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Fluoroelastmers are well known for their resistance to heat and fluids, and have become major material for crankcase oil seals. On the other hand, new additive formulations are developed for engine lubricants used for fuel economic gasoline engines. In this paper, the effects of those additives on properties of fluoroelastmers are investigated. The results of the immersion tests of both test plaques and oil seal products indicate that dithiocarbamates, friction modifier, have hardening effects on fluoroelastmers. The fluoroelastmer deterioration mechanism is determined by analysis of elastmer samples after immersion in oil.

This paper describes lubricant technology to enhance the durability of the low friction performance of gasoline engine oils which were formulated with molybdenum dithiodicarbamates (MoDTCs) as friction modifiers. This paper also describes an evaluation method which consists of three tests: (1) Our in-house rig test to simulate oil deterioration in an engine stand; (2) Quantitative analysis of MoDTC and ZnDTP in oils and; (3) A friction test (SRV). It was found that the low friction performance of fuel economy engine oils deteriorated primarily due to the consumption of MoDTC and ZnDTP. Calcium salicylates had better durability of low friction performance than calcium sulfonates. Furthermore, sulfurized compounds enhanced the durability. Based on these findings, an experimental oil was formulated.

A bench engine test for evaluating the fuel efficiency of automotive crankcase oils using modern engines was developed. The fuel consumption was primarily proportional to the viscosity of the oils down to 5 mm2/s at operating temperatures, indicating that the use of low-viscosity oil was effective in improving fuel efficiency. This may be because the oil film would be formed easily, since sliding parts, such as valve train systems, in modern engines are finely finished. Organo molybdenum dithiocarbamates were effective in improving fuel efficiency at high temperature. A 2.7% improvement in fuel efficiency relative to conventional SAE 10W-30 oils was achieved by the combination of low-viscosity SAE 5W-20 oils and organo molybdenum dithiocarbamates under constant operating conditions with engine speed 1,500 rpm and torque 37.2 N•m.

This paper describes lubricant technology which helps to prevent intake valve deposit (IVD) formation for use with conventional gasolines without detergents, as well as the IVD evaluation method used in testing. The FED 3462 method was modified to establish a new panel coking test method, with excellent correlation with the engine stand IVD test, for the quantitative evaluation of IVD. Tests have shown that IVD increases when the volatility of base oils becomes higher due to condensation and polymerization of engine oil additives. Furthermore, viscosity index improvers, metallic detergents and ashless dispersants have considerable effect on IVD formation. Based on various experiments, the authors have established a formulation technology for engine oils to lower IVD, which they incorporated in two newly formulated SG oils with lower IVD than conventional 5W-30 SG oil.

Fuel economy is one of the most important performance features for modern engine oils. For some time now, fuel efficient engine oils (called Energy Conserving II or EC-II) have been available in the marketplace. However, the performance of EC-II oils is only 2.7% Equivalent Fuel Economy Improvement (EFEI) as measured by the ASTM Sequence VI Engine Test. To meet future industry needs, more fuel efficient engine oils are desirable. In order to achieve this, a study of highly fuel efficient engine oils was initiated. An initial target of 3.9% EFEI was selected and several candidate oils were evaluated, some of which exceeded this target. The oils were evaluated using a chassis dynamometer using the U. S. EPA mode. The test results may be summarized: 5W-30 Prototype Oil containing MoDTC showed between 1.6 and 2.6% better fuel economy than conventional 5W-30 and 10W-30 EC-II oils. There was an optimum viscosity for maximum fuel economy using the EPA testing mode.