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Technical Paper

Update on Gasoline Fuel Property and Gasoline Additives Impacts on Stochastic Preignition with Review of Global Market Gasoline Quality

2022-08-30
2022-01-1071
Stochastic Preignition (SPI) is an abnormal combustion phenomenon for internal combustion engines (ICE), which has been a significant impact to automotive companies developing high efficiency, turbocharged, direct fuel injection, spark ignited engines. It is becoming clearer what fuel properties are related to the cause of SPI, whether directly with fuel preparation in the cylinder, or mechanisms related to the deposit build-up which contributes to initial and follow-on SPI events. The purpose of this paper is to provide a summary of global market gasoline fuel properties with special attention given to properties and specific compounds from the fuel and fuel additives that can contribute to SPI and the deposit build-up in engines. Based on a review of the global fuel quality, it appears that the fuel quality has not caught up to meet the technology requirements for fuel economy from modern technology engines.
Technical Paper

Impact of Fuel Detergent Type and Concentration on the Rate and Severity of Stochastic Preignition in a Turbocharged Spark Ignition Direct Injection Gasoline Engine

2021-04-06
2021-01-0490
Stochastic Preignition (SPI) is an abnormal combustion event that occurs in a turbocharged engine and can lead to the loss in fuel economy and engine hardware damage, and in turn result in customer dissatisfaction. It is a significant limiting factor on the use and continued downsizing of turbocharged spark ignited direct injection (SIDI) gasoline engines. Understanding and mitigating all the factors that cause and influence the rate and severity of SPI occurrence are of critical importance to the engine’s continued use and fuel economy improvements for future designs. Previous studies have shown that the heavy molecular weight components of the fuel formulations are one factor that influences the rate of SPI from a turbocharged SIDI gasoline engine. All the previous studies have involved analyzing the fuel’s petroleum hydrocarbon chemistry, but not specifically the additives that are put in the fuel to protect and clean the internal components over the life of the engine.
Technical Paper

Global Market Gasoline Quality Review: Five Year Trends in Particulate Emission Indices

2021-04-06
2021-01-0623
A gasoline’s chemical composition impacts a vehicle’s sooting tendency and therefore has been the subject of numerous emissions studies. From these studies, several mathematical correlation equations have been developed to predict a gasoline’s sooting tendency in modern spark-ignited internal combustion engine vehicles. This paper reviews the recently developed predictive tool methods and summarizes five years of global market fuel survey data to characterize gasoline sooting tendency trends around the world. Additionally, the paper will evaluate and suggest changes to the predictive methods to improve emissions correlations.
Journal Article

Fuel Effects on the Propensity to Establish Propagating Flames at SPI-Relevant Engine Conditions

2021-04-06
2021-01-0488
In order to further understand the sequence of events leading to stochastic preignition in a spark-ignition engine, a methodology previously developed by the authors was used to evaluate the propensity of a wide range of fuels to establishing propagating flames under conditions representative of those at which stochastic preignition (SPI) occurs. The fuel matrix included single component hydrocarbons, binary mixtures, and real fuel blends. The propensity of each fuel to establish a flame was correlated to multiple fuel properties and shown to exhibit consistent blending behaviors. No single parameter strongly predicted a fuel’s propensity to establish a flame, while multiple reactivity-based parameters exhibited moderate correlation. A two-stage model of the flame establishment process was developed to interpret and explain these results.
Technical Paper

Fuel Properties and Their Impact on Stochastic Pre-Ignition Occurrence and Mega-Knock in Turbocharged Direct-Injection Gasoline Engines

2020-04-14
2020-01-0614
Stochastic Pre-Ignition (SPI) or Low Speed Pre-Ignition (LSPI) is an abnormal combustion event that can occur during the operation of modern, highly boosted direct-injection gasoline engines. This abnormal combustion event is characterized by an undesired and early start of combustion that is not initiated by the spark plug. Early SPI events can subsequently lead to violent auto-ignitions that are referred to as Mega- or Super-Knock in literature and have the potential to severely damage engines in the field. Numerous studies to analyze impact factors on SPI occurrence and severity have been conducted in recent years. While initial studies have focused strongly on engine oil formulation, calibration and engine design and their respective impact on SPI initiation, the impact of physical and chemical properties of the fuel have also become of interest in recent years.
Technical Paper

Impact of Fuel Octane Quality on Various Advanced Vehicle Technologies

2020-04-14
2020-01-0619
Fuel with higher octane content is playing a key role in optimising engine performance by allowing a more optimal spark timing which leads to increased engine efficiency and lower CO2 emissions. In a previous study the impact of octane was investigated with a fleet of 20 vehicles using market representative fuels, varying from RON 91 to 100. The resulting data showed a clear performance and acceleration benefit when higher RON fuel was used. In this follow-up study 10 more vehicles were added to the database. The vehicle fleet was extended to be more representative of Asian markets, thus broadening the geographical relevance of the database, as well as adding vehicles with newer technologies such as boosted down-sized direct injection engines, or higher compression ratio engines. Eight different fuel combinations varying in RON were tested, representing standard gasoline and premium gasoline in different markets around the world.
Journal Article

Detailed Analyses and Correlation of Fuel Effects on Stochastic Preignition

2020-04-14
2020-01-0612
Stochastic or Low-Speed Preignition (SPI or LSPI) is an undesirable abnormal combustion phenomenon encountered in spark-ignition engines. It is characterized by very early heat release and high cylinder pressure and can cause knock, noise and ultimately engine damage. Much of the focus on mitigating SPI has been directed towards the engine oil formulation, leading to the emergence of the Sequence IX test and second-generation GM dexos® oil requirements. Engine design, calibration and fuels also contribute to the prevalence of SPI. As part of a recently completed research consortium, a series of engine tests were completed to determine the impact of fuel composition on SPI frequency. The fuel blends had varying levels of paraffins, olefins, aromatics and ethanol.
Technical Paper

Analysis of the Impact of Production Lubricant Composition and Fuel Dilution on Stochastic Pre-Ignition in Turbocharged, Direct-Injection Gasoline Engines

2019-04-02
2019-01-0256
The occurrence of abnormal combustion events leading to high peak pressures and severe knock can be considered to be one of the main challenges for modern turbocharged, direct-injected gasoline engines. These abnormal combustion events have been referred to as Stochastic Pre-Ignition (SPI) or Low-Speed Pre-Ignition (LSPI). The events are characterized by an undesired, early start of combustion of the cylinder charge which occurs before or in parallel to the intended flame kernel development from the spark plug. Early SPI events can subsequently lead to violent auto-ignitions that are often referred to as Mega- or Super-Knock. These heavy knock events lead to strong pressure oscillations which can destroy production engines within a few occurrences. SPI occurs mainly at low engine speed and high engine load, thus limiting the engine operating area that is in particular important to achieve good drivability in downsized engines.
Journal Article

Fuel & Lubricant Effects on Stochastic Preignition

2019-01-15
2019-01-0038
In this multi-phase study, fuel and lubricant effects on stochastic preignition (SPI) were examined. First, the behavior of fuels for which SPI data had previously been collected were characterized in terms of their combustion and emissions behavior, and correlations between these characteristics and their SPI behavior were examined. Second, new SPI data was collected for a matrix of fuels that was constructed to test and confirm hypotheses that resulted from interpretation of the earlier data in the study and from data in open literature. Specifically, the extent to which the presence of heavy components in the fuel affected SPI propensity, and the extent to which flame initiation propensity affected SPI propensity, were examined. Finally, the interaction of fuels with lubricants expected to exhibit a range of SPI propensities was examined.
Technical Paper

Investigation of the Impact of Fuel Properties on Particulate Number Emission of a Modern Gasoline Direct Injection Engine

2018-04-03
2018-01-0358
Gasoline Direct Injection (GDI) has become the preferred technology for spark-ignition engines resulting in greater specific power output and lower fuel consumption, and consequently reduction in CO2 emission. However, GDI engines face a substantial challenge in meeting new and future emission limits, especially the stringent particle number (PN) emissions recently introduced in Europe and China. Studies have shown that the fuel used by a vehicle has a significant impact on engine out emissions. In this study, nine fuels with varying chemical composition and physical properties were tested on a modern turbo-charged side-mounted GDI engine with design changes to reduce particulate emissions. The fuels tested included four fuels meeting US certification requirements; two fuels meeting European certification requirements; and one fuel meeting China 6 certification requirements being proposed at the time of this work.
Technical Paper

A Robust Preignition Rating Methodology: Evaluating the Propensity to Establish Propagating Flames under Real Engine Conditions

2017-10-08
2017-01-2241
In this work, an experimental and analysis methodology was developed to evaluate the preignition propensity of fuels and engine operating conditions in an SI engine. A heated glow plug was introduced into the combustion chamber to induce early propagating flames. As the temperature of the glowplug varied, both the fraction of cycles experiencing these early flames and the phasing of this combustion in the engine cycle varied. A statistical methodology for assigning a single-value to this complex behavior was developed and found to have very good repeatability. The effects of engine operating conditions and fuels were evaluated using this methodology. While this study is not directly studying the so-called stochastic preignition or low-speed preignition problem, it studies one aspect of that problem in a very controlled manner.
Technical Paper

China Market Gasoline Review Using Fuel Particulate Emission Correlation Indices

2017-10-08
2017-01-2401
The impact of gasoline composition on vehicle particulate emissions response has been widely investigated and documented. Correlation equations between fuel composition and particulate emissions have also been documented, e.g. Particulate Matter Index (PMI) and Particulate Evaluation Index (PEI). Vehicle PM/PN emissions correlate very well with these indices. In a previous paper, global assessment with PEI on fuel sooting tendency was presented [1]. This paper will continue the previous theme by the authors, and cover China gasoline in more detail. With air pollution an increasing concern, along with more stringent emission requirements in China, both OEMs and oil industries are facing new challenges. Emissions controls require a systematic approach on both fuels and vehicles. Chinese production vehicle particulate emissions for a range of PEI fuels are also presented.
Journal Article

Influence of Ethanol Blends on Low Speed Pre-Ignition in Turbocharged, Direct-Injection Gasoline Engines

2017-03-28
2017-01-0687
Modern combustion engines must meet increasingly higher requirements concerning emission standards, fuel economy, performance characteristics and comfort. Especially fuel consumption and the related CO2 emissions were moved into public focus within the last years. One possibility to meet those requirements is downsizing. Engine downsizing is intended to achieve a reduction of fuel consumption through measures that allow reducing displacement while simultaneously keeping or increasing power and torque output. However, to reach that goal, downsized engines need high brake mean effective pressure levels which are well in excess of 20bar. When targeting these high output levels at low engine speeds, undesired combustion events with high cylinder peak pressures can occur that can severely damage the engine. These phenomena, typically called low speed pre-ignition (LSPI), set currently an undesired limit to downsizing.
Technical Paper

Global Market Gasoline Range Fuel Review using Fuel Particulate Emission Correlation Indices

2016-10-17
2016-01-2251
The Particulate Matter Index (PMI) is a helpful tool which provides an indication of a fuel’s sooting tendency. Currently, the index is being used by various laboratories and OEMs as a metric to understand the gasoline range fuels impact on both sooting found on engine hardware and vehicle out emissions. This paper will explore a new method that could be used to give indication of the sooting tendency of the gasoline range fuels, with good correlation agreement to PMI. In addition, the paper will cover a global assessment of a gasoline range fuel’s sooting tendency based on the PMI number and the proposed method. Areas around the globe where market gasoline range fuels are of concern will be highlighted, in coordination with the new emissions regulations. Vehicle PM/PN data will also be presented that shows correlations of the indices to the vehicle response.
Technical Paper

Impact of Fuel Octane Rating and Aromatic Content on Stochastic Pre-Ignition

2016-04-05
2016-01-0721
The effects of aromatic content and octane rating of gasoline fuels on stochastic pre-ignition (SPI) behaviors were investigated at typical operating conditions using a modern 2.0 L turbocharged engine. In-cylinder pressure time history measurements made during a speed-load test sequence designed to stimulate SPI were used to determine both the frequency of SPI occurrence and the in-cylinder peak pressure during such events. Six fuels were tested with varying levels of aromatic content (15 - 35% by vol.) and two octane rating levels (∼88 & 94 anti-knock index). The engine was operated using a production-intent calibration with equivalence ratio near one. Pressure and temperature in the intake manifold were held constant near two bar and 35°C respectively. Significant SPI activity was observed, with abnormal event frequencies up to ∼1 SPI event per 1,000 engine cycles and in-cylinder peak pressures up to ∼200 bar.
Technical Paper

Effects of Gasoline and Ethanol Fuel Corrosion Inhibitors and Fuel Detergents on Powertrain Intake Valve Deposits

2014-04-01
2014-01-1383
Corrosion inhibitors (CIs) have been used for years to protect the supply and distribution systems used for transportation of fuel from refineries. They are also used to buffer the potential organic acids present in an ethanol blended fuel to enhance storage stability. The impact of the types of inhibitors on spark-ignition engine fuel systems, specifically intake valve deposits, is known and presented in open literature. However, the relationship of the corrosion inhibitors to the powertrain intake valve deposit performance is not understood. This paper has two purposes: to present and discuss a survey of corrosion inhibitors and how they vary in concentration in the final blended fuel, specifically E85 (Ethanol Fuel Blends); and to show how variation in concentration of components of CIs and detergents impact intake valve deposit formation.
Journal Article

Fuel Octane and Volatility Effects on the Stochastic Pre-Ignition Behavior of a 2.0L Gasoline Turbocharged DI Engine

2014-04-01
2014-01-1226
Classic, hot-spot induced pre-ignition is a phenomenon that has been observed in gasoline spark ignited engines over the past 60-70 years. With the development of turbocharged, direct-injected (DI) gasoline engines, a new pre-ignition phenomenon occurring at low engine speeds and high loads has been encountered. Termed Stochastic Pre-ignition (SPI), it has become a significant issue to address in allowing for the full potential of gasoline turbo DI technology to improve powertrain efficiency. Many researchers are studying all aspects of the causes of Stochastic Pre-ignition, including causes by oil, fuel and engine hardware systems. The focus of this specific research was to study the relationship of fuel octane and volatility to Stochastic Pre-ignition behavior utilizing a GM 2.0L Gasoline Turbocharged DI engine (LHU).
Journal Article

Effects of Gasoline and Ethanol Fuel Corrosion Inhibitors on Powertrain Intake Valve Deposits

2013-04-08
2013-01-0893
Corrosion inhibitors (CIs) have been used for years to protect the supply and distribution hardware used for transportation of fuel from refineries and to buffer the potential organic acids present in an ethanol blended fuel to enhance storage stability. The impact of these inhibitors on spark-ignition engine fuel systems, specifically intake valve deposits, is known and presented in open literature. However, the relationship of the corrosion inhibitors to the powertrain intake valve deposit performance is not understood. This paper has two purposes: to present and discuss a second market place survey of corrosion inhibitors and how they vary in concentration in the final blended fuel, specifically E85 (Ethanol Fuel Blends); and, to show how the variation in the concentrations of the components of the CIs impacts the operation and performance of vehicles, specifically, the effects on intake valve deposit formation.
Technical Paper

Investigation Regarding the Influence of a Catalytic Combustion Chamber Coating on Gasoline Combustion Characteristics, Emission Formation and Engine Efficiency

2012-04-16
2012-01-1097
Over the past few years, both global warming and rising oil prices led to a significantly increased demand for low fuel consumption in passenger cars. However, the necessity to also meet the limits of today's and future emission regulations makes it more and more difficult to maintain a high engine efficiency without the use of an expensive external exhaust gas after-treatment system. Therefore, new technologies that simultaneously prevent emission formation and reduce fuel consumption inside the internal combustion engine during the combustion process itself are of highest interest. This paper analyzes the influence of a catalytic coating of the combustion chamber on combustion, emission formation and fuel consumption. For this purpose, test runs with a production 2.0-liter, 4-cylinder, 4-valve, double overhead camshaft (DOHC), port fuel injection (PFI) gasoline engine were performed.
Technical Paper

Systematic Approach to Analyze and Characterize Pre-ignition Events in Turbocharged Direct-injected Gasoline Engines

2011-04-12
2011-01-0343
Downsized direct-injected boosted gasoline engines with high specific power and torque output are leading the way to reduce fuel consumption in passenger car vehicles while maintaining the same performance when compared to applications with larger naturally aspirated engines. These downsized engines reach brake mean effective pressure levels which are in excess of 20 bar. When targeting high output levels at low engine speeds, undesired combustion events called pre-ignition can occur. These pre-ignition events are typically accompanied by very high cylinder peak pressures which can lead to severe damage if the engine is not designed to withstand these high cylinder pressures. Although these pre-ignition events have been reported by numerous other authors, it seems that their occurrence is rather erratic which makes it difficult to investigate or reliably exclude them.
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