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Advanced combustion engines, as power sources, dominate all aspects of the transportation sector. Stringent emission and fuel efficiency standards have promoted the research interest in advanced combustion strategies and alternative fuels. Owing to the comparable energy density to the existing fossil fuels and renewable production, alcohol and ether fuels may be a suitable replacement, or an additive to the gasoline/diesel fuels to meet the future emission standards with minimal modification to current engine geometry. Furthermore, lean and diluted combustion are well-researched pathways for efficiency improvement and reduction of engine-out emissions of modern engines. However, lean-burn or EGR dilution can introduce combustion inefficiencies in the form of excessive hydrocarbon, carbonyl species and carbon monoxide emissions.

The use of renewable fuels in place of conventional hydrocarbon fuels can minimize the carbon footprint of internal combustion engines. DME has been treated as a suitable surrogate to diesel fuel because of its high reactivity and soot-less combustion characteristics. The lower energy density of DME fuel demands a higher fuel supply rate to match the engine loads compared to diesel, which was achieved through prolonged injection duration and larger nozzle holes. When used as a pilot fuel to control the combustion behavior in a dual-fuel application, the fuel energy delivery rate becomes less critical allowing the use of a standard diesel common-rail injector for DME direct injection. In this work, the combustion of DME-Ethanol dual-fuel reactivity-controlled compression ignition was experimentally investigated.

With the increasing demand of emission reductions from the automotive industry, advanced after-treatment strategies have been investigated to overcome the challenges associated with meeting increasingly stringent emission regulations. Ongoing investigations on low temperature combustion (LTC) strategies are being researched to meet future emission regulations, however, the lowered exhaust temperature presents an even greater issue for exhaust after-treatment due to the change in combustion modes. Catalyst temperature is critical for the catalytic ability to maintain effective conversion efficiency of regulated emissions. The use of periodic flow reversal has shown benefits of maintaining catalyst temperature by alternating the exhaust flow direction through the catalytic converter, reducing the catalyst sensitivity to inlet gas temperature fluctuations.

Low temperature combustion (LTC) has been proved to overcome the trade-off between NOx and soot emissions in direct injection compression ignition engines. However, the lowered NOx emissions are accompanied by high hydrocarbon and CO emissions. Moreover, the NOx emissions under LTC has much higher NO2 concentrations compared with traditional high temperature combustion conditions. Experimental investigations have been carried out to show the hydrocarbon impact on NOx emissions and NO-NO2 conversion under various engine operation conditions, but the mechanism is less understood. The article includes numerical studies of the impact of hydrocarbons in the in-cylinder conversion of NO to NO2 during low temperature conditions in a compression ignition engine. In the present work, a stochastic reactor model with detailed chemical kinetics is utilized to investigate the reaction pathways during the NOx reduction and NO2 conversion processes.

The ever-stringent emission regulations are major challenges for the diesel fueled engines in automotive industry. The applications of advanced after-treatment technologies as well as alternative fuels [1] are considered as promising methodology to reduce exhaust emission from compression ignition (CI) engines. Using dimethyl ether (DME) as an alternative fuel has been extensively studied by many researchers and automotive manufactures since DME has demonstrated enormous potential in terms of emission reduction, such as low CO emission, and soot and sulfur free. However, the effect of employing DME in a lean NOX trap (LNT) based after-treatment system has not been fully addressed yet. In this work, investigations of the long breathing LNT system using DME as a reductant were performed on a heated after-treatment flow bench with simulated engine exhaust condition.

Reduction of nitrogen oxides (NOx) in lean burn and diesel fueled Compression Ignition (CI) engines is one of the major challenges faced by automotive manufacturers. Lean NOx Trap (LNT) and urea-based Selective Catalytic Reduction (SCR) exhaust after-treatment systems are well established technologies to reduce NOx emissions. However, each of these technologies has associated advantages and disadvantages for use over a wide range of engine operating conditions. In order to meet future ultra-low NOx emission norms, the use of both alternative fuels and advanced after-treatment technology may be required. The use of an alcohol fuel such as n-butanol or ethanol in a CI engine can reduce the engine-out NOx and soot emissions. In CI engines using LNTs for NOx reduction, the fuel such as diesel is utilized as a reductant for LNT regeneration.

In this work, empirical investigations of the diesel-ethanol Premixed Pilot-Assisted Combustion (PPAC) are carried out on a high compression ratio (18.2:1) single-cylinder diesel engine. The tests focus on determining the minimum ethanol fraction for ultra-low NOx & soot emissions, effect of single-pilot vs. twin-pilot strategies on emissions and ignition controllability, reducing the EGR requirements, enabling clean combustion across the load range and achieving high efficiency full-load operation. The results show that both low NOx and almost zero soot emissions can be achieved but at the expense of higher unburned hydrocarbons. Compared to a single-pilot injection, a twin-pilot strategy reduces the soot emissions significantly and also lowers the NOx emissions, thereby reducing the requirements for EGR. The near-TDC pilot provides excellent control over the combustion phasing, further reducing the need of a higher EGR quantity for phasing control.

Dual fuel applications of alcohol fuels such as ethanol or butanol through port injection with direct injection of diesel can be effective in reduction of NOx. However, these dual fuel applications are usually associated with an increase in the incomplete combustion products such as hydrocarbons (HC), carbon monoxide (CO), and hydrogen (H2) emissions. An analysis of these products of incomplete combustion and the resulting combustion efficiency penalty was made in the diesel ignited alcohol combustion modes. The effect of EGR application was evaluated using ethanol and butanol as the port injected fuel, with varying alcohol fractions at the mid-load condition (10 -12 bar IMEP). The impact of varying the engine load (5 bar to 19 bar IMEP) in the diesel ignited ethanol mode on the incomplete combustion products was also studied. Emission measurements were taken and the net fuel energy loss as a result of the incomplete combustion was estimated.

An experimental investigation of low temperature combustion (LTC) cycles is conducted with diesel and ethanol fuels on a high compression ratio (18.2:1), common-rail diesel engine. Two LTC modes are studied; near-TDC injection of diesel with up to 60% exhaust gas recirculation (EGR), and port injected ethanol ignited by direct injection of diesel with moderate EGR (30-45%). Indicated mean effective pressures up to 10 bar in the diesel LTC mode and 17.6 bar in the dual-fuel LTC mode have been realized. While the NOx and smoke emissions are significantly reduced, a thermal efficiency penalty is observed from the test results. In this work, the efficiency penalty is attributed to increased HC and CO emissions and a non-conventional heat release pattern. The influence of heat release phasing, duration, and shape, on the indicated performance is explained with the help of parametric engine cycle simulations.

Experimental testing was done with a modern compression ignition engine to study the effect of the engine load and the effect of different fuels on the post injection characteristics. Two different fuels were utilized; ultra-low sulphur diesel and n-butanol. The results showed that a post injection can be an effective method for increasing the operating range of the engine load. Engine operation at high load can be limited by the peak cylinder pressure but the test results showed that an early post injection can increase the engine load without increasing the peak in-cylinder pressure. Neat butanol combustion may have a very high peak in-cylinder pressure and a very high peak pressure rise rate even at low load conditions. The test results showed that a butanol post injection can contribute to engine power without significantly affecting the peak pressure rise rate and the peak in-cylinder pressure.

This study investigates neat n-butanol, as a cleaner power source, to directly replace conventional diesel fuels for enabling low temperature combustion on a modern common-rail diesel engine. Engine tests are performed at medium engine loads (6∼8 bar IMEP) with the single-shot injection strategy for both n-butanol and diesel fuels. As indicated by the experimental results, the combustion of neat n-butanol offers comparable engine efficiency to that of diesel while producing substantially lower NOx emissions even without the use of exhaust gas recirculation. The greater resistance to auto-ignition allows n-butanol to undergo a prolonged ignition delay for air-fuel mixing; the high volatility helps to enhance the cylinder charge homogeneity; the fuel-borne oxygen contributes to smoke reduction and, as a result, the smoke emissions of n-butanol combustion are generally at a near-zero level under the tested engine operating conditions.

Diesel aided by gasoline low temperature combustion offers low NOx and low soot emissions, and further provides the potential to expand engine load range and improve engine efficiency. The diesel-gasoline operation however yields high unburned hydrocarbons (UHC) and carbon monoxide (CO) emissions. This study aims to correlate the chemical origins of the key hydrocarbon species detected in the engine exhaust under diesel-gasoline operation. It further aims to help develop strategies to lower the hydrocarbon emissions while retaining the low NOx, low soot, and efficiency benefits. A single-cylinder research engine was used to conduct the engine experiments at a constant engine load of 10 bar nIMEP with a fixed engine speed of 1600 rpm. Engine exhaust was sampled with a FTIR analyzer for speciation investigation.

Modern diesel engines were known for producing ultra-low levels of hydrogen and hydrocarbons. However, as emission control techniques such as exhaust gas recirculation (EGR) are implemented to meet stringent NOx standards, the resulting increase in partial-combustion products can be significant in quantity both as pollutants and sources of lost engine efficiency. In this work, a modern common-rail diesel engine was configured to investigate the EGR threshold for elevated carbon monoxide, hydrocarbon, and hydrogen emissions at fixed loads and fixed heat-release phasing. It is noted that increase in hydrocarbons, in particular light hydrocarbons (such as methane, ethylene, and acetylene) was concurrent with ultra-low NOx emissions. Hydrogen gas can be emitted in significant quantities with the application of very high EGR. Under ultra-low NOx production conditions for medium and high load conditions, the light hydrocarbon species can account for the majority of hydrocarbon emissions.

Diesel engines operating in the low-temperature combustion (LTC) mode generally tend to produce very low levels of NOx and soot. However, the implementation of LTC is challenged by the higher cycle-to-cycle variation with heavy EGR operation and the narrower operating corridors. Small variations in the intake charge dilution can significantly increase the unburnt hydrocarbon and carbon monoxide emissions as well as escalate the consecutive cyclic fluctuations of the cylinder charge. This in turn adversely affects the robustness and efficiency of the LTC operation. However, Improvements in the promptness and accuracy of combustion control as well as tightened control on the intake oxygen concentration can enhance the robustness and efficiency of the LTC operation in diesel engines. In this work, a set of field programmable gate array (FPGA) modules were coded and interlaced to suffice on-the-fly combustion event modulations on a cycle-by-cycle basis.

In this paper a method of misfiring control in current cycle at engine start is presented. With this novel method, the high HC emissions of gasoline engine employed in traditional or hybrid electrical vehicles will be avoided. By the feedback of ion current signal, misfire phenomenon is identified within 30 degrees crank angle after spark plug ignited. Then, the ignition coil will be recharged and the plug sparked again to promote air fuel mixture oxidation and deplete the unburned hydrocarbon produces in exhaust gas. On the other hand, too late ignition will not always result in normal combustion, a kind of reaction similar with slow oxidation also occurs in such case.

Exhaust gas recirculation, fuel injection strategy and boost pressure are among the key enablers to attain low NOx and soot emissions simultaneously on modern diesel engines. In this work, the individual influence of these parameters on the emissions are investigated independently for engine loads up to 8 bar IMEP. A single-shot fuel injection strategy has been deployed to push the diesel cycle into low temperature combustion with EGR. The results indicated that NOx was a stronger respondent to injection pressure levels than to boost when the EGR ratio is relatively low. However, when the EGR level was sufficiently high, the NOx was virtually grounded and the effect of boost or injection pressure becomes irrelevant. Further tests indicated that a higher injection pressure lowered soot emissions across the EGR sweeps while the effect of boost on the soot reduction appeared significant only at higher soot levels.

In a DI diesel engine, THC emissions increase significantly with lower compression ratios, a low coolant temperature, or during the transient state. During the transient after a load increase, THC emissions are increased significantly to very high concentrations from just after the start of the load increase until around the 10th cycle, then rapidly decreased until the 20th cycle, before gradually decreasing to a steady state value after 1000 cycles. In the fully-warmed steady state operation with a compression ratio of 16 and diesel fuel, THC is reasonably low, but THC increases with lower coolant temperatures or during the transient period just after increasing the load. This THC increase is due to the formation of over-lean mixture with the longer ignition delay and also due to the fuel adhering to the combustion chamber walls. A low distillation temperature fuel such as normal heptane can eliminate the THC increase.

The characteristics of three-way-catalyst during engine start process were investigated based on a simulated start/stop test system for HEV application. Although the catalyst has already reached its light-off temperature, the conversion efficiency is poor during engine start process due to the deviation of lambda from stoichiometric. The high concentration hydrocarbon emission spike can be stored by catalyst substrate temporarily, then it is released. This dynamic process decreases the conversion efficiency for the following exhaust hydrocarbon emission. When the initial temperature of catalyst substrate before engine start increased from 150°C to 400°C, the conversion efficiency for both the hydrocarbon and NO are increased.

Simultaneous low NOx (< 0.15 g/kWh) & soot (< 0.01 g/kWh) are attainable for enhanced premixed combustion that may lead to higher levels of hydrocarbons and carbon monoxide emissions as the engine cycles move to low temperature combustion, which is a departure from the ultra low hydrocarbon and carbon monoxide emissions, typical of the high compression ratio diesel engines. As a result, the fuel efficiency of such modes of combustion is also compromised (up to 5%). In this paper, advanced strategies for fuel injection are devised on a modern 4-cylinder common rail diesel engine modified for single cylinder research. Thermal efficiency comparisons are made between the low temperature combustion and the conventional diesel cycles. The fuel injection strategies include single injection with heavy EGR, and early multi-pulse fuel injection under low or medium engine loads respectively.

Extensive empirical work indicates that the exhaust emission and fuel efficiency of modern common-rail diesel engines characterise strong resilience to biodiesel fuels when the engines are operating in conventional high temperature combustion cycles. However, as the engine cycles approach the low temperature combustion (LTC) mode, which could be implemented by the heavy use of exhaust gas recirculation (EGR) or the homogeneous charge compression ignition (HCCI) type of combustion, the engine performance start to differ between the use of conventional and biodiesel fuels. Therefore, a set of fuel injection strategies were compared empirically under independently controlled EGR, intake boost, and exhaust backpressure in order to improve the neat biodiesel engine cycles.