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Sources of unburned hydrocarbon (UHC) emissions are examined for a highly dilute (10% oxygen concentration), moderately boosted (1.5 bar), low load (3.0 bar IMEP) operating condition in a single-cylinder, light-duty, optically accessible diesel engine undergoing partially-premixed low-temperature combustion (LTC). The evolution of the in-cylinder spatial distribution of UHC is observed throughout the combustion event through measurement of liquid fuel distributions via elastic light scattering, vapor and liquid fuel distributions via laser-induced fluorescence, and velocity fields via particle image velocimetry (PIV). The measurements are complemented by and contrasted with the predictions of multi-dimensional simulations employing a realistic, though reduced, chemical mechanism to describe the combustion process.

Low temperature combustion (LTC) strategies, which can mitigate emissions of particulate matter (PM) and nitrogen oxides (NOx) from diesel engines, typically have longer ignition delays compared to conventional diesel operation. With extended ignition delays, more time is available for premixing, which reduces PM formation. The effect of varying ignition delay on the spatial and temporal evolution of soot in LTC diesel jets is studied by imaging the natural soot luminosity, while the in-cylinder soot mass and temperature are measured using two-color soot thermometry. Ignition delay in the engine is controlled by adjusting the intake air temperature while keeping the same charge density at TDC. This allowed us to study sooting characteristics at various ignition delays while keeping the same diesel jet penetration for all the cases.

The soot distribution as function of ambient O₂ mole fraction in a heavy-duty diesel engine was investigated at low load (6 bar IMEP) with laser-induced incandescence (LII) and natural luminosity. A Multi-YAG laser system was utilized to create time-resolved LII using 8 laser pulses with a spacing of one CAD with detection on an 8-chip framing camera. It is well known that the engine-out smoke level increases with decreasing oxygen fraction up to a certain level where it starts to decrease again. For the studied case the peak occurred at an O₂ fraction of 11.4%. When the oxygen fraction was decreased successively from 21% to 9%, the initial soot formation moved downstream in the jet. At the lower oxygen fractions, below 12%, no soot was formed until after the wall interaction. At oxygen fractions below 11% the first evidence of soot is in the recirculation zone between two adjacent jets.

This paper presents experimental results for two fuel-related topics in a diesel engine: (1) how fuel volatility affects the premixed burn and heat release rate, and (2) how ignition quality influences the soot formation. Fast evaporation of fuel may lead to more intense heat release if a higher percentage of the fuel is mixed with air to form a combustible mixture. However, if the evaporation of fuel is driven by mixing with high-temperature gases from the ambient, a high-volatility fuel will require less oxygen entrainment and mixing for complete vaporization and, consequently, may not have potential for significant heat release simply because it has vaporized. Fuel cetane number changes also cause uncertainty regarding soot formation because variable ignition delay will change levels of fuel-air mixing prior to combustion.

The effects of spray targeting on mixing, combustion, and pollutant formation under a low-load, late-injection, low-temperature combustion (LTC) diesel operating condition are investigated by optical engine measurements and multi-dimensional modeling. Three common spray-targeting strategies are examined: conventional piston-bowl-wall targeting (152° included angle); narrow-angle floor targeting (124° included angle); and wide-angle piston-bowl-lip targeting (160° included angle). Planar laser-induced fluorescence diagnostics in a heavy-duty direct-injection optical diesel engine provide two-dimensional images of fuel-vapor, low-temperature ignition (H2CO), high-temperature ignition (OH) and soot-formation species (PAH) to characterize the LTC combustion process.

Fuel injection during negative valve overlap (NVO) can extend low-load gasoline HCCI operation through control of main combustion phasing. Reactions and heat release accompanying NVO fuel injection give rise to changes in temperature and composition of the charge prior to main combustion. The extent of reaction of injected NVO fuel and the relative importance of resulting thermal and chemical effects on main combustion are a current research topic. In this work, bulk temperature computations are used to quantify thermal conditions prior to main ignition for cases with and without NVO fueling. To separate measured thermal effects from chemical effects of NVO fuel reactions on the main combustion, cases without NVO fuel but with similar mixture temperatures and combustion phasing are compared. Effects of varying NVO fuel amount and injection timing on heat release, combustion phasing, bulk temperature evolution, and iso-octane ignition temperatures are analyzed.

Multiple fuel-injections during a single engine cycle can reduce combustion noise and improve pollutant emissions tradeoffs. Various hypotheses have been proposed in the literature regarding the in-cylinder processes responsible for the pollutant emissions improvements. This paper provides a brief overview of these hypotheses along with an investigation exploring which of these mechanisms are important for post injections under low-temperature combustion (LTC) conditions in a heavy-duty diesel engine. In-cylinder soot and exhaust smoke are measured by 2-color soot thermometry and filter paper blackening, respectively. The evolution and interaction of soot regions from each of the injections is visualized using high-speed imaging of soot luminosity, both in the piston bowl and in the squish regions.

The influence of soy- and palm-based biofuels on the in-cylinder sources of unburned hydrocarbons (UHC) and carbon monoxide (CO) was investigated in an optically accessible research engine operating in a partially premixed, low-temperature combustion regime. The biofuels were blended with an emissions certification grade diesel fuel and the soy-based biofuel was also tested neat. Cylinder pressure and emissions of UHC, CO, soot, and NOx were obtained to characterize global fuel effects on combustion and emissions. Planar laser-induced fluorescence was used to capture the spatial distribution of fuel and partial oxidation products within the clearance and bowl volumes of the combustion chamber. In addition, late-cycle (30° and 50° aTDC) semi-quantitative CO distributions were measured above the piston within the clearance volume using a deep-UV LIF technique.

Fuel injection during negative valve overlap offers a promising method of controlling HCCI combustion, but sorting out the thermal and chemical effects of NVO fueling requires knowledge of temperatures throughout the cycle. Computing bulk temperatures throughout closed portions of the cycle is relatively straightforward using an equation of state, once a temperature at one crank angle is established. Unfortunately, computing charge temperatures at intake valve closing for NVO operation is complicated by a large, unknown fraction of residual gases at unknown temperature. To address the problem, we model blowdown and recompression during exhaust valve opening and closing events, allowing us to estimate in-cylinder charge temperatures based on exhaust-port measurements. This algorithm permits subsequent calculation of crank-angle-resolved bulk temperatures and residual gas fraction over a wide range of NVO operation.

This paper examines the interaction of bulk flow and jet-induced fuel convection in an optically accessible hydrogen-fueled engine with direct injection. Planar laser-induced fluorescence (PLIF) of gaseous acetone as a fuel tracer was performed to obtain quantitative images of the hydrogen mole-fraction in the operating engine. With the engine motored, fuel was injected into inert bulk gas from a centrally located injector during the compression stroke. The injector had a single-hole nozzle with the jet angled at 50 degrees with respect to the vertical injector axis. Two parameters were varied in the experiments, injector orientation and tumble intensity, and for each of these, the injection timing was varied. Image series of the mean fuel mole-fraction between injection and near-TDC crank angles capture the mixture-formation process for each configuration and injection timing.

Lignin by-products from biorefineries has the potential to provide a low-cost alternative to petroleum-based precursors to manufacture carbon fiber, which can be combined with a binding matrix to produce a structural material with much greater specific strength and specific stiffness than conventional materials such as steel and aluminum. The market for carbon fiber is universally projected to grow exponentially to fill the needs of clean energy technologies such as wind turbines and to improve the fuel economies in vehicles through lightweighting. In addition to cellulosic biofuel production, lignin-based carbon fiber production coupled with biorefineries may provide $2,400 to $3,600 added value dry Mg−1 of biomass for vehicle applications. Compared to producing ethanol alone, the addition of lignin-derived carbon fiber could increase biorefinery gross revenue by 30% to 300%.

Cavitation plays a significant role in high pressure diesel injectors. However, cavitation is difficult to measure under realistic conditions. X-ray phase contrast imaging has been used in the past to study the internal geometry of fuel injectors and the structure of diesel sprays. In this paper we extend the technique to make in-situ measurements of cavitation inside unmodified diesel injectors at pressures of up to 1200 bar through the steel nozzle wall. A cerium contrast agent was added to a diesel surrogate, and the changes in x-ray intensity caused by changes in the fluid density due to cavitation were measured. Without the need to modify the injector for optical access, realistic injection and ambient pressures can be obtained and the effects of realistic nozzle geometries can be investigated. A range of single and multi-hole injectors were studied, both sharp-edged and hydro-ground. Cavitation was observed to increase with higher rail pressures.

This paper implements a coupled approach to integrate the internal nozzle flow and the ensuing fuel spray using a Volume-of-Fluid (VOF) method in the CONVERGE CFD software. A VOF method was used to model the internal nozzle two-phase flow with a cavitation description closed by the homogeneous relaxation model of Bilicki and Kestin [1]. An Eulerian single velocity field approach by Vallet et al. [2] was implemented for near-nozzle spray modeling. This Eulerian approach considers the liquid and gas phases as a complex mixture with a highly variable density to describe near nozzle dense sprays. The mean density is obtained from the Favreaveraged liquid mass fraction. The liquid mass fraction is transported with a model for the turbulent liquid diffusion flux into the gas.

Measurements of ignition behavior, homogeneous reactor simulations employing detailed kinetics, and quantitative in-cylinder imaging of fuel-air distributions are used to delineate the impact of temperature, dilution, pilot injection mass, and injection pressure on the pilot ignition process. For dilute, low-temperature conditions characterized by a lengthy ignition delay, pilot ignition is impeded by the formation of excessively lean mixture. Under these conditions, smaller pilot mass or higher injection pressures further lengthen the pilot ignition delay. Similarly, excessively rich mixtures formed under relatively short ignition delay conditions typical of conventional diesel combustion will also prolong the ignition delay. In this latter case, smaller pilot mass or higher injection pressures will shorten the ignition delay. The minimum charge temperature required to effect a robust pilot ignition event is strongly dependent on charge O2 concentration.

Despite ongoing research efforts directed at reducing engine-out emissions, diesel engines are known to be one of the largest sources of atmospheric particulate matter (i.e., soot). Quantitative measurements are of primary importance to address soot production during the combustion process in the cylinder of diesel engines. This study presents the capabilities of an extinction-based diagnostic developed to quantitatively measure the soot volume fraction in n-dodecane sprays injected in a high-pressure, high-temperature vessel. Coupled with high-speed imaging, the technique yields time-resolved measurements of the soot field by relying on a diffused back-illumination scheme to improve extinction quantification in the midst of intense beam steering. The experiments performed in this work used two wavelengths, which, when combined with the Rayleigh-Debye-Gans theory, provide information about the optical and physical properties of soot.

In order to ensure the safety of a structure, adequate strength for structural elements must be provided. Moreover, catastrophic deformations such as buckling must be prevented. Using the linear finite element method, deterministic buckling analysis is completed in two main steps. First, a static analysis is performed using an arbitrary ordinate applied loading pattern. Using the obtained element axial forces, the geometric stiffness of the structure is assembled. Second, an eigenvalue problem is performed between structure's elastic and geometric stiffness matrices, yielding the structure's critical buckling loads. However, these deterministic approaches do not consider uncertainty the structure's material and geometric properties. In this work, a new method for finite element based buckling analysis of a structure with uncertainty is developed. An imprecise probability formulation is used to quantify the uncertainty present in the mechanical characteristics of the structure.

Although soot-formation processes in diesel engines have been well characterized during the mixing-controlled burn, little is known about the distribution of soot throughout the combustion chamber after the end of appreciable heat release during the expansion and exhaust strokes. Hence, the laser-induced incandescence (LII) diagnostic was developed to visualize the distribution of soot within an optically accessible single-cylinder direct-injection diesel engine during this period. The developed LII diagnostic is semi-quantitative; i.e., if certain conditions (listed in the Appendix) are true, it accurately captures spatial and temporal trends in the in-cylinder soot field. The diagnostic features a vertically oriented and vertically propagating laser sheet that can be translated across the combustion chamber, where “vertical” refers to a direction parallel to the axis of the cylinder bore.

This work contributes to the understanding of physical mechanisms that control flashback, or more appropriately combustion recession, in diesel sprays. A large dataset, comprising many fuels, injection pressures, ambient temperatures, ambient oxygen concentrations, ambient densities, and nozzle diameters is used to explore experimental trends for the behavior of combustion recession. Then, a reduced-order model, capable of modeling non-reacting and reacting conditions, is used to help interpret the experimental trends. Finally, the reduced-order model is used to predict how a controlled ramp-down rate-of-injection can enhance the likelihood of combustion recession for conditions that would not normally exhibit combustion recession. In general, fuel, ambient conditions, and the end-of-injection transient determine the success or failure of combustion recession.

Negative valve overlap (NVO) is a viable control strategy that enables low-temperature gasoline combustion (LTGC) at low loads. Thermal effects of NVO fueling on main combustion are well understood, but fuel reforming chemistry during NVO has not been extensively studied. The objective of this work is to analyze the impact of global equivalence ratio and available oxidizer on NVO product concentrations. Experiments were performed in a LTGC single-cylinder engine under a sweep of NVO oxygen concentration and NVO fueling rates. Gas sampling at the start and end of the NVO period was performed via a custom dump-valve apparatus with detailed sample speciation by gas chromatography. Single-zone reactor models using detailed chemistry at relevant mixing and thermodynamic conditions were used in parallel to the experiments to evaluate expected yields of partially oxidized species under representative engine time scales.

The study of spray-wall interaction is of great importance to understand the dynamics that occur during fuel impingement onto the chamber wall or piston surfaces in internal combustion engines. It is found that the maximum spreading length of an impinged droplet can provide a quantitative estimation of heat transfer and energy transformation for spray-wall interaction. Furthermore, it influences the air-fuel mixing and hydrocarbon and particle emissions at combusting conditions. In this paper, an analytical model of a single diesel droplet impinging on the wall with different inclined angles (α) is developed in terms of βm (dimensionless maximum spreading length, the ratio of maximum spreading length to initial droplet diameter) to understand the detailed impinging dynamic process.