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Typical automotive emission testing systems usually employ Flame Ionization Detection (FID) analyzers to measure unburned fuel species in the exhaust, but the technique is not suitable for engines operating on alcohol fuels. The FID method is not sensitive to measuring unburned alcohol fuels due to the presence of oxygen bonds in the fuel molecule. Other techniques, such as Fourier Transform Infrared (FTIR), can provide accurate unburned fuel measurements with alcohol fuel. However, these techniques are expensive and are less accessible compared to FID analyzers. In this study, the unburned fuel emissions from the engine exhaust were measured simultaneously with FID and FTIR analyzers, with the engine operating on pure alcohols, which are methanol, ethanol, and n-butanol. While most previous work focuses on stoichiometric air-fuel mixtures, a wide range of lean operating conditions between global-λ 1.6 to 2.8 will be tested in this study.

In this study, the authors investigated the effect of fuel properties on the combustion characteristics by employing methane, methanol, ethanol, and primary reference fuels (PRFs) as the main chamber fuel while using methane for the pre-chamber. Global excess air ratios (λ) from 1.6 to lean limit were tested, while 13% of total fuel energy supplied to the engine was delivered via the pre-chamber. The gaseous methane was injected into the pre-chamber at the gas exchange top-dead-center (TDC). Port fuel injection was tested with both open and closed inlet valves. The pre-chamber assembly was designed to fit into the diesel injector pocket of the base engine, which resulted in a narrow throat diameter of 3.3 mm. The combustion stability limit was set at 5% of the coefficient of variation of gross IMEP, and the knock intensity limit was set at 10 bar. GT-Power software was used to estimate the composition of pre-chamber species and was used in heat release analysis of the two chambers.

With increasingly stringent emissions regulations, the use of pre-chamber combustion systems is gaining popularity in Internal Combustion Engines (ICE). The advantages of pre-chambers are well established, such as improving fuel economy by increasing the lean limit and reducing emissions, particularly NOX. In pre-chamber combustion, flame jets shoot out from the pre-chamber orifices into the main chamber, generating several ignition points that promote a rapid burn rate of the lean mixture (excess-air ratio (λ) >1) in the main chamber. This work studies the effects of using two different fuels in the main chamber and assesses the lean limit, the combustion efficiency (ηc), and the emissions of a single-cylinder heavy-duty engine equipped with a narrow-throat active pre-chamber. Ethanol (C2H5OH) was tested in the main chamber while keeping the pre-chamber fueled with methane (CH4), and the results were then compared to using methane as the sole fuel.

Pre-chamber combustion (PCC) enables leaner air-fuel ratio operation by improving its ignitability and extending flammability limit, and consequently, offers better thermal efficiency than conventional spark ignition operation. The geometry and fuel concentration of the pre-chamber (PC) is one of the major parameters that affect overall performance. To understand the dynamics of the PCC in practical engine conditions, this study focused on (i) correlation of the events in the main chamber (MC) with the measured in-cylinder pressure traces and, (ii) the effect of fuel concentration on the MC combustion characteristics using laser diagnostics. We performed simultaneous acetone planar laser-induced fluorescence (PLIF) from the side, and OH* chemiluminescence imaging from the bottom in a heavy-duty optical engine. Two different PC Fueling Ratios (PCFR, the ratio of PC fuel to the total fuel), 7%, and 13%, were investigated.

Pre-chamber spark ignition (PCSI) combustion is an emerging lean-burn combustion mode capable of extending the lean operation limit of an engine. The favorable characteristic of short combustion duration at the lean condition of PCSI results in high efficiencies compared to conventional spark ignition combustion. Since the engine operation is typically lean, PCSI can significantly reduce engine-out NOx emissions while maintaining short combustion durations. In this study, experiments were conducted on a heavy-duty engine at lean conditions at mid to low load. Two major studies were performed. In the first study, the total fuel energy input to the engine was fixed while the intake pressure was varied, resulting in varying the global excess air ratio. In the second study, the intake pressure was fixed while the amount of fuel was changed to alter the global excess air ratio.

In a previous study, we demonstrated that the isobaric combustion cycle, achieved with a split injection strategy, can be more suitable for the double compression expansion engine concept than the conventional diesel combustion cycle. The present work is focused on understanding the effect of different injection strategies on the heat release, efficiency, and emissions of isobaric combustion at the peak cylinder pressure of 150 bar. In situ injection rate measurements are performed to improve our understanding of the heat release rate shape and pollutant formation. A variation of load is performed to demonstrate the feasibility of the isobaric combustion cycle at higher loads, and the means of achieving them. The thermal efficiency reduces at lower loads because of heat losses. It peaks at a medium load point before reducing again at higher loads because of exhaust losses.

The split injection strategy holds a potential for high pressure combustion engines. One advantage of such strategy is the capability to control the heat release rate, which also implies the use of multiple split-injections with relatively short dwell intervals. Most injection rate measurement techniques require installment of the injector on a dedicated test rig. However, these techniques fail to accurately reproduce real-engine operating conditions. Using the spray impingement method, this paper investigates the injection rate of a high flow-rate solenoid injector while being operated on the engine. The aim is to have an experimental configuration as similar as possible to the real engine in terms of the acoustics and the fuel temperature within the injection system. The assumption of spray force proportional to the spray momentum is used here to measure the injection rate.

Due to stringent emission standards, the demand for higher efficiency engines has been unprecedentedly high in recent years. Among several existing combustion modes, pre-chamber spark ignition (PCSI) emerges to be a potential candidate for high-efficiency engines. Research on the pre-chamber concept exhibit higher indicated efficiency through lean limit extension while maintaining the combustion stability. In this study, a unique pre-chamber geometry was tested in a single-cylinder heavy-duty engine at low load lean conditions. The geometry features a narrow throat, which was designed to be packaged inside a commercial diesel injector pocket. The pre-chamber was fueled with methane while the main chamber was supplied with an ethanol/air mixture.

Homogeneous charge compression ignition (HCCI) experiments were run with the aid of a Cooperative fuel research (CFR) engine, operating at 600 rpm and under very lean conditions (ϕ = 0.3). This study seeks to examine the combustion behavior of different fuels by finding the pressure-temperature (p-t) conditions that instigate the start of combustion, and the transition from low temperature combustion to principal combustion. The pressure-temperature diagram emphasizes p-t conditions according to their traces through the compression stroke. In each fuel tested, p-t traces were examined by a sweep of the intake temperature; and for each experimental point, combustion phasing was maintained at top dead center by adjusting the compression ratio of the engine. In addition to the p-t diagram, results were analyzed using a compression ratio-intake temperature diagram, which showed the compression ratio required with respect to intake temperature.

Due to their physical and chemical properties, alcohols such as ethanol and methanol when blended with gasoline provide high anti-knock quality and hence efficient engines. However, there are few promising properties of 1-butanol similar to conventional gasoline which make it a favorable choice for internal combustion engines. Previously the author showed that by blending ethanol and methanol with low octane fuels, non-linear increase in the HCCI fuel number occurs in HCCI combustion mode. Very few studies have been conducted on the use of 1-butanol in HCCI combustion mode, therefore for this work, 1-butanol with a RON 96 was selected as the high octane fuel. Three low octane fuels with octane number close to 70 were used as a base fuel. Two of the low octane fuels are Fuels for Advanced Combustion Engines (FACE gasolines), more specifically FACE I and FACE J and also primary reference fuel (PRF 70) were selected.

The present study experimentally examines the low-temperature autoignition area of isooctane within the in-cylinder pressure-in-cylinder temperature map. Experiments were run with the help of a Cooperative Fuel Research (CFR) engine. The boundaries of this engine were extended so that experiments could be performed outside the domain delimited by research octane number (RON) and motor octane number (MON) traces. Since homogeneous charge compression ignition (HCCI) combustion is governed by kinetics, the rotation speed for all the experiments was set at 600 rpm to allow time for low-temperature heat release (LTHR). All the other parameters (intake pressure, intake temperature, compression ratio, and equivalence ratio) were scanned, such as the occurrence of isooctane combustion. The principal results showed that LTHR for isooctane occurs effortlessly under high intake pressure (1.3 bar) and low intake temperature (25 °C).

Future internal combustion engines demand higher efficiency but progression towards this is limited by the phenomenon called knock. A possible solution for reaching high efficiency is Octane-on-Demand (OoD), which allows to customize the antiknock quality of a fuel through blending of high-octane fuel with a low octane fuel. Previous studies on Octane-on-Demand highlighted efficiency benefits depending on the combination of low octane fuel with high octane booster. The author recently published works with ethanol and methanol as high-octane fuels. The results of this work showed that the composition and octane number of the low octane fuel is significant for the blending octane number of both ethanol and methanol. This work focuses on toluene as the high octane fuel (RON 120). Aromatics offers anti-knock quality and with high octane number than alcohols, this work will address if toluene can provide higher octane enhancement.

The blending behavior of ethanol in five different hydrocarbon base fuels with octane numbers of approximately 70 and 84 was examined under Spark-Ignited (SI) and Homogeneous Charge Compression Ignited (HCCI) operating conditions. The Blending octane number (BON) was used to characterize the blending behavior on both a volume and molar basis. Previous studies have shown that the blending behavior of ethanol generally follows several well-established rules. In particular, non-linear blending effects are generally observed on a volume basis (i.e. BON > RON or MON of pure ethanol; 108 and 89, respectively), while linear blending effects are generally observed on a molar basis (i.e. BON = RON or MON of pure ethanol). This work firstly demonstrates that the non-linear volumetric blending effects traditionally observed under SI operating conditions are also observed under HCCI operating conditions.

The objective of this study was to investigate the effect of aromatic on combustion stratification and particulate emissions for PRF60. Experiments were performed in an optical CI engine at a speed of 1200 rpm for TPRF0 (100% v/v PRF60), TPRF20 (20% v/v toluene + 80% PRF60) and TPRF40 (40% v/v toluene + 60% PRF60). TPRF mixtures were prepared in such a way that the RON of all test blends was same (RON = 60). Single injection strategy with a fuel injection pressure of 800 bar was adopted for all test fuels. Start of injection (SOI) was changed from early to late fuel injection timings, representing various modes of combustion viz HCCI, PPC and CDC. High-speed video of the in-cylinder combustion process was captured and one-dimensional stratification analysis was performed from the intensity of images. Particle size, distribution and concentration were measured and linked with the in-cylinder combustion images.

The literature study on PPC in optical engine reveals investigations on OH chemiluminescence and combustion stratification. So far, mostly PRF fuel is studied and it is worthwhile to examine the effect of fuel properties on PPC. Therefore, in this work, fuel having different octane rating and physical properties are selected and PPC is studied in an optical engine. The fuels considered in this study are diesel, heavy naphtha, light naphtha and their corresponding surrogates such as heptane, PRF50 and PRF65 respectively. Without EGR (Intake O2 = 21%), these fuels are tested at an engine speed of 1200 rpm, fuel injection pressure of 800 bar and pressure at TDC = 35 bar. SOI is changed from late to early fuel injection timings to study PPC and the shift in combustion regime from CI to PPC is explored for all fuels. An increased understanding on the effect of fuel octane number, physical properties and chemical composition on combustion and emission formation is obtained.

The blending of ethanol with PRF (Primary reference fuel) 84 was investigated and compared with FACE (Fuels for Advanced Combustion Engines) A gasoline surrogate which has a RON of 83.9. Previously, experiments were performed at four HCCI conditions but the chemical effect responsible for the non-linear blending behavior of ethanol with PRF 84 and FACE A was not understood. Hence, in this study the experimental measurements were simulated using zero-dimensional HCCI engine model with detailed chemistry in CHEMKIN PRO. Ethanol was used as an octane booster for the above two base fuels in volume concentration of 0%, 2%, 5% and 10%. The geometrical data and the intake valve closure conditions were used to match the simulated combustion phasing with the experiments. Low temperature heat release (LTHR) was detected by performing heat release analysis.

The concept of double compression, and double expansion engine (DCEE) for improving the efficiency of piston reciprocating engines was introduced in SAE Paper 2015-01-1260. This engine configuration has separate high, and low pressure units thereby effectively reducing friction losses for high effective compression ratios. The presence of an additional expander stage also theoretically allows an extra degree of freedom to manipulate the combustion heat release rate so as to achieve better optimum between heat transfer, and friction losses. This paper presents a 1-D modeling study of the engine concept in GT-Power for assessing the sensitivity of engine losses to heat release rate. The simulations were constrained by limiting the maximum pressure to 300 bar.

Increasing the anti-knock quality of gasoline fuels can enable higher efficiency in spark ignition engines. In this study, the blending anti-knock quality of dicyclopentadiene (DCPD), a by-product of ethylene production from naphtha cracking, with various gasoline fuels is explored. The blends were tested in an ignition quality tester (IQT) and a modified cooperative fuel research (CFR) engine operating under homogenous charge compression ignition (HCCI) and knock limited spark advance (KLSA) conditions. Due to current fuel regulations, ethanol is widely used as a gasoline blending component in many markets. In addition, ethanol is widely used as a fuel and literature verifying its performance. Moreover, because ethanol exhibits synergistic effects, the test results of DCPD-gasoline blends were compared to those of ethanol-gasoline blends. The experiments conducted in this work enabled the screening of DCPD auto-ignition characteristics across a range of combustion modes.

The blending of ethanol with primary reference fuel (PRF) mixtures comprising n-heptane and iso-octane is known to exhibit a non-linear octane response; however, the underlying chemistry and intermolecular interactions are poorly understood. Well-designed experiments and numerical simulations are required to understand these blending effects and the chemical kinetic phenomenon responsible for them. To this end, HCCI engine experiments were previously performed at four different conditions of intake temperature and engine speed for various PRF/ethanol mixtures. Transfer functions were developed in the HCCI engine to relate PRF mixture composition to autoignition tendency at various compression ratios. The HCCI blending octane number (BON) was determined for mixtures of 2-20 vol % ethanol with PRF70. In the present work, the experimental conditions were considered to perform zero-dimensional HCCI engine simulations with detailed chemical kinetics for ethanol/PRF blends.

Gasoline-ethanol-methanol (GEM) blends, with constant stoichiometric air-to-fuel ratio (iso-stoichiometric blending rule) and equivalent to binary gasoline-ethanol blends (E2, E5, E10 and E15 in % vol.), were defined to investigate the effect of methanol and combined mixtures of ethanol and methanol when blended with three FACE (Fuels for Advanced Combustion Engines) Gasolines, I, J and A corresponding to RON 70.2, 73.8 and 83.9, respectively, and their corresponding Primary Reference Fuels (PRFs). A Cooperative Fuel Research (CFR) engine was used under Spark Ignition and Homogeneous Charge Compression Ignited modes. An ignition quality tester was utilized in the Compression Ignition mode. One of the promising properties of GEM blends, which are derived using the iso-stoichiometric blending rule, is that they maintain a constant octane number, which has led to the introduction of methanol as a drop-in fuel to supplement bio-derived ethanol.