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Ammonia Selective Catalytic Reduction (SCR) is adapted for a variety of applications to control nitrogen oxides (NOx) in diesel engine exhaust. The most commonly used catalyst for SCR in established markets is Cu-Zeolite (CuZ) due to excellent NOx conversion and thermal durability. However, most applications in emerging markets and certain applications in established markets utilize vanadia SCR. The operating temperature is typically maintained below 550°C to avoid vanadium sublimation due to active regeneration of the diesel particulate filter (DPF), or some OEMs may eliminate the DPF because they can achieve particulate matter (PM) standard with engine tuning. Further improvement of vanadia SCR durability and NOx conversion at low exhaust gas temperatures will be required in consideration of future emission standards.

Ammonia Selective Catalytic Reduction (SCR) is a key emission control component utilized in diesel engine applications for NOx reduction. There are several types of SCR catalyst currently in the market: Cu-Zeolite, Fe-Zeolite and Vanadia. Diesel vehicle and engine manufacturers down select their production SCR catalyst primarily based on vehicle exhaust gas temperature operation, ammonia dosing strategy, fuel quality, packaging envelope and cost. For Vanadia SCR, the operating temperature is normally controlled below 550oC to avoid vanadium sublimation. In emerging markets, the Vanadia SCR is typically installed alone or downstream of the DOC with low exhaust gas temperature exposure. Vanadia SCR is also utilized in some European applications with passive DPF soot regeneration. However, further improvement of Vanadia SCR NOx conversion at low exhaust gas temperatures will be required to meet future emission regulations (i.e.: HDD Phase 2 GHG).

Honeycomb substrates are widely used to reduce harmful emissions from gasoline engines and are exposed to numerous thermal shocks during their lifetime making thermal shock resistance one of the key factors in designing honeycomb substrates. More stringent emission regulations will require the honeycomb substrates to be lighter in weight to improve light-off performance and to have better thermal shock resistance than conventional honeycomb substrates to handle higher expected temperature gradients. Thermal shock resistance is generally evaluated on a substrate by evaluating the thermal strain caused by temperature gradients inside the substrate during durability testing [1,2]. During the test, a heated substrate is cooled at a surface face to generate temperature gradients while the temperature inside the honeycomb substrate is monitored by multiple thermocouples.

The production of the BMW ALPINA B12 5.7 with Switch-Tronic transmission provides the markets of Europe and Japan with an exclusive, luxury-orientated, high performance limited series limousine. This is the first vehicle worldwide to be fitted with the progressive exhaust gas aftertreatment technology known as the Electrically Heated Catalyst (EHC), in which the effectiveness of the power utilized is increased significantly by an alternating heating process for both catalytic converters. Only since this achievement has the implementation of the EHC been viable without extensive modification to the battery and alternator. With this exhaust gas aftertreatment concept, the emissions of this high performance vehicle will fall to less than half the maximum permissible for compliance with 1996 emission standards.

The present paper describes the results of a joint development program focussing on a system approach to meet the EURO IV emission standards for an upper class passenger car equipped with a newly developed high displacement gasoline engine. Based on the well known catalyst systems of recent V6- and V8-engines for the EURO III emission standards with a combination of close coupled catalysts and underfloor catalysts, the specific boundary conditions of an engine with an even larger engine displacement had to be considered. These boundary conditions consist of the space requirements in the engine compartment, the power/torque requirements and the cost requirements for the complete aftertreatment system. Theoretical studies and computer modeling showed essential improvements in catalyst performance by introducing thin wall substrates with low thermal inertia as well as high cell densities with increased geometric surface area.

Selective catalyst reduction (SCR) using cordierite honeycomb substrate is generally used as a DeNOx catalyst for diesel engines exhaust in both on-road and commercial off-highway vehicles to meet today’s worldwide emission regulations. Worldwide NOx emission regulations will become stricter, as represented by CARB2027 and EuroVII. Technologies which can achieve further lower NOx emissions are required. Recently, several technologies, like increased SCR catalyst loading amount on honeycomb substrates, and additional SCR catalyst volume in positions closer to the engine are being considered to achieve ultra-low NOx emissions. However, undesirable pressure drop increase and enlarging after treatment systems will be caused by adopting these technologies. Therefore, optimization of the material and honeycomb cell structure for SCR is inevitable to achieve ultra-low NOx emissions, while minimizing any system drawbacks.

Fleet average SULEV30 emissions over FTP-75 must be met under full implementation of US Tier 3/LEV III emission regulation in 2025. The majority of SULEV30 certified 2021 model year vehicles are equipped with ≤ 2L displacement engines and some models adopt hybrid powertrain systems. Pickup trucks account for > 20% of passenger vehicles in the US. They could represent a quick route to meet fleet average SULEV30 targets. The newest pickup truck models are typically ULEV50 or ULEV70 certified. To reach SULEV30 or lower emission category, total tailpipe emissions must be reduced by more than 40%. Improvement of cold start emission is essential because over 70% of regulated emission is emitted during the first 60 seconds of a drive cycle with current engine and aftertreatment technology. High porosity (HP) ceramic substrate is designed to reduce thermal mass and time required to reach three-way catalyst (TWC) active temperature compared to conventional ceramic substrates.

For the measurement of exhaust emissions, Constant Volume Sampling (CVS) technology is recommended by legislation and has proven its practical capability in the past. However, the introduction of new low emission standards has raised questions regarding the accuracy and variability of the CVS system when measuring very low emission levels. This paper will show that CVS has the potential to achieve sufficient precision for certification of SULEV concepts. Thus, there is no need for the introduction of new test methods involving high cost. An analysis of the CVS basic equations indicates the importance of the Dilution Factor (DF) for calculating true mass emissions. A test series will demonstrate that, by adjusting the dilution and using state of the art analyzers, the consistency of exhaust results is comparable with those of LEV concepts, measured with conventional CVS systems and former standard analyzers.

The LEV II and SULEV/PZEV emission standards legislated by the US EPA and the Californian ARB will require continuous reduction in the vehicles' emission over the next several years. Similar requirements are under discussion in the European Union (EU) in the EU Stage V program. These future emission standards will require a more efficient after treatment device that exhibits high activity and excellent durabilty over an extended lifetime. The present study summarizes the findings of a joint development program targeting such demanding future emission challenges, which can only be met by a close and intensive co-operation of the individual expert teams. The use of active systems, e.g. HC-adsorber or electrically heated light-off catalysts, was not considered in this study. The following parameters were investigated in detail: The development of a high-tech three-way catalyst technology is described being tailored for applications on ultra thin wall ceramic substrates (UTWS).

Development of the ultra thin wall ceramic catalytic substrate is necessary to meet increasingly strict emissions regulations. The cell walls need to be thinner in order to improve the warm-up characteristics related to the reduction of emissions and to lower the back pressure. However, the thinner the wall thickness, the smaller the mechanical strength of the substrate becomes. For substrates with 2.5mil wall thickness, we densified a conventional material with 35% porosity to less than 30%[1] to improve erosion resistance. Furthermore, for substrates less than 2.5mil wall thickness, a denser material and strengthened end surface is necessary to protect against erosion. In addition to that, we think that a reinforced periphery is necessary for isostatic strength. In this paper, we evaluated the effect of a densified material, strengthened end surface, and a reinforced periphery.