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This paper examines the issues concerning particulate matter (PM) emissions measurement at the 3 mg/mi level proposed as the future LEV III standard. These issues are general in nature, but are exacerbated at the low levels contemplated for upcoming emissions standards. They are discussed in the context of gasoline direct injection (GDI) engines, where they can have an important impact on the continued development of this technology for improved fuel economy. GDI particulate emissions, just as engine-out diesel PM, contain a high fraction of soot. But the total PM mass is significantly lower than from diesel engines, and there can be significant variations in emissions rate and apparent PM composition between cold-start and running emissions. PM emissions levels depend on sampling method and location. As a result, there can be substantial differences in PM sampled and diluted directly at the exhaust pipe, as opposed to measurements from a dilution tunnel.

Concentrations of individual species in the engine-out exhaust gas from a gasoline-fueled (101.5 or 91.5 RON), direct-injection, compression-ignition (HCCI) engine have been measured by gas chromatography over the A/F range 50 to 230 for both stratified and nearly homogeneous fuel-air mixtures. The species identified include hydrocarbons, oxygenated organic species, CO, and CO2. A single-cylinder HCCI engine (CR = 15.5) with heated intake charge was used. Measurements of the mass and size distribution of particulate emissions were also performed. The 101.5 RON fuel consisted primarily of five species, simplifying interpretation of the exhaust species data: iso-pentane (24%), iso-octane (22%), toluene (17%), xylenes (10%), and trimethylbenzenes (9%).

The effect of fuel preparation on time-resolved, engine-out hydrocarbon (HC) emissions over a Federal Test Procedure cycle [FTP (75CVS)] for a ULEV vehicle equipped with a 6 cylinder engine has been investigated. Using a single-cone injector, the HC mole fraction in Bag 1 increased by a factor of 3-4 during each of the three accelerations in the first 100 sec after start. No such increases were observed in Bag 3 when the engine was fully warm. The increases during accelerations in Bag 1 were reduced by a factor of 3 when using a Dual-cone fuel injector as a drop-in substitute. The total, tailpipe FTP (75CVS) mass emissions were 25% smaller when using the Dual-cone injector. These results demonstrate that fuel preparation can affect HC emissions from a vehicle very significantly during cold start as has been deduced previously during cold-start tests using a dynamometer-controlled engine.

Particulate emissions are reported for a 0.31 L single cylinder engine fitted with an air forced direct injection system. Trends in number, size, and mass of engine out particle emissions are examined as a function of injection timing, spark timing, and EGR. Injection timing determines to a large degree the nature of the combustion, with early injection leading to homogeneous like combustion and late injection producing stratified charge combustion. As fuel injection is retarded, at a fixed lean air to fuel ratio, PM emissions decline to a minimum at an injection time well within the compression stroke, after which they rapidly increase. In the heavily stratified regime, the PM increase can be attributed to a growing number of rich zones that occur in the progressively more inhomogeneous fuel mixture. At fixed injection timing, advancing the spark causes a general increase in particle emissions.

This paper explores the extent to which standard dilution tunnel measurements of motor vehicle exhaust particulate matter modify particle number and size. Steady state size distributions made directly at the tailpipe, using an ejector pump, are compared to dilution tunnel measurements for three configurations of transfer hose used to transport exhaust from the vehicle tailpipe to the dilution tunnel. For gasoline vehicles run at a steady 50 - 70 mph, ejector pump and dilution tunnel measurements give consistent results of particle size and number when using an uninsulated stainless steel transfer hose. Both methods show particles in the 10 - 100 nm range at tailpipe concentrations of the order of 104 particles/cm3.

A single-cylinder, spark-ignited engine was run on a certification test gasoline to saturate the oil in the sump with fuel through exposure to blow-by gas. The sump volume was large relative to production engines making its absorption-desorption time constant long relative to the experimental time. The engine was motored at 1500 RPM, 90° C coolant and oil temperature, and 0.43 bar MAP without fuel flow. Exhaust HC concentrations were measured by on-line FID and GC analysis. The total motoring HC emissions were 150 ppmC1; the HC species distribution was heavily weighted to the low-volatility components in the gasoline. No high volatility components were visible. The engine was then fired on isooctane fuel at the above conditions, producing a total engine-out HC emission of 2300 ppmC1 for Φ = 1.0 and MBT spark timing.

Absorption of fuel in engine oil layers has been shown to be a possible source of hydrocarbon (HC) emissions from spark-ignited engines. However, the magnitude of this source in a normally operating engine has not been determined unambiguously. In these experiments, a series of n-alkanes of widely different solubility (n-hexane through undecane) was added (1.5 wt % each) to a Base gasoline (CA Phase 2). Steady-state experiments were carried out at two coolant temperatures (339 and 380 K) using a single-cylinder engine with the combustion chamber of a production V-8. Both total and speciated engine-out HC emissions were measured. The emissions indices of the heavier dopants did not increase relative to hexane at either coolant temperature.

The effect of engine operating parameters (speed, spark timing, and fuel-air equivalence ratio [Φ]) on hydrocarbon (HC) oxidation within the cylinder and exhaust system is examined using propane or isooctane fuel. Quench gas (CO2) is introduced at two locations in the exhaust system (exhaust valve or port exit) to stop the oxidation process. Increasing the speed from 1500 to 2500 RPM at MBT spark timing decreases the total, cylinder-exit HC emissions by ∼50% while oxidation in the exhaust system remains at 40% for both fuels. For propane fuel at 1500 rpm, increasing Φ from 0.9 (fuel lean) to 1.1 (fuel rich) reduces oxidation in the exhaust system from 42% to 26%; at 2500 RPM, exhaust system oxidation decreases from 40% to approximately 0% for Φ = 0.9 and 1.1, respectively. Retarded spark increases oxidation in the cylinder and exhaust system for both fuels. Decreases in total HC emissions are accompanied by increased olefinic content and atmospheric reactivity.

Modern four-valve engines are running at ever higher compression ratios in order to improve fuel efficiency. Hotter cylinder bores also can produce increased fuel economy by decreasing friction due to less viscous oil layers. In this study changes in compression ratio and coolant temperature were investigated to quantify their effect on exhaust emissions. Tests were run on a single cylinder research engine with a port-deactivated 4-valve combustion chamber. Two compression ratios (9.15:1 and 10.0:1) were studied at three air/fuel ratios (12.5, 14.6 and 16.5) at a part load condition (1500 rpm, 3.8 bar IMEP). The effect of coolant temperature (66 °C and 108°C) was studied at the higher compression ratio. The exhaust was sampled and analyzed for both total and speciated hydrocarbons. The speciation analysis provided concentration data for hydrocarbons present in the exhaust containing twelve or fewer carbon atoms.

For several years, a single-cylinder, spark-ignited engine without catalyst has been operated at Ford on single-component fuels that are constituents of gasoline as well as on simple fuel mixtures. This paper presents a review of these experiments as well as others pertinent to understanding hydrocarbon emissions. The engine was run at four steady-state conditions which are typical of normal operation. The fuel structure and the engine operating conditions affected both the total HC emissions and the reactivity of these emissions for forming photochemical smog in the atmosphere. These experiments identified major precursor species of the toxic HC emissions benzene and 1,3-butadiene to be alkylated benzenes and either straight chain terminal olefins or cyclic alkanes, respectively. In new data presented, the primary exhaust hydrocarbon species from MTBE combustion is identified as isobutene.

The requirement of reducing HC emissions during cold start and improving transient performance has prompted a study of the fuel injection process. Port-fuel-injection with the Intake-valve open using small droplets is a potentially feasible option to achieve the goals. To gain a better understanding of the injection process, the effects of droplet size, injection timing, and coolant temperature on the total and speciated HC emissions were tested In a Single-cylinder engine. It was found that droplet size plays an important role in the total HC emission increase during open-valve injection, especially with cold operation. Large droplets (300 μm SMD) produced a substantial HC increase while small droplets (14 μm SMD) produced no observable increase. Increase In the total HC emissions was always accompanied by an increase in the heavy fuel components in the exhaust gases.