Search Results

To meet LEV and EU Stage III emission requirements, it is necessary for new catalytic converters to be designed which exceed light-off temperature as quickly as possible. The technical solutions are secondary air injection, active heating systems such as the electrically heated catalytic converter, and the close coupled catalytic converter. Engine control functions are extensively used to heat the converter and will to play a significant role in the future. The concept of relocating the converter to a position close to the engine in an existing vehicle involves new conflicts. Examples include the space requirements, the thermal resistance of the catalytic coating and high temperature loads in the engine compartment.

A technical approach to reduce NOx and to minimize the fuel consumption caused by the DeNOx aftertreatment system was introduced. The NEDC mode test of the HMC (Hyundai Motor Company) DeNOx system was done with a Euro 5 vehicle (ETW (Equivalent Test Weight) = 1,810 kg, 143 kW, 430 N⋅m), which resulted in that the Euro 6 legislation standards were met. The NOx and HC emissions were, respectively, measured to be 0.059 g/km and 0.087 g/km with the hydrothermal-aged catalysts, and CO₂ was increased by ≺ 4%.

Urea-SCR system consisted of combined deNOx catalysts with wide range of temperature window, injector, sensor and injection controller. Synthetic gas activity test and NOx conversion efficiency test on the engine bench were carried out to evaluate and improve the performance of this system. To better suit the application of the urea-SCR system without engine modification, temperature of catalyst and engine RPM were used as input data to control amounts of urea aqueous solution that reacts with NOx. We concentrated on designing types of deNOx catalysts and controlling amounts of urea solution under different driving conditions to achieve higher NOx reduction and wider temperature window. Designed urea-SCR system showed substantial NOx reduction performance and relatively wide temperature window under different driving conditions.

Emission of carbon dioxide from mobile sources seriously concerned to solve greenhouse effect and high price of gasoline in some countries have resulted in the development of lean-burn concept engine. In spite of many studies on the lean deNOx catalyst, we have no clear solution to obtain high fuel economy and high efficiency of NOx conversion in lean-burn application. This paper describes applicability and problems of NOx adsorber system to partial lean-burn vehicle, the development of three-way catalyst with improvement of washcoat technology based on three-way catalyst used for gasoline application, and comparison test results of evaluations is synthesized gas activity test, Federal Test Procedure (FTP) test, etc. This study shows improved three-way catalysts in partial lean- burn vehicle have max. 89% of NOx conversion in FTP without adding rich spike and regeneration functions to engine management system.

This study suggests new types of catalysts that show low hydrogen sulfide emission without scavenger such as NiO. Hydrogen sulfide can be reduced by changing the physicochemical properties of washcoat components. Synthesized gas activity tests were performed to investigate the effect of modified washcoat on hydrogen sulfide formation and catalytic activity. BET surface area tests, X- ray diffraction tests, and gas chromatography tests were also carried out to examine the characteristics of catalysts. Preparation methods for catalysts were focused on minimizing the adsorption of sulfur species on catalysts. The first approach is heat treatment of cerium oxide to reduce adsorption sites for sulfur compounds. But this leads to deterioration of CO and NOx conversion efficiencies. The second one is adding new types of promoters that increase thermal durability and dynamic oxygen storing function of cerium oxide.

This paper describes the development of THC reduction technologies compliant with SULEV regulations. Technologies embodied by the developmental work include improvement of fuel spay atomization, quick warm-up through coolant control shut off, and acceleration of fuel atomization for the fast rise of cylinder head temp inside the water jacket as well as the improvement of combustion state. The technologies likewise entail reduced HC while operating in lean A/F condition during engine warm-up with the cold lean-burn technology, individual cylinder A/F control for improvement of catalytic converting efficiency, aftertreatment such as thin-wall catalyst, HC absorber and EHC and etc., through vehicle application evaluation in cold start. We carried out an experimental as well as a practical study against SULEV regulations, and the feasibility of adopting these items in vehicle was likewise investigated.

The new concept oxidation for diesel engine has been developed. It has been designed to use under circumstances of the "dry condition" of exhausted emission, which indicates low soluble organics and high dry soot concentration under high exhaust gas temperature. For the reliability and performance of catalysts in dry condition, several design concepts were established. First of all, extremely low sulfate formation on catalyst at high temperature conditions, and an improved soluble organic burning characteristics was required. A minimization of deposition of the particulate component, especially sulfate, was obtained from the adjustment of washcoat loading and material property. Six different types of catalysts have been prepared and tested in a laboratory. Diesel vehicle test showed the possibility that soluble organic could be removed mostly with minimal sulfate formation.

In studying H2S emissions, it is desirable to have an analytical technique which is rapid, continuous, accurate and easy to use in a laboratory or vehicle exhaust environment. Typically, H2S has been measured using the EPA impinger method with collection times on the order of 1 to 2 minutes. Other techniques have been developed with significantly shorter response times. However, it has been shown that the major release of H2S occurs in less than 20 seconds after a vehicle changes from rich to lean operation. Therefore, it is highly desirable to have an H2S analytical technique with a response time of less than 10 seconds. In this paper, the benefits of use of a chemical ionization mass spectrometer (CIMS) to continuously monitor H2S and SO2, emissions are reported. Using the CIMS technique, the effects of several operating parameters on the release of H2S and SO2 from automotive catalysts were studied.

Apart from the reduction of engine-out emissions from the powerplant, the development of an efficient and reliable catalytic converter heating system is an important task of automotive engineering in the future to meet standards that will require reduction of cold start emissions. Carrying out a comprehensive study in this field, BMW has tested and evaluated possible solutions to this challenge. In additon to the electrically heated catalytic converter (E-cat) and the afterburner chamber, an incorporated burner system would meet the requirement for fast catalyst light-off in the future, particularly in the case of larger engines.

The production of the BMW ALPINA B12 5.7 with Switch-Tronic transmission provides the markets of Europe and Japan with an exclusive, luxury-orientated, high performance limited series limousine. This is the first vehicle worldwide to be fitted with the progressive exhaust gas aftertreatment technology known as the Electrically Heated Catalyst (EHC), in which the effectiveness of the power utilized is increased significantly by an alternating heating process for both catalytic converters. Only since this achievement has the implementation of the EHC been viable without extensive modification to the battery and alternator. With this exhaust gas aftertreatment concept, the emissions of this high performance vehicle will fall to less than half the maximum permissible for compliance with 1996 emission standards.

In a joint research project between industrial companies and a number of research institutes, nitrogen oxide conversion in oxygen containing exhaust gas has been investigated according to the following procedure Basic investigations of elementary steps of the chemical reaction Production and prescreening of different catalytic material on laboratory scale Application oriented screening of industrial catalyst material Catalyst testing on a lean bum gasoline engine, passenger car diesel engines (swirl chamber and DI) and on a DI truck engine Although a number of solid body structures show nitrogen oxide reduction by hydrocarbons, only noble metal containing catalysts and transition metal exchanged zeolites gave catalytic efficiencies of industrial relevance. A maximum of 25 % NOx reduction was found in the European driving cycle for passenger cars, about 40 % for truck engines in the respective European test.

A new exhaust system has been developed to cope with post-SULEV (Super Ultra-Low Emissions Vehicle) regulation by newly designed hardware of exhaust system. This paper will describe the various new technologies used for achieving the post-SULEV standards, such as Conicat (cone-type metal catalyst), dual-wall pipe, pipe-type metal catalyst, ultra thin wall monolith and HC trap system for the improvement of catalyst light-off time. The tested data on 2.0L SULEV vehicle indicate that Conicat(cone-type metal catalyst) and HC trap (hydrocarbon absorbing catalyst) have more positive characteristics, and are expected to show the enhanced HC reduction performance with the optimization of emission system.

For the BMW V8 engine, a new LEV/EU3 emission concept has been developed by improvements to the previous engine management and secondary air supply and a complete new exhaust system. Beside the emission limits, also high engine output targets and high operating reliability were targeted. In addition the new exhaust system had to meet low cost targets. Based on these requirements an exhaust concept with separate pre catalyst and main catalyst was chosen. To reduce the heat mass and to optimize the pressure drop, 4.3mil/400cpsi thin wall ceramic substrates were used for the pre and main catalyst.

The shape of unit cell of catalytic converter has great influence on the conversion efficiency and pressure drop characteristics. Therefore, the properties of design parameters of catalyst monolith were analyzed and the parameters of various cell shapes of catalyst were compared. Also, the numerical study of a three dimensional compressible flow in a Close-coupled Catalyst Converter (CCC) system was performed to investigate the flow characteristics and the flow distribution of exhaust gases. Unsteady flow analysis shows that severe interferences of each pulsating exhaust gas flow as well as geometric factors (junction, mixing pipe, cell shape etc.) influence greatly on the flow uniformity and flow characteristic in substrate. The results can be applied for the catalytic converter design.

Polylactide (PLA), which is one of the most important biocompatible polyesters that are derived from annually renewable biomass such as corn and sugar beets, has attracted much attention for automotive parts application. The manufacturing method of PLA is the ring-opening polymerization of the dimeric cyclic ester of lactic acid, lactide. For the PLA composites including stereocomplexed with L- and D-PLA, we developed the unit processes such as fermentation, separation, lactide conversion, and polymerization. We investigated D-lactic acid fermentation with a view to obtaining the strains capable of producing D-lactic acid, and through catalyst screening test for polycondensation and depolymerization reactions, we got a new method which shortens the whole reaction time of lactide synthesis step. Poly(d-lactide) is obtained from the ring-opening polymerization of d-lactide. Also we investigated several catalysts and polymerization conditions.

This paper describes how to meet LEVII ULEV70 emission standards and minimize fuel consumption with the combined NOx after-treatment (LNT+SCR) system for diesel vehicles. Through analysis of LNT's functionality and characteristics in a LNT+SCR combined after-treatment system, allowed a new control strategy to be established, different from the existing LNT-only system. In the 200°C or higher condition where SCR can provide the most stable NOx conversion efficiency, rich regeneration of LNT was optimized to minimize LNT deterioration and fuel consumption. Optimized mapping between rapid heat up strategy and raw NOx reduction maximized LNT's NOx conversion efficiency during the intervals when it is not possible for SCR to purify NOx This study used bench aged catalysts which were equivalent to 150K full useful life.