected operating conditions representing low speed, maximum torque, and rated power. A hundred piston bowl shapes were generated, of which 32 shapes with 3 spray angles for each shape were numerically analyzed and one optimized design of piston bowl geometry with spray angle was selected. On average, the optimized combustion system decreased nitrogen oxide (NOx) emissions by 17% and soot emissions by 41% without compromising maximum engine power and fuel economy.

High-pressure gasoline injection can improve combustion efficiency and lower engine-out emissions; however, the spray characteristics of high-pressure gasoline (>500 bar) are not well known. Effects of different injector nozzle geometry on high-pressure gasoline sprays were studied using a constant volume chamber. Five nozzles with controlled internal flow features including differences in nozzle inlet rounding, conicity, and outlet diameter were investigated. Reference grade gasoline was injected at fuel pressures of 300, 600, 900, 1200, and 1500 bar. The chamber pressure was varied using nitrogen at ambient temperature and pressures of 1, 5, 10, and 20 bar. Spray development was recorded using diffuse backlit shadowgraph imaging methods.

The ignition of lubricating oil droplet has been proved to be the main factor for pre-ignition and the following super-knock in turbocharged gasoline direct injection engine. In this paper, the ignition process of lubricating oil droplet in combustible ambient gaseous mixture was investigated in a rapid compression machine (RCM). The pre-ignition induction by oil droplet of the ambient gaseous mixture was analyzed under different initial droplet volume and effective temperature conditions. The oil droplet was suspended on a tungsten fiber in the combustion chamber and the ignition process was recorded by a high-speed camera through the quartz window mounted at the end of the combustion chamber. The pressure traces were also obtained by a sensor in order to get the ignition delay and analyze the combustion process in detail.

Compression ratio and specific heat ratio are two dominant factors influencing engine thermal efficiency. Therefore, ultra-lean burn may be one method to deal with increasingly stringent fuel consumption and emission regulations in the approaching future. To achieve high efficiency and clean combustion, innovative combustion modes have been applied on research engines including homogeneous charge compression ignition (HCCI), spark-assisted compression ignition (SACI), and gasoline direct-injection compression ignition (GDCI), etc. Compared to HCCI, SACI can extend the load range and more easily control combustion phase while it is constrained by the limit of flame propagation. For SACI with ultra-lean burn in engines, equivalence ratio (φ), rich-fuel mixture around spark plug, and supercharging are three essentials for combustion stability.

Polyoxymethylene dimethyl ethers (PODEn) have high cetane number, high oxygen content and high volatility, therefore can be added to gasoline to optimize the performance and soot emission of Gasoline Compression Ignition (GCI) combustion. High speed imaging was used to investigate the spray and combustion process of gasoline/PODEn blends (PODEn volume fraction 0%-30%) under various ambient conditions and injection strategies in a constant volume vessel. Results showed that with an increase of PODEn proportion from 10% to 30%, liquid-phase penetration of the spray increased slightly, ignition delay decreased from 3.8 ms to 2.0 ms and flame lift off length decreased 29.4%, causing a significant increase of the flame luminance. For blends with 20% PODEn, when ambient temperature decreased from 893 K to 823 K, the ignition delay increased 1.3 ms and the flame luminance got lower.

Compressed Natural Gas (CNG), because of its low cost, high H/C ratio, and high octane number, has great potential in automotive industry, especially for heavy-duty commercial vehicles. However, relative slow flame speed of natural gas leads to long combustion duration and low thermal efficiency and tends to cause knock combustion at high load, which will aggravate engine thermal load and reliability. Enhancing turbulence intensity in combustion chamber is an effective way to accelerate flame propagation speed and improve combustion performance. In this study, the flow simulations of several piston bowls with different inner-convex forms were carried out using three-dimensional computational fluid dynamics (3D-CFD) software CONVERGE. The numerical results showed the piston bowls with inner-convex could disturb the charge swirl motion and enhance turbulence of different intensity. A hexagram geometry bowl was proved to have the best function in strengthening turbulence intensity.

Non-reacting spray behaviors of the Engine Combustion Network “Spray G” gasoline fuel injector were investigated at flash and non-flash boiling conditions in an optically accessible single cylinder engine and a constant volume spray chamber. High-speed Mie-scattering imaging was used to determine transient liquid-phase spray penetration distances and observe general spray behaviors. The standardized “G2” and “G3” test conditions recommended by the Engine Combustion Network were matched in this work and the fuel was pure iso-octane. Results from the constant volume chamber represented the zero (stationary piston) engine speed condition and single cylinder engine speeds ranged from 300 to 2,000 RPM. As expected, the present results indicated the general spray behaviors differed significantly between the spray chamber and engine. The differences must be thoughtfully considered when applying spray chamber results to guide spray model development for engine applications.

Wide Distillation Fuel (WDF), with a distillation range from Initial Boiling Point of gasoline to Final Boiling Point of diesel, can be easily gained directly by blending diesel with gasoline. However, the reduced auto-ignitability of WDF could lead to higher HC emissions. Polyoxymethylene Dimethyl Ethers (PODE), with good volatility and oxygen content of up to 49%, have great potential to improve combustion and emission characteristics, especially for soot reduction. Experiments were carried out in a light-duty four-cylinder diesel engine fueled with neat diesel, gasoline/diesel blends (GD), GD/PODE blends (GDP) and the combustion and emission characteristics were carefully examined. Results showed that GDP had the lowest PM emission and diesel had the poorest one among the three fuels. Due to the addition of gasoline and the relatively poor ignitability, GD had lower combustion efficiency and higher Soluble Organic Fraction (SOF) emissions than diesel.

Gasoline Direct Injection (GDI) has become the preferred technology for spark-ignition engines resulting in greater specific power output and lower fuel consumption, and consequently reduction in CO2 emission. However, GDI engines face a substantial challenge in meeting new and future emission limits, especially the stringent particle number (PN) emissions recently introduced in Europe and China. Studies have shown that the fuel used by a vehicle has a significant impact on engine out emissions. In this study, nine fuels with varying chemical composition and physical properties were tested on a modern turbo-charged side-mounted GDI engine with design changes to reduce particulate emissions. The fuels tested included four fuels meeting US certification requirements; two fuels meeting European certification requirements; and one fuel meeting China 6 certification requirements being proposed at the time of this work.

In order to meet increasingly stringent fuel consumption and emission regulations, more attentions are paid to improve engine efficiency. A large amount of energy-saving technologies have been applied in automotive field especially in gasoline engines. It is well known that lean burn and ultra-high compression ratio technologies are two basic and important methods to increase efficiency. In this paper, a rapid compression machine was employed to study combustion process of lean iso-octane mixture at ultra-high compression ratios (16 to 19:1). Regardless of flammability of the mixture, spark was triggered at the timing right after the end of compression, then, the flame propagation and/or auto-ignition can be recorded using high-speed photography simultaneously. The effects of equivalence ratio (φ), compression ratio (ε), dilution ratio, and effective temperature (Teff) on the combustion process was investigated.

High-pressure gasoline fuel injection is a means to improve combustion efficiency and lower engine-out emissions. The objective of this study was to quantify the effects of fuel injection pressure on transient gasoline fuel spray development for a wide range of injection pressures, including over 1000 bar, using a constant volume chamber and high-speed imaging. Reference grade gasoline was injected at fuel pressures of 300, 600, 900, 1200, and 1500 bar into the chamber, which was pressurized with nitrogen at 1, 5, 10, and 20 bar at room temperature (298 K). Bulk spray imaging data were used to quantify spray tip penetration distance, rate of spray tip penetration and spray cone angle. Near-nozzle data were used to evaluate the early spray development.

Polyoxymethylene Dimethyl Ether (PODEn) is a promising green additive to diesel fuel, owing to the unique chemical structure (CH3O[CH2O]nCH3, n≥2) and high cetane number. Together with the general wide-distillation fuel (WDF), which has an attractive potential to reduce the cost of production of vehicle fuel, the oxygenated WDF with PODEn can help achieve a high efficiency and low emissions of soot, NOx, HC, and CO simultaneously. In this paper, the first detailed reaction mechanism (225 species, 1082 reactions) which can describe the ignition characteristics of PODE1 and PODE3 at low temperature was developed.