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The goal of reducing the impact of road transportation on the environment can be reached by different approaches. The use of non-fossil synthetic fuels from renewable energy sources in the entire fleet of internal combustion engine vehicles is only one promising pathway to minimize the vehicle’s carbon footprint during the use phase. The steadily tightening emissions legislation confront the developers of future combustion engines with major challenges: Historically, the chemical and physical improvement of the combustion process, tail pipe emissions reduction and the development of optimized after-treatment systems were linked to improvements in fuel quality. In order to further decrease exhaust gas emissions, the optimization of the chemical composition of renewable fuels are a basic requirement.

Investigations were performed, in which the emission behavior of renewable and conventional fuels of different composition and renewable fuel components was observed. The influence of the start of injection on the emissions at WOT was investigated. This shows how much wall and valve wetting as well as the available evaporation time affects the mixture formation of the different fuels. Further, the air fuel ratio in an operating point for catalytic converter heating, with medium engine temperatures, was varied. This shows the ability of evaporation of the fuels at engine warm-up conditions and sub-stochiometric λ-values. The studied fuels were four fuel mixtures of significantly different composition of which three were compliant with the European fuel standard EN 228. A RON 98 in-field fuel, a Euro 6 reference fuel, an Anti-Spark-Fouling (ASF) fuel (designed for minimum soot production) and a potentially completely renewable, thus CO2-neural, fuel, which is designed by Dr. Ing. h.c.

Investigations were performed, in which fuels and fuel components were compared regarding gaseous as well as particulate number (PN) emissions. The focus on the selection of the fuel components was set on the possibility of renewable production, which lead to Ethanol, as the classic bio-fuel, Isopropanol, Isobutanol and methyl tert-butyl ether (MTBE). As fuels, a Euro 6 (EU6) reference fuel, an anti-spark-fouling (ASF) fuel, a European Super Plus (RON 98) in-field fuel and a potentially completely renewable fuel, which was designed by Porsche AG (named POSYN), were chosen. The composition of the fuels differs significantly which results in large differences in the exhaust gas emissions. The fuels, except ASF, are compliant with the European fuel standard EN 228.The experiments chosen were a variation of the start of injection (SOI) at different load points at a constant engine speed of 2000 rpm, amongst others.