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In recent years, internal combustion engine using hydrogen gas, has attracted attention as one solution to the problem of global warming. Hydrogen gas has excellent combustion characteristics such as wide limits of inflammability and fast burning velocity because of high diffusion rate. Therefore, it has been made to obtain stable ignition and combustion by adding hydrogen with lean mixture in spark ignition engines using hydrocarbon fuels and to be attempted efficient operation by engine researchers. The purpose of this study is to reduce cooling loss in a gas engine using hydrogen gas and hydrogen Mixer system (Mixer) engine was remodeled to hydrogen Port Injection (PI) system engine. In this report, the heterogeneity of hydrogen mixture is clarified by comparing the combustion characteristics of the Mixer and the PI, and the effect of the difference in hydrogen supply systems on cooling loss is system. Ignition delay of the PI system is shorter than that of the Mixer.

Research on alternative fuels is necessary to reduce CO2 emissions. Hydrotreated Vegetable Oil (HVO) of light fuel physically improves spray and combustion characteristics. Fatty Acid Methyl Ester (FAME) is an oxygenated fuel and its combustion characteristics are chemically improved, although its spray characteristics such as penetration and atomization are deteriorated. The purpose of this study is to understand the effects of blending HVO, which has carbon neutral (CN) characteristics, with FAME, which also has CN characteristics, on spray and combustion characteristics, and to further improve emission such as THC and Smoke. This report presents the effect of the combination of improved spray characteristics and oxygenated fuel on emissions. Spray characteristics such as penetration, spray angle and spray volume were investigated by shadowgraph photography.

Bio-hydro fined diesel (BHD) oil is known as a second generation oil made from bio hydro finning process. Biodiesel in the first generation is made from transesterification process and it has several disadvantages such as high density and increased the viscosity that can cause operational problems because can make some deposits in the engine. To overcome this, the second generation process of biodiesel has been modified from the first generation oil. BHD is made from the waste cooking oil by using the hydro finning process without the trans-esterification process. The results of BHD oil has nearly the same with diesel oil. BHD oil has low viscosity and high oxidation stability. Therefore, BHD oil can be used in the diesel engine without making any modifications in the engine. In this study, the comparison of performance and emissions characteristics from BHD oil, waste cooking oil, and diesel oil are investigated.

We have proposed the application of EGR gas dissolved fuel which might improve spray atomization through effervescent atomization instead of high injection pressure. In this paper, the purpose is to evaluate the influence of the application of CO2 gas dissolved fuel on the combustion characteristics and emissions inside the single cylinder, direct injection diesel engine. As a result, by use of the fuel, smoke was reduced by about 50 to 70%. The amount of NOx was reduced at IMEP=0.3 MPa, but it was increased at IMEP=0.9 MPa.

The CO2 gas dissolved fuel for the diesel combustion is effective to reduce the NOx emissions to achieve the internal EGR (Exhaust Gas Recirculation) effect by fuel. This method has supplied EGR gas to the fuel side instead of supply EGR gas to the intake gas side. The fuel has followed specific characteristics for the diesel combustion. When the fuel is injected into the chamber in low pressure, this CO2 gas is separated from the fuel spray. The distribution characteristics of the spray are improved and the improvement of the thermal efficiency by reduction heat loss in the combustion chamber wall, and reduce soot emissions by the lean combustion is expected. Furthermore, this CO2 gas decreases the flame temperature. Further, it is anticipated to reduce NOx emissions by the spray internal EGR effect.

n-Tridecane is a low boiling point component of gas oil, and has been used as a single-component fuel for diesel spray and combustion experiments. However, no reduced chemical kinetic mechanisms for n-tridecane have been presented for three-dimensional modeling. A detailed mechanism developed by KUCRS (Knowledge-basing Utilities for Complex Reaction Systems), contains 1493 chemical species and 3641 reactions. Reaction paths during ignition process for n-tridecane in air computed using the detailed mechanism, were analyzed with the equivalence ratio of 0.75 and the initial temperatures of 650 K, 850 K, and 1100 K, which are located in the cool-flame dominant, negative-temperature coefficient, and blue-flame dominant regions, respectively.

Fuel design approach has been proposed as the control technique of spray and combustion processes in diesel engine to improve thermal efficiency and reduce exhaust emissions. In order to kwow if this approach is capable of controlling spray flame structure and interaction between the flame and a combustion chamber wall, the present study investigated ignition and flame characteristics of dual-component fuels, while varying mixing fraction, fuel temperature and ambient conditions. Those characteristics were evaluated through chemiluminescence photography and luminous flame photography. OH radical images and visible luminous flame images were analyzed to reveal flame shape aspect ratio and its fractal dimension.

Methyl butanoate (MB) and methyl decanoate (MD) are surrogates for biodiesel fuels. According to computational results with their detailed reaction mechanisms, MB and MD indicate shorter ignition delays than long alkanes such as n-heptane and n-dodecane do at an initial temperature over 1000 K. The high ignitability of these methyl esters was computationally analyzed by means of contribution matrices proposed by some of the authors. Due to the high acidity of an α-H atom in a carbonyl compound, hydroperoxy radicals are generated out of the equilibrium between forward and backward reactions of O₂ addition to methyl ester radicals by the internal transfer of an α-H atom in the initial stage of an ignition process. Some of the hydroperoxy methyl ester radicals can generate OH to activate initial reactions. MB has an efficient CH₃O formation path via CH₃ generated by the β-scission of an MB radical which has a radical site on the α-C atom to the carbonyl group.

A dual fuel operation with different reactivity fuels has the possibility of optimizing performance and emissions in premixed charge compression ignition engines by controlling the spatial concentration and distribution of both fuels. In the present study, n-heptane and i-octane were independently injected through two different injectors. In-cylinder pressure analysis and emissions measurement were performed in a compression ignition engine. Injection timings, fuel quantity ratio between the injections were changed for the two cases, in which one fuel was injected using a port fuel injection system while the other was directly injected into the cylinder, in order to drastically vary mixture distributions and ignition timings. In addition, an optical diagnostic was performed in a rapid compression and expansion machine to develop an understanding of the ignition processes of the two mixtures.

Authors propose the reformulation technique of physical properties of Biodiesel Fuel (BDF) by mixing lower boiling point fuels. In this study, waste cooking oil methyl ester (B100), which have been produced in Kyoto city, is used in behalf of BDF. N-Heptane (C7H16) and n-Dodecane (C12H26) are used as low and medium boiling point fuel. Mixed fuel of BDF with lower boiling point fuels have lighter quality as compared with neat BDF. This result is based on the chemical-thermo dynamical liquid-vapor equilibrium theory. This paper describes fundamental spray and combustion characteristics of mixed fuel of B100 with lower boiling point fuels as well as the reformulation technique. By mixing lower boiling point fuel, lighter quality fuels can be refined. Thus, mixed fuels have higher volatility and lower viscosity. Therefore, vaporization of mixed fuel spray is promoted and liquid phase penetration of mixed fuel shortens as compared with that of neat BDF.

It is thought that the synthetic gas, including hydrogen and carbon monoxide, has a potential to be an alternative fuel for internal combustion engines, because a heating value of the synthetic gas is higher than one of hydrogen or natural gas. A purpose of this study is to acquire stable auto-ignition and combustion of the synthetic gas which is supposed to be applied into a direct-injection compression ignition engine. In this study, the effects of ambient gas temperatures and oxygen concentrations on auto-ignition characteristics of the synthetic gas with changing percentage of hydrogen (H2) or carbon monoxide (CO) concentrations in the synthetic gas. An electronically-controlled, hydraulically-actuated gas injector was used to control a precise injection timing and period of gaseous fuels, and the experiments were conducted in an optically accessible, constant-volume combustion chamber under simulated quiescent diesel engine conditions.

This paper describes the results of on-board measurement of engine performance and emissions in diesel vehicle operated with bio-diesel fuels. Here, two waste-cooking oils were investigated. One fuel is a waste-cooking oil methyl esters. This fuel is actually applied to a garbage collection vehicle with DI diesel engine (B100) and the city bus (B20; 80% gas oil is mixed into B100 in volume) as an alternative fuel of gas oil in Kyoto City. Another one is a fuel with ozone treatment by removing impurities from raw waste-cooking oils. Here, in order to improve the fuel properties, kerosene is mixed 70% volume in this fuel. This mixed fuel (i-BDF) is applied into several tracks and buses in Wakayama City. Then, these 3 bio-diesel fuels were applied to the on-board experiments and the results were compared with gas oil operation case.

The Flame structure and combustion characteristics for two waste-cooking oils were investigated in detail. One fuel is the waste-cooking oil methyl esters. This fuel is actually applied to the garbage collection vehicle with DI diesel engine (B100) and the city bus (B20; 80% gas oil is mixed into B100 in volume) as an alternative fuel of gas oil in Kyoto City. Another one is the fuel with ozone treatment by removing impurities from raw waste-cooking oils. Here, in order to improve the fuel properties, kerosene is mixed 70% volume in this fuel. This mixed fuel (i-BDF) is applied into several tracks and buses in Wakayama City. In the experiments, the used fuels were gas oil, i-BDF, B100 and B20. Spray characteristics and basic combustion properties were measured inside a rapid compression and an expansion machine (RCEM).

Flash-boiling occurs when a fuel is injected to a combustion chamber where the ambient pressure is lower than the saturation pressure of the fuel. It has been known that flashing is a favorable mechanism for atomizing liquid fuels. On the other hand, alternative fuels, such as gaseous fuels and oxygenated fuels, are used to achieve low exhaust emissions in recent years. In general, most of these alternative fuels have high volatility and flash-boiling takes place easily in fuel spray, when they are injected into the combustion chamber of an internal combustion engine under high pressure. In addition, fuel design concept the multicomponent fuel with high and low volatility fuels has been proposed in the previous study in order to control the spray and combustion processes in internal combustion engine. It is found that the multicomponent fuel produce flash-boiling with an increase in the initial fuel temperature.

This work presents the ignition delay time characteristics of oxygenated fuel sprays under simulated diesel engine conditions. A constant volume combustion vessel is used for the experiments. The fuels used in the experiments were three oxygenated fuels: diethylene glycol dibutyl ether, diethylene glycol diethyl ether, and diethylene glycol dimethyl ether. JIS 2nd class gas oil was used as the reference fuel. The ambient gas temperature and oxygen concentration were ranging from 700 to 1100K and from 21 to 9%, respectively. The results show that the ignition delay of each oxygenated fuel tested in this experiments exhibits shorter than that of gas oil fuel for the wide range of ambient gas conditions. Also, NTC (negative temperature coefficient) behavior which appears under shock tube experiment for homogenous fuel-air mixture was observed on low ambient gas oxygen concentration for each fuel. And at the condition, the ignition behavior exhibits two-stage phase.

The experiment-based droplet impinging breakup model was applied to a fan shaped spray and the impinging behavior was analyzed quantitatively. Evaluation of the quantitative results with validation tests verified the following. The model enables prediction of fan shaped spray thickness after impingement caused by the breakup of fuel droplets, which could not be represented with the Wall-Jet model, widely used at present. Fuel film movement on a wall is negligible when the injection pressure of the fan shaped spray is high and the spray travelling length is not too short. The proposed heat transfer coefficient between fuel film and the wall is too small to represent the vaporizing rate of the fuel film.

In this study, characteristics of the development and auto-ignition/combustion of hydrogen jets were investigated in a constant-volume vessel. The authors focused on the effects of the jet developing process and thermodynamic states of the ambient gas on auto-ignition delays of hydrogen jets. The results show that the ambient gas temperature and nozzle-hole diameter are significantly effective parameters. By contrast, it is clarified that the ambient gas oxygen concentration has a weak effect on the auto-ignition/combustion of hydrogen jets. Consequently, it is supposed that the mixture formation process is capable of improving the auto-ignition/combustion of hydrogen jets.

In an SI engine with direct injection of gasoline (DGI), many small droplets disperse in premixed gas in the cylinder. In a CI engine, diesel spray is injected a cylinder, thus, the situation at the spray periphery is almost the same as that of DGI SI engine. From the standpoint it is useful for understanding the combustion phenomena in both engines to experiment the combined combustion of premixed gas where many small droplets exist. This paper describes this kind of combustion and it seems to be able to apply the results to the simulation of combustion in these engines.

Soot formation process inside the combustion chamber of an DI diesel engine is focused as a phenomenological basic scheme by using several optical diagnostics technique for the improvement of diesel exhaust emission. We have conducted the series of optical measurement research for the clarification of combustion field in an DI diesel engine. Then, this paper is a kind of review by adding the fuel vapor properties and particle image velocimetry (PIV) analysis with focusing the soot formation process. The experiments were carried out in a small sized high-speed DI diesel engine installed with an optical access view. The spray characteristics and its flow field in 2-D field were measured by laser sheet scattering (LIS) method and PIV scheme.

A transient gas jet and its flame are the most fundamental phenomena of a transient spray and its flame breaking out in a CI engine and an SI engine with the direct injection system. In the case of CNG and LNG engines, the fuel itself is just gaseous state. The 2-LIF technique was applied to the transient gas jet to obtain the mixing process between the surroundings and it, and the simultaneous application of LII and LIS techniques were applied to the transient gas jet flame to obtain the soot formation process.