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The increasing need to reduce greenhouse gas emissions and shift away from fossil fuels has raised an interest for methanol. Methanol can be produced from renewable sources and can drastically lower soot emissions from compression ignition engines (CI). As a result, research and development efforts have intensified focusing on the use of methanol as a replacement for diesel in CI engines. The issue with methanol lies in the fact that methanol is challenging to ignite through compression alone, particularly at low-load and cold starts conditions. This challenge arises from methanol's high octane number, low heating value, and high heat of vaporization, all of which collectively demand a substantial amount of heat for methanol to ignite through compression.

The growing demand to lower greenhouse gas emissions and transition from fossil fuels, has put methanol in the spotlight. Methanol can be produced from renewable sources and has the property of burning almost soot-free in compression ignition (CI) engines. Consequently, there has been a notable increase in research and development activities directed towards exploring methanol as a viable substitute for diesel fuel in CI engines. The challenge with methanol lies in the fact that it is difficult to ignite through compression alone, particularly in low-load and cold start conditions. This difficulty arises from methanol's high octane number, relatively low heating value, and high heat of vaporization, collectively demanding a considerable amount of heat for methanol to ignite through compression. Previous studies have addressed the use of a pilot injection in conjunction with a larger main injection to lower the required intake air temperature for methanol to combust at low loads.

The worldwide adoption of renewable energy mandates, together with the widespread utilization of biofuels has created a sharp increase in the production of biodiesel (fatty acid alkyl esters). As a consequence, the production of glycerol, the main by-product of the transesterification of fatty acids, has increased accordingly, which has led to an oversupply of that compound on the markets. Therefore, in order to increase the sustainability of the biodiesel industry, alternative uses for glycerol need to be explored and the production of fuel additives is a good example of the so-called glycerol valorization. The goal of this study is therefore to evaluate the suitability of a number of glycerol-derived compounds as diesel fuel additives. Moreover, this work concerns the assessment of low-concentration blends of those glycerol derivatives with diesel fuel, which are more likely to conform to the existing fuel standards and be used in unmodified engines.

The forthcoming introduction of the EURO VII regulation requires urgent strategies and solutions for the reduction of sub-23 nm particle emissions. Although they have been historically considered as particulate matter-free, the high interest for Natural Gas (NG) Heavy-Duty engines in the transport sector, demands their compliance with the new proposed regulations. In order to obtain high conversion of gas pollutants and a strong abatement of the emitted particles, the use of Particle Filters in NG aftertreatment (CPF) in conjunction with the Three-Way Catalyst (TWC) may represent an attractive and feasible solution. Performances of a cordierite filter were explored through an extensive experimental campaign both in Steady-State conditions and during transient engine maneuvers that involved a whole analysis of the emitted particles in terms of number and mass.

Hydrogen Internal Combustion Engines (H2-ICEs) are subject to increased attention thanks to their extremely low criteria pollutant emission and near-zero CO2 tailpipe emissions. However, to further minimize exhaust emissions and increase the efficiency of a H2-ICE, it is important to carefully control the relative air-fuel ratio of operation, i.e. Lambda (λ), which will lead in turn to an optimal combustion process. The precise λ control mainly relies upon the methodology to calculate λ on board of the engine, where the availability of reliable sensors specifically-developed for hydrogen combustion is currently limited. In this article, a comparative analysis of different methodologies for the calculation of λ is performed, comparing four methodologies: exhaust gas analysis through a Spindt-Brettschneider approach (λEMI), raw Universal Exhaust Gas Oxygen (λR-UEGO), processed Universal Exhaust Gas Oxygen (λP-UEGO) and speed-density (λSD) outputs.

A modern diesel engine is a reliable and efficient mean of producing power. A way to reduce harmful exhaust and greenhouse gas (GHG) emissions and secure the sources of energy is to develop technology for an efficient diesel engine operation independent of fossil fuels. Renewable diesel fuels are compatible with diesel engines without any major modifications. Rapeseed oil methyl esters (RME) and other fatty acid methyl esters (FAME) are commonly used in low level blends with diesel. Lately, hydrotreated vegetable oil (HVO) produced from vegetable oil and waste fat has found its way into the automotive market, being approved for use in diesel engines by several leading vehicle manufacturers, either in its pure form or in a mixture with the fossil diesel to improve the overall environmental footprint. There is a lack of data on how renewable fuels change the semi-volatile organic fraction of exhaust emissions.

An increasing need to lower greenhouse gas emissions, and so move away from fossil fuels like diesel and gasoline, has greatly increased the interest for methanol. Methanol can be produced from renewable sources and eliminate soot emissions from combustion engines [1]. Since compression ignition (CI) engines are used for the majority of commercial applications, research is intensifying into the use of methanol, as a replacement for diesel fuel, in CI engines. This includes work on dual-fuel set-ups, different fuel blends with methanol, ignition enhancers mixed with methanol, and partially premixed combustion (PPC) strategies with methanol. However, methanol is difficult to ignite, using compression alone, at low load conditions. The problem comes from methanol’s high octane number, low lower heating value and high heat of vaporization, which add up to a lot of heat being needed from the start to combust methanol [2].

A commercially available fuel, E85, a blend of ~85% ethanol and ~15% gasoline, can be a viable substitute for fossil fuels in internal combustion engines in order to achieve a reduction of the greenhouse gas (GHG) emissions. Ethanol is traditionally made of biomass, which makes it a part of the food-feed-fuel competition. New processes that reuse waste products from other industries have recently been developed, making ethanol a renewable and sustainable second-generation fuel. So far, work on E85 has focused on spark ignition (SI) concepts due to high octane rating of this fuel. There is very little research on its application in CI engines. Alcohols are known for low soot particle emissions, which gives them an advantage in the NOx-soot trade-off of the compression ignition (CI) concept.

In the recent years, the interest in heavy-duty engines fueled with Compressed Natural Gas (CNG) is increasing due to the necessity to comply with the stringent CO2 limitation imposed by national and international regulations. Indeed, the reduced number of carbon atoms of the NG molecule allows to reduce the CO2 emissions compared to a conventional fuel. The possibility to produce synthetic methane from renewable energy sources, or bio-methane from agricultural biomass and/or animal waste, contributes to support the switch from conventional liquid fuels to CNG. To drive the engine development and reduce the time-to-market, the employment of numerical analysis is mandatory. This requires a continuous improvement of the simulation models toward real predictive analyses able to reduce the experimental R&D efforts. In this framework, 1D numerical codes are fundamental tools for system design, energy management optimization, and so on.

Research activities in the development of reliable computational models for aftertreatment systems are constantly increasing in the automotive field. These investigations are essential in order to get a complete understanding of the main catalytic processes which clearly have a great impact on tailpipe emissions. In this work, a 1D chemical reaction model to simulate the catalytic activity of a Pd/Rh Three-Way Catalyst (TWC) for a Natural Gas heavy-duty engine is presented. An extensive database of tests carried out with the use of a Synthetic Gas Bench (SGB) has been collected to investigate the methane abatement pathways, linked to the lambda variation and oxide formation on palladium surface. Specific steady-state tests have shown a dynamics of the methane conversion even at fixed λ and temperature conditions, essentially due to the Pd/PdO ratio.

A wider use of biofuels in internal combustion engines could reduce the emissions of pollutants and greenhouse gases from the transport sector. In particular, due to stringent emission regulatory programs, compression ignition engine requires interventions aimed at reducing their polluting emissions. Ethanol, a low carbon fuel generally produced from biomass, is a promising alternative fuel applicable in compression ignition engines to reduce CO2 and soot emissions. In this paper, the application of a dual fuel diesel-ethanol configuration in a light-duty compression ignition engine has been numerically investigated. Ethanol is injected into the intake port, while diesel fuel is directly injected into the combustion chamber of the analyzed engine. CFD simulations have been carried out by means of the AVL Fire 3-D code. The operation at given engine load and speed has been simulated considering different diesel injection timings.

Low temperature combustion (LTC), is a promising alternative for combustion engines, because it combines the positive aspects of both CI and SI engines, high efficiency and low emissions. Another positive aspect of LTC is that it can operate with gasoline of different octane ratings. Still, higher octane gasolines prove to be difficult to operate at low load conditions leading to high combustion instability (COV) that leads also to high emissions. This drawback can be reduced by increasing the intake air temperature or increasing compression ratio, but it is not a viable strategy in conventional applications. For a diesel engine running under LTC conditions, a possibility is to use the existing hardware, glow plugs in this case, to increase the in-cylinder temperature at low loads and facilitate an improved combustion event.

CO2 is a greenhouse gas that is believed to be one of the main contributors to global warming. Recent studies show that a combination of methanol as a renewable fuel and advanced combustion concepts could be a promising future solution to alleviate this problem. However, high unburned hydrocarbon (UHC) and carbon monoxide (CO) emissions can be stated as the main drawback in low load operations when using methanol under advanced combustion concepts. This issue can be mitigated by modifying the stratification of the local equivalence ratio to achieve a favorable level. The stratifications evolved, and the regimes that can simultaneously produce low emissions, and high combustion efficiency can be identified by sweeping the injection timing from homogeneous charge compression ignition (HCCI) to partially premixed combustion (PPC). Understanding how the stratification of the local equivalence ratio for methanol evolves during the sweep is essential to gain these benefits.

Methanol is not a fuel typically used in compression ignition engines due to the high resistance to auto-ignition. However, conventional diesel combustion and PPC offer high engine efficiency along with low HC and CO emissions, albeit with the trade-off of increased NOx and PM emissions. This trade-off balance is mitigated in the case of methanol and other alcohol fuels, as they bring oxygen in the combustion chamber. Thus methanol compression ignition holds the potential for a clean and effective alternative fuel proposition. Most existing research on methanol is on SI engines and very little exists in the literature regarding methanol auto-ignition engine concepts. In this study, the spray characteristics of methanol inside the optically accessible cylinder of a DI-HD engine are investigated. The liquid penetration length at various injection timings is documented, ranging from typical PPC range down to conventional diesel combustion.

In recent years the research on Diesel engines has been increasingly shifting from performance and refinement to ultra-low emissions and efficiency. In fact, the last two attributes are key for the powertrain competitiveness in the propulsion electrified future, especially in the European market where 95gCO2/km fleet average and Euro6D RDE Step2 are phasing in at the same time. The present paper describes some of the most innovative research that GM and Istituto Motori Napoli are performing in the field, exploring how the steel-based additive manufacturing can be used to create innovative combustion bowl features that optimize the combustion process to a level that was not compatible with standard manufacturing technologies.

Gas engines (fuelled with CNG, LNG or Biogas) for generation of power and heat are, to this date, taking up larger shares of the market with respect to diesel engines. In order to meet the limit imposed by the TA-Luft regulations on stationary engines, lean combustion represents a viable solution for achieving lower emissions as well as efficiency levels comparable with diesel engines. Leaner mixtures however affect the combustion stability as the flame propagation velocity and consequently heat release rate are slowed down. As a strategy to deliver higher ignition energy, an active pre-chamber may be used. This work focuses on assessing the performance of a pre-chamber combustion configuration in a stationary heavy-duty engine for power generation, operating at different loads, air-to-fuel ratios and spark timings.

There is growing global interest in using renewable alcohols to reduce the greenhouse gases and the reliance on conventional fossil fuels. Recent studies show that methanol combined with partially premixed combustion provide clear performance and emission benefits compared to conventional diesel diffusion combustion. Nonetheless, high unburned hydrocarbon (HC) and carbon monoxide (CO) emissions can be stated as the main PPC drawback in light load condition when using high octane fuel such as Methanol with single injection strategy. Thus, the present experimental study has been carried out to investigate the influence of multiple injection strategies on the performance and emissions with methanol fuel in partially premixed combustion. Specifically, the main objective is to reduce HC, CO and simultaneously increase the gross indicated efficiency compared to single injection strategy.

This study investigates particulate matter (PM) and regulated emissions from renewable rapeseed oil methyl ester (RME) biodiesel in pure and blended forms and contrasts that to conventional diesel fuel. Environmental and health concerns are the major motivation for combustion engines research, especially finding sustainable alternatives to fossil fuels and reducing diesel PM emissions. Fatty acid methyl esters (FAME), including RME, are renewable fuels commonly used from low level blends with diesel to full substitution. They strongly reduce the net carbon dioxide emissions. It is largely unknown how the emissions and characteristics of PM get altered by the combined effect of adding biodiesel to diesel and implementing modern engine concepts that reduce nitrogen oxides (NOx) emissions by exhaust gas recirculation (EGR).

The use of gaseous fuels in internal combustion engines is increasing, due to several reasons, first of all their low environmental impact, large availability and low cost. Nevertheless, the need to reduce emissions also from gas engines is an important aspect to be considered in order to comply with future engine emissions regulations. In this scenario, an extensive experimental activity was performed to fully characterize an heavy duty spark ignition engine, under development for Euro VI compliance and designed to run with gaseous fuels. Two separate sets of experiments were carried out, in order to analyze the engine behavior when burning LPG and CNG, respectively. To this aim, the engine was installed on a dynamic test bench, accurately instrumented to characterize the combustion evolution, performance and exhaust pollutant emissions, along the World Harmonized Transient Cycle (WHTC), the new European driving homologation cycle.

Recently, it has been worth pointing out the relevance of alternative fuels in the improvement of air quality conditions and in the mitigation of global warming. In order to deal with these demands, in recent studies, it has been considered a great variety of alternative fuels. It goes without saying that the alternative fuels industry needs the best of the efficiency with a moderate layout. From this perspective, Liquefied Petroleum Gas (LPG) could represent a valid option, although it is not a renewable fuel. In terms of polluting emissions, the LPG can reduce nitrous oxides and smoke concentrations in the air, a capability that has a relevant importance for the modern pollution legislation. LPG is well known as an alternative fuel for Spark Ignition (SI) engines and, more recently, LPG systems have also been introduced in the Compression Ignition (CI) engines in dual-fuel configuration.