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A commercially available fuel, E85, a blend of ~85% ethanol and ~15% gasoline, can be a viable substitute for fossil fuels in internal combustion engines in order to achieve a reduction of the greenhouse gas (GHG) emissions. Ethanol is traditionally made of biomass, which makes it a part of the food-feed-fuel competition. New processes that reuse waste products from other industries have recently been developed, making ethanol a renewable and sustainable second-generation fuel. So far, work on E85 has focused on spark ignition (SI) concepts due to high octane rating of this fuel. There is very little research on its application in CI engines. Alcohols are known for low soot particle emissions, which gives them an advantage in the NOx-soot trade-off of the compression ignition (CI) concept.

De-fossilization is an increasingly important trend in the energy sector. In the transport sector the de-fossilization efforts have been centered in promoting the electrification of vehicles, nonetheless other pathways, like the use of carbon neutral or carbon-offsetting fuels under current vehicle fleets, are also worth considering. Low-carbon fuels (LCF) can be synthetized from sources that can take advantage of the carbon already present in the atmosphere (either by technologies like direct carbon capture or biological processes like photosynthesis in biofuels) and use energy from renewable sources for the necessary industrial processes. Although, LCFs can be compared to fossil fuels as energy sources for internal combustion engines, their composition is not the same and their properties can modify the engine combustion and emissions.

Focusing on the dual-mode dual-fuel (DMDF) combustion concept, a combined optimization of the piston bowl geometry with the fuel injection strategy was conducted at low, mid, and high loads. By coupling the KIVA-3V code with the enhanced genetic algorithm (GA), a total of 14 parameters including the piston bowl geometric parameters and the injection parameters were optimized with the objective of meeting Euro VI regulations while improving the fuel efficiency. The optimal piston bowl shape coupled with the corresponding injection strategy was summarized and integrated at various loads. Furthermore, the effects of the key geometric parameters were investigated in terms of organizing the in-cylinder flow, influencing the energy distribution, and affecting the emissions. The results indicate that the behavior of the DMDF combustion mode is further enhanced in the aspects of improving the fuel economy and controlling the emissions after the bowl geometry optimization.

Fleet electrification has been demonstrated as a feasible solution to decarbonize the heavy-duty transportation sector. The combination of hybridization and advanced combustion concepts may provide further advantages by also introducing reductions on criteria pollutants such as nitrogen oxides and soot. In this scenario, the interplay among the different energy paths must be understood and quantified to extract the full potential of the powertrain. One of the key devices in such powertrains is the battery, which involves different aspects regarding operation, safety, and degradation. Despite this complexity, most of the models still rely on resistance-capacity models to describe the battery operation. These models may lead to unpractical results since the current flow is governed by limiters rather than physical laws. Additionally, phenomena related with battery degradation, which decreases the nominal capacity and enhances the heat generation are also not considered in this approach.

The continuous improvement of internal combustion engines (ICEs) with strategies that can be applied to existing vehicle platforms, either directly or with minor modifications, can improve efficiency and reduce GHG emissions to help achieve Paris climate targets. Low carbon fuels (LCF) as diesel substitutes for light and heavy-duty vehicles are currently being considered as a promising alternative to reduce well-to-wheel (WTW) CO2 emissions by taking advantage of the carbon offset their synthesis pathway can promote, which could capture more CO2 than it releases into the atmosphere. Additionally, some low carbon fuels, like OMEx blends, have non-sooting properties that can significantly improve the NOx-soot tradeoff. The current work studies the calibration optimization of a EU6D-TEMP light-duty engine using various LCFs with different renewable contents with the goal of reduced NOx emissions.

Emissions regulations for engine and vehicle manufacturers are bound to become more limiting to prevent greenhouse gas emissions and mitigate the negative effects that potentiate global warming. To fulfill the energy demand necessary in the transportation sector for the short-to-medium term, a parallel optimization of the internal combustion engine, powertrain and fuels is necessary. The combination of novel combustion modes like the reactivity-controlled compression ignition (RCCI), that seeks the benefits of both compression ignition and spark ignition engines, with the so-called e-fuels, that reduce the carbon footprint from well-to-wheel, is worth exploring. This work investigates the potential of the RCCI concept using OMEx-gasoline to reduce the engine-out emissions beyond the current EURO VI legislation. To do so, eight representative operating conditions from several driving cycles for heavy-duty vehicles will be explored experimentally.

Dual-mode dual-fuel combustion is a promising combustion concept to achieve the required emissions and CO2 reductions imposed by the next standards. Nonetheless, the fuel formulation requirements are stricter than for the single-fuel combustion concepts as the combustion concept relies on the reactivity of two different fuels. This work investigates the effect of the low reactivity fuel sensitivity (S=RON-MON) and the octane number at different operating conditions representative of the different combustion regimes found during the dual-mode dual-fuel operation. For this purpose, experimental tests were performed using a PRF 95 with three different sensitivities (S0, S5 and S10) at operating conditions of 25% load/950 rpm, 50%/1800 rpm and 100%/2200 rpm. Moreover, air sweeps varying ±10% around a reference air mass were performed at 25%/1800 rpm and 50%/1800 rpm. Conventional diesel fuel was used as high reactivity fuel in all the cases.

Plug-in Hybrid Electric Vehicles (PHEVs) can be considered as the most promising technology to achieve the European CO2 targets together with a moderate infrastructure modification. However, the real benefits, in terms of CO2 emissions, depend on a great extent on the energy source (fuel and electricity mix), user responsibility, and vehicle design. Moreover, the electrification of the powertrain does not reduce other emissions as NOx and particulate matter (mainly soot). In the last years, low temperature combustion (LTC) modes as the reactivity controlled compression ignition (RCCI) have shown to achieve ultra-low NOx and soot emissions simultaneously due to the use of two fuels with different reactivity together with high exhaust gas recirculation (EGR) rates. Therefore, the aim of this work is to assess, through numerical simulations fed with experimental results, the effects of different energy sources on the performance and emissions of a series RCCI PHEV.

The increasingly stringent emissions regulations together with the demand of highly efficient vehicles from the customers, lead to rapid developments of distinct powertrain solutions, especially when the electrification is present in a certain degree. The combination of electric machines with conventional powertrains diversifies the powertrain architectures and brings the opportunity to save energy in greater extents. On the other hand, alternative combustion modes as reactivity controlled compression ignition (RCCI) have shown to provide simultaneous ultra-low NOx and soot emissions with similar or better thermal efficiency than conventional diesel combustion (CDC). In addition, it is necessary to introduce more renewable fuels as ethanol to reduce the total CO2 emitted to the atmosphere, also called well-to-wheel (WTW) emission, in the transport sector.

With demanding emissions legislations and the need for higher efficiency, new technologies for compression ignition engines are in development. One of them relies on reducing the heat losses of the engine during the combustion process as well as to devise injection strategies that reduce soot formation. Therefore, it is necessary a better comprehension about the turbulent kinetic energy (TKE) distribution inside the cylinder and how it is affected by the interaction between air flow motion and fuel spray. Furthermore, new diesel engines are characterized by massive decrease of NOx emissions. Therefore, considering the well-known NOx-soot trade-off, it is necessary a better comprehension and overall quantification of soot formation and how the different injection strategies can impact it.

It is known that in-cylinder airflow structures during intake and compression strokes deeply affects the combustion process in compression ignition (CI) engines. This work presents a methodology for the analysis of the swirling structures by means of the CFD proprietary code Converge 2.3. The methodology is based on the CFD modelling and the comparison of results with in-cylinder velocity fields measured by particle image velocimetry (PIV). Furthermore, the analysis is extended to the accuracy evaluation of other methods available to define the flow in the cylinder of internal combustion engines, such as experiments in steady flow rigs. These methods, in junction with simple phenomenological models, have been traditionally used to determine some of the fundamental variables that define the in-cylinder flow in ICE engines. The CFD analysis is focused in the flow structures around top dead centre (TDC) at the end of the compression stroke.

Ever decreasing permitted emission levels and the necessity of more efficient engines demand a better understanding of in-cylinder phenomena. In swirl-supported compression ignition (CI) engines, mean in-cylinder flow structures formed during the intake stroke deeply influence mixture preparation prior to combustion, heat transfer and pollutant oxidation all of which could potentially improve engine performance. Therefore, the ability to characterize these mean flow structures is relevant for achieving performance improvements. CI mean flow structure is mainly described by a precessing vortex. The location of the vortex center is key for the characterization of the flow structure. Consequently, this work aims at evaluating algorithms that allow for the location of the vortex center both, in ensemble-averaged velocity fields and in instantaneous velocity fields.

This work investigates the particulates size distribution of reactivity controlled compression ignition combustion, a dual-fuel concept which combines the port fuel injection of low-reactive/gasoline-like fuels with direct injection of highly reactive/diesel-like fuels. The particulates size distributions from 5-250 nm were measured using a scanning mobility particle sizer at six engine speeds, from 950 to 2200 rpm, and 25% engine load. The same procedure was followed for conventional diesel combustion. The study was performed in a single-cylinder engine derived from a stock medium-duty multi-cylinder diesel engine of 15.3:1 compression ratio. The combustion strategy proposed during the tests campaign was limited to accomplish both mechanical and emissions constraints. The results confirms that reactivity controlled compression ignition promotes ultra-low levels of nitrogen oxides and smoke emissions in the points tested.

In the past few years’ various studies have shown how the application of a highly premixed dual fuel combustion for CI engines leads a strong reduction for both pollutant emissions and fuel consumption. In particular a drastic soot and NOx reduction were achieved. In spite of the most common strategy for dual fueling has been represented by using two different injection systems, various authors are considering the advantages of using a single injection system to directly inject blends in the chamber. In this scenario, a characterization of the behavior of such dual-fuel blend spray became necessary, both in terms of inert and reactive ambient conditions. In this work, a light extinction imaging (LEI) has been performed in order to obtain two-dimensional soot distribution information within a spray flame of different diesel/gasoline commercial fuel blends. All the measurements were conducted in an optically accessible two-stroke engine equipped with a single-hole injector.

With ever-demanding emission legislations in Compression Ignition (CI) engines, new premixed combustion strategies have been developed in recent years seeking both, emissions and performance improvements. Since it has been shown that in-cylinder air flow affects the combustion process, and hence the overall engine performance, the study of swirling structures and its interaction with fuel injection are of great interest. In this regard, possible Turbulent Kinetic Energy (TKE) distribution changes after fuel injection may be a key parameter for achieving performance improvements by reducing in-cylinder heat transfer. Consequently, this paper aims to gain an insight into spray-swirl interaction through the analysis of in-cylinder velocity fields measured by Particle Image Velocimetry (PIV) when PCCI conditions are proposed. Experiments are carried out in a single cylinder optical Diesel engine with bowl-in-piston geometry.

Engine-out soot emissions are the result of a complex balance between in-cylinder soot formation and oxidation. Soot is formed in the diffusion flame, just after the lift-off length (LOL). Size and mass of soot particles increase through the diffusion flame and finally they are partially oxidized at the flame front. Therefore, engine-out soot emissions depend on the amount of soot formed and oxidized inside the combustion chamber. There is a considerable amount of work in the literature on characterization of soot formation. However, there is a clear lack of published research related to the characterization of soot oxidation. Thus, the main objective of the current research is to provide more knowledge and insight into the soot oxidation processes. For this purpose, a combination of theoretical and experimental tools were used. In particular, in-cylinder optical thickness (KL) was quantified with an optoelectronic sensor that uses two-color pyrometry.

In the last two decades engine research has been mainly focused on reducing pollutant emissions. This fact together with growing awareness about the impacts of climate change are leading to an increase in the importance of thermal efficiency over other criteria in the design of internal combustion engines (ICE). In this framework, the heat transfer to the combustion chamber walls can be considered as one of the main sources of indicated efficiency diminution. In particular, in modern direct-injection diesel engines, the radiation emission from soot particles can constitute a significant component of the efficiency losses. Thus, the main of objective of the current research was to evaluate the amount of energy lost to soot radiation relative to the input fuel chemical energy during the combustion event under several representative engine loads and speeds. Moreover, the current research characterized the impact of different engine operating conditions on radiation heat transfer.

Compared to the gasoline engine, the diesel engine has the advantage of being more efficient and hence achieving a reduction of CO₂ levels. Unfortunately, particulate matter (PM) and nitrogen oxides (NOx) emissions from diesel engines are high. To overcome these drawbacks, several new combustion concepts have been developed, including the PCCI (Premixed Charge Compression Ignition) combustion mode. This strategy allows a simultaneous reduction of NOx and soot emissions through the reduction of local combustion temperatures and the enhancement of the fuel/air mixing. In spite of PCCI benefits, the concept is characterized by its high combustion noise levels. Currently, a promising way to improve the PCCI disadvantages is being investigated. It is related with the use of low cetane fuels such as gasoline and diesel-gasoline blends.

A fundamental study to experimentally analyze the effect of cavitation in common-rail diesel nozzles on the soot formation process was carried out. The soot content was characterized by measuring the soot radiation, and an original methodology was developed to suitably characterize the soot formation process from this soot content. After a significant effort to overcome the different difficulties when analyzing the experimental data, the results seem to show a promising conclusion: cavitation reduces the soot formation rate. This reduction is explained, on the one hand, because it leads to a reduction in the effective diameter, thus diminishing the equivalence fuel/air ratio at the lift-off length; and, on the other hand, because it provokes an increase in effective velocity, thus increasing the lift-off length and reducing the corresponding equivalence fuel/air ratio.

Most of the new Diesel combustion concepts are mainly based on reducing local combustion temperatures and enhancing the fuel/air mixing with the aim of simultaneously reducing soot and NOx emissions. In this framework, Premixed Charge Compression Ignition (PCCI) has revealed as one of the best options to combine both low emissions and good combustion controllability. During last years, PCCI strategy has been widely explored using high EGR levels and different early or late injection timings to extend the ignition delay. Recently, the use of lower cetane fuels is under investigation. Despite the great quantity of research work performed, there are still some aspects related to PCCI combustion that are not completely well known. In this paper an experimental and numerical study is carried out focused on understanding the mixing and auto-ignition processes in PCCI combustion conditions using Diesel and Gasoline fuels.