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Polyoxymethylene dimethyl ethers (OME) are synthetic fuels, which offer the property of sustainability because the reactants of production base on hydrogen and carbon dioxide on the one hand, and the air pollution control in consequence of a soot-free combustion in a diesel engine on the other hand. High exhaust gas recirculation (EGR) rates are a promising measure for nitrogen oxide (NOx) reduction without increasing particle emissions because of the resolved soot-NOx trade-off. However, EGR rates towards stoichiometric combustion in OME operation reveals other trade-offs such as methane and formaldehyde emissions. To avoid these, a lean mixture with a combination of EGR and exhaust after-treatment with selective catalytic reduction (SCR) is useful. The limitation of urea dosing due to the light-off temperature of SCR systems requires heating measures.