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In pursuing sustainable automotive technologies, exploring alternative fuels for hybrid vehicles is crucial in reducing environmental impact and aligning with global carbon emission reduction goals. This work compares methanol and naphtha as potential suitable alternative fuels for running in a battery-driven light-duty hybrid vehicle by comparing their performance with the diesel baseline engine. This work employs a 0-D vehicle simulation model within the GT-Power suite to replicate vehicle dynamics under the Worldwide Harmonized Light Vehicles Test Cycle (WLTC). The vehicle choice enables the assessment of a delivery application scenario using distinct payload capacities: 0%, 25%, 50%, and 100%. The model is fed with engine maps derived from previous experimental work conducted in the same engine, in which a full calibration was obtained that ensures the engine's operability in a wide region of rotational speed and loads.

Ammonia has emerged as a promising carbon-free alternative fuel for internal combustion engines (ICE), particularly in large-bore engine applications. However, integrating ammonia into conventional engines presents challenges, prompting the exploration of innovative combustion strategies like dual-fuel combustion. Nitrous oxide (N2O) emissions have emerged as a significant obstacle to the widespread adoption of ammonia in ICE. Various studies suggest that combining exhaust gas recirculation (EGR) with adjustments in inlet temperature and diesel injection timing can effectively mitigate nitrogen oxides (NOx) emissions across diverse operating conditions in dual-fuel diesel engines.

In the perspective of a reduction of emissions and a rapid decarbonisation, especially for compression ignition engines, hydrogen plays a decisive role. The dual fuel technology is perfectly suited to the use of hydrogen, a fuel characterized by great energy potential. In fact, replacing, at the same energy content, the fossil fuel with a totally carbon free one, a significant reduction of the greenhouse gases, like carbon dioxide and total hydrocarbon, as well as of the particulate matter can be obtained. The dual fuel with indirect injection of gaseous fuel in the intake manifold, involves the problem of hydrogen autoignition. In order to avoid this difficulty, the optimal conditions for the injection of the incoming mixture into the cylinder were experimentally investigated. All combustion processes are carried out on a research engine with optical access. The engine speed has is set at 1500 rpm, while the EGR valve is deactivated.

Predicting and preventing combustion anomalies leads to safe and efficient operation of the hydrogen internal combustion engine. This research presents the application of three machine learning (ML) models – K-Nearest Neighbors (KNN), Random Forest (RF) and Logistic Regression (LR) – for the prediction of combustion anomalies in a hydrogen internal combustion engine. A small experimental dataset was used to train the models and posterior experiments were used to evaluate their performance and predicting capabilities (both in operating points -speed and load- within the training dataset and operating points in other areas of the engine map). KNN and RF exhibit superior accuracy in classifying combustion anomalies in the training and testing data, particularly in minimizing false negatives, which could have detrimental effects on the engine.

With the aim of decarbonizing the vehicles fleet, the use of hydrogen is promising solution. Hydrogen is an energy carrier, carbon-free, with high calorific value and with no CO2 and HC emissions burning in ICE. Hydrogen use in spark ignition engines has already been extensively investigated and optimized. On the other hand, its use in compression ignition engines has been little developed and, therefore, there is a lack of information regarding the combustion in ultra-lean conditions, typical of diesel engines. Several applications employ dual fuel combustion for the easy management of the PFI injection system to be applied in addition to the DI Common Rail system. However, this mode suffers from several problems regarding the management of the maximum flow rate of hydrogen into the intake. In particular, to avoid throwing hydrogen into the exhaust, injection must be started after the valve crossing.

The transport of goods and people by sea, today, must meet the need to reduce the consumption of fuel oil. In addition, it has to ensure operational reliability and vessel availability, to reduce maintenance costs and comply with emission legislation. To this end, it is necessary to apply a marine engine combustion control system already widely used in engines for land transport. This will allow the ship's engines to operate reliably and in compliance with the best performance for which it was designed. The combustion control could also ensure a more balanced operation of the cylinders and reduce the torsional vibrations of the entire engine, as well as the management of the engine according to the adopted fuel: diesel, dual fuel, methanol, ammonia. Generally, the control of combustion in engines is carried out through the use of pressure sensors that face directly into the combustion chamber.

Electrification of transport, together with the decarbonization of energy production are suggested by the European Union for the future quality of air. However, in the medium period, propulsion systems will continue to dominate urban mobility, making mandatory the retrofitting of thermal engines by applying combustion modes able to reduce NOx and PM emissions while maintaining engine performances. Low Temperature Combustion (LTC) is an attractive process to meet this target. This mode relies on premixed mixture and fuel lean in-cylinder charge whatever the fuel type: from conventional through alternative fuels with a minimum carbon footprint. This combustion mode has been subject of numerous modelling approaches in the engine research community. This study provides a theoretical comparative analysis between multi-zone (MZ) and Transported probability density function (TPDF) models applied to LTC combustion process.

Using renewable fuels is a reliable approach for decarbonization of combustion engines. iso-Butanol and n-butanol are known as longer chain alcohols and have the potential of being used as gasoline substitute or a renewable fraction of gasoline. The combustion behavior of renewable fuels in modern combustion engines and advanced combustion concepts is not well understood yet. Low-temperature combustion (LTC) is a concept that is a basis for some of the low emissions-high efficiency combustion technologies. Fuel ɸ-sensitivity is known as a key factor to be considered for tailoring fuels for these engines. The Lund ɸ-sensitivity method is an empirical test method for evaluation of the ɸ-sensitivity of liquid fuels and evaluate fuel behavior in thermal. iso-Butanol and n-butanol are two alcohols which like other alcohol exhibit nonlinear behavior when blended with (surrogate) gasoline in terms of RON and MON.

Methanol is currently being evaluated as a promising alternative fuel for internal combustion engines, due to being attainable by carbon neutral or negative pathways (renewable energy and carbon capture technology). The low ignitability of methanol has made it attractive mostly as a fuel for spark ignition engines, however the low sooting properties of the fuel could potentially reduce the NOx-soot tradeoff present in compression ignition engines. In this work, using a 4-cylinder engine with compression ratio modified from 16:1 to 19:1, methanol combustion is evaluated under five operating conditions in terms of fuel consumption, criteria pollutants, CO2 emissions and engine efficiency in addition to the qualitative assessment of the combustion stability. It was found that combustion is stable at medium to high loads, with medium load NOx emissions levels at least 30% lower than the original diesel engine and comparable emissions at maximum load conditions.

Although in the latest years the use of compression ignition engines has been a thread of discussion in the automotive field, it is possible to affirm that it still will be a fundamental producer of mechanical power in other sectors, such as naval and off-road applications. However, the necessity of reducing emissions requires to keep on studying new solutions for this kind of engine. Dual fuel combustion concept with methane has demonstrated to be effective in preserving the performance of the original engine and reducing soot, but issues related to the low flame speed forced researcher to find an alternative fuel at low impact of CO2. Hydrogen, thanks to its chemical and physical properties, can be a perfect candidate to ensure a good level of combustion efficiency; however, this is possible only with a proper management of the in-cylinder mixture ignition by means of a pilot injection, preventing uncontrolled autoignition events as well.

In order to reduce fuel consumption and polluting emissions from engines, alternative fuels such as hydrogen could play an important role towards carbon neutrality. Moreover, dual-fuel (DF) technology has the potential to offer significant improvements in carbon dioxide emissions for transportation and energy sectors. The dual fuel concept (natural gas/diesel or hydrogen/diesel) represents a possible solution to reduce emissions from diesel engines by using low-carbon or carbon-free gaseous fuels as an alternative fuel. Moreover, DF combustion is a possible retrofit solution to current diesel engines by installing a PFI injector in the intake manifold while diesel is injected directly into the cylinder to ignite the premixed mixture. In the present study, dual fuel operation has been investigated in a single cylinder research engine.

In this work, an ozone/air/gasoline mixture has been used as an alternative strategy to achieve a stable combustion in a spark ignition (SI) single cylinder PFI research engine. The air intake manifold has been modified to include four cells to produce ozone with different concentrations. In the research engine, various operating parameters have been monitored such as the in-cylinder pressure, temperature and composition of the exhaust gases, pressure and temperature of the mixture in the intake manifold, engine power and torque and specific fuel consumption. Experimental tests have been carried out under stoichiometric mixture conditions to observe the influence of ozone addition on the combustion process. The results show an advance and an increase of the in-cylinder pressure compared to the reference test-case, where a gasoline/air mixture is used. It is worth noting that, especially under stoichiometric condition, ozone concentration induces auto-ignition and knock.

The application of an alternative fuel such as hydrogen to internal combustion engines is proving to be an effective and flexible solution for reducing fuel consumption and polluting emissions from engines. An easy to use and immediate application solution is the dual fuel (DF) technology. It has the potential to offer significant improvements in carbon dioxide emissions from light compression ignition engines. The dual fuel concept (natural gas / diesel or hydrogen / diesel) represents a possible solution to reduce emissions from diesel engines by using low-carbon or carbon-free gaseous fuels as an alternative fuel. Moreover, DF combustion is a possible retrofit solution to current diesel engines by installing a PFI injector in the intake manifold while diesel is injected directly into the cylinder to ignite the premixed mixture. In the present study, dual fuel operation has been investigated in a single cylinder research engine.

A commercially available fuel, E85, a blend of ~85% ethanol and ~15% gasoline, can be a viable substitute for fossil fuels in internal combustion engines in order to achieve a reduction of the greenhouse gas (GHG) emissions. Ethanol is traditionally made of biomass, which makes it a part of the food-feed-fuel competition. New processes that reuse waste products from other industries have recently been developed, making ethanol a renewable and sustainable second-generation fuel. So far, work on E85 has focused on spark ignition (SI) concepts due to high octane rating of this fuel. There is very little research on its application in CI engines. Alcohols are known for low soot particle emissions, which gives them an advantage in the NOx-soot trade-off of the compression ignition (CI) concept.

Nowadays, the stricter regulations in terms of emissions have limited the use of diesel engines on urban roads. On the contrary, for marine and off-road applications the diesel engine still represents the most feasible solution for work production. In the last decades, dual fuel operation with methane supply has been widely investigated. Starting from previous studies on a research engine, where diesel-methane dual fuel combustion has been deepened both experimentally and numerically with the aid of a CFD code, the authors implemented and tested a kinetic mechanism. It is obtained from the combination of the well-established GRIMECH 3.0 and a detailed scheme for a diesel surrogate oxidation. Moreover, the Autoignition-Induced Flame Propagation model, included in the ANSYS Forte® software, is applied because it can be considered the most appropriate model to describe dual fuel combustion.

De-fossilization is an increasingly important trend in the energy sector. In the transport sector the de-fossilization efforts have been centered in promoting the electrification of vehicles, nonetheless other pathways, like the use of carbon neutral or carbon-offsetting fuels under current vehicle fleets, are also worth considering. Low-carbon fuels (LCF) can be synthetized from sources that can take advantage of the carbon already present in the atmosphere (either by technologies like direct carbon capture or biological processes like photosynthesis in biofuels) and use energy from renewable sources for the necessary industrial processes. Although, LCFs can be compared to fossil fuels as energy sources for internal combustion engines, their composition is not the same and their properties can modify the engine combustion and emissions.

Focusing on the dual-mode dual-fuel (DMDF) combustion concept, a combined optimization of the piston bowl geometry with the fuel injection strategy was conducted at low, mid, and high loads. By coupling the KIVA-3V code with the enhanced genetic algorithm (GA), a total of 14 parameters including the piston bowl geometric parameters and the injection parameters were optimized with the objective of meeting Euro VI regulations while improving the fuel efficiency. The optimal piston bowl shape coupled with the corresponding injection strategy was summarized and integrated at various loads. Furthermore, the effects of the key geometric parameters were investigated in terms of organizing the in-cylinder flow, influencing the energy distribution, and affecting the emissions. The results indicate that the behavior of the DMDF combustion mode is further enhanced in the aspects of improving the fuel economy and controlling the emissions after the bowl geometry optimization.

Fleet electrification has been demonstrated as a feasible solution to decarbonize the heavy-duty transportation sector. The combination of hybridization and advanced combustion concepts may provide further advantages by also introducing reductions on criteria pollutants such as nitrogen oxides and soot. In this scenario, the interplay among the different energy paths must be understood and quantified to extract the full potential of the powertrain. One of the key devices in such powertrains is the battery, which involves different aspects regarding operation, safety, and degradation. Despite this complexity, most of the models still rely on resistance-capacity models to describe the battery operation. These models may lead to unpractical results since the current flow is governed by limiters rather than physical laws. Additionally, phenomena related with battery degradation, which decreases the nominal capacity and enhances the heat generation are also not considered in this approach.

In the challenge to reduce CO2, NOx and PM emissions, the application of natural gas or biogas in engines is a viable approach. In heavy duty and marine, either a conventional dual fuel (CDF), or a reactivity-controlled compression ignition (RCCI) approach is feasible on existing diesel engines. In both technologies a pilot diesel injection is used to ignite the premixed natural gas. However, the influence of injection-timing and -pressure on the start of combustion timing (SOC) is opposite between both modes. For a single operating point these relations can be explained by a detailed CFD simulation, but an intuitive overall explanation is lacking. This makes it difficult to incorporate both modes into one engine application, using a single controller. In an experimental campaign by the authors, on a medium speed engine, the lowest emissions were found to be very close to the SOC corresponding to the transition from RCCI to CDF.

Emissions regulations for engine and vehicle manufacturers are bound to become more limiting to prevent greenhouse gas emissions and mitigate the negative effects that potentiate global warming. To fulfill the energy demand necessary in the transportation sector for the short-to-medium term, a parallel optimization of the internal combustion engine, powertrain and fuels is necessary. The combination of novel combustion modes like the reactivity-controlled compression ignition (RCCI), that seeks the benefits of both compression ignition and spark ignition engines, with the so-called e-fuels, that reduce the carbon footprint from well-to-wheel, is worth exploring. This work investigates the potential of the RCCI concept using OMEx-gasoline to reduce the engine-out emissions beyond the current EURO VI legislation. To do so, eight representative operating conditions from several driving cycles for heavy-duty vehicles will be explored experimentally.