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Maintaining low NOx emissions over the operating range of diesel engines continues to be a major issue. However, optical measurements of nitric oxide (NO) are lacking particularly in the core of diesel jets, i.e. in the region of premixed combustion close to the spray axis. This is basically caused by severe attenuation of both the laser light and fluorescent emission in laser-induced fluorescence (LIF) applications. Light extinction is reduced by keeping absorption path lengths relatively short in this work, by investigating diesel jets in a combustion vessel instead of an engine. Furthermore, the NO-detection threshold is improved by conducting 1-d line measurements instead of 2-d imaging. The NO-LIF data are corrected for light attenuation by combined LIF and spontaneous Raman scattering. The quantified maximum light attenuation is significantly lower than in comparable previous works, and its wavelength dependence is surprisingly weak.

With increasing interest in new biofuel candidates, 1-octanol and di-n-butylether (DNBE) were presented in recent studies. Although these molecular species are isomers, their properties are substantially different. In contrast to DNBE, 1-octanol is almost a gasoline-type fuel in terms of its auto-ignition quality. Thus, there are problems associated with engine start-up for neat 1-octanol. In order to find a suitable glow-plug position, mixture formation is studied in the cylinder under almost idle operating conditions in the present work. This is conducted by planar laser-induced fluorescence in a high-speed direct-injection optical diesel engine. The investigated C8-oxygenates are also significantly different in terms of their evaporation characteristics. Thus, in-cylinder mixture formation of these two species is compared in this work, allowing conclusions on combustion behavior and exhaust emissions.

Pilot injection (PI) during the negative-valve-overlap (NVO) period is one method to improve control of combustion in gasoline controlled auto-ignition engines. This is generally attributed to both chemical and thermal effects. However, there are little experimental data on active species formed by the combusting PI and their effect on main combustion in real engines. Thus, it is the objective of the current study to apply and assess optical in-cylinder diagnostics for these species. Firstly, the occurrence and nature of combustion during the NVO period is investigated by spectrally-resolved multi-species flame luminescence measurements. OH*, CH*, HCO*, CO-continuum chemiluminescence, and soot luminosity are recorded. Secondly, spectrally-, spatially-, and cycle-resolved laser-induced fluorescence measurements of formaldehyde are conducted. It is attempted to find a cycle-resolved measure of the chemical effect of PI.

Multiple-injection strategies are widely used in DI diesel engines. However, the interaction of the injection pulses is not yet fully understood. In this work, a split injection into a combustion vessel is studied by multiple optical imaging diagnostics. The vessel provides quiescent high-temperature, high-pressure ambient conditions. A common-rail injector which is equipped with a three-hole nozzle is used. The spray is visualized by Mie scattering. First and second stage of ignition are probed by formaldehyde laser-induced fluorescence (LIF) and OH* chemiluminescence imaging, respectively. In addition formation of soot is characterized by both laser-induced incandescence (LII) and natural luminosity imaging, showing that low-sooting conditions are established. These qualitative diagnostics yield ensemble-averaged, two-dimensional, time-resolved distributions of the corresponding quantities.

Tailor-made multi-component fuels are currently being developed for advanced Diesel engines. Accordingly, there is renewed interest in the detailed evaporation characteristics of such multi-component fuels, in particular because soot formation in reacting Diesel sprays generally depends on the mixture formation upstream of the lift-off location. It is also well established that fuel components with different volatility are generally not coevaporative due to fractional distillation in the mixture formation process of spark-ignition engines, but it is not clear if this holds for Diesel-like sprays, in which evaporation and mixing are expected to be more rapid. Unfortunately, little work has been done in this field, and some of the previous results appear to be contradictory. This paper presents a new laser diagnostic approach, which yields the vapor-phase concentrations of two fuel components simultaneously in Diesel-like sprays.

The finite nature and instability of fossil fuel supply has led to an increasing and enduring investigation demand of alternative and regenerative fuels. An investigation program is carried out to explore the potential of tailor made fuels to reduce engine-out emissions while maintaining engine efficiency and an acceptable noise level. In this paper, fundamental results of the Diesel engine relevant combustion are presented. To enable optimum engine performance a range of different reference fuels have been investigated. The fundamental effects of different physical and chemical properties on emission formation and engine performance are investigated using a thermodynamic diesel single cylinder research engine and an optically-accessible combustion vessel. Depending on the chain length and molecular structure, fuel compounds vary in cetane number, boiling temperature etc. Therefore, different hydrocarbons including n-heptane, n-dodecane, and l-decanol were investigated.

In view of limited crude oil resources, alternative fuels for internal combustion engines are currently being intensively researched. Synthetic fuels from natural gas offer a promising interim option before the development of CO2-neutral fuels. Up to a certain degree, these fuels can be tailored to the demands of modern engines, thus allowing a concurrent optimization of both the engine and the fuel. This paper summarizes investigations of a Gas-To-Liquid (GTL) diesel fuel in a modern, post-EURO 4 compliant diesel engine. The focus of the investigations was on power output, emissions performance and fuel economy, as well as acoustic performance, in comparison to a commercial EU diesel fuel. The engine investigations were accompanied by injection laboratory studies in order to assist in the performance analyses.