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To meet LEV and EU Stage III emission requirements, it is necessary for new catalytic converters to be designed which exceed light-off temperature as quickly as possible. The technical solutions are secondary air injection, active heating systems such as the electrically heated catalytic converter, and the close coupled catalytic converter. Engine control functions are extensively used to heat the converter and will to play a significant role in the future. The concept of relocating the converter to a position close to the engine in an existing vehicle involves new conflicts. Examples include the space requirements, the thermal resistance of the catalytic coating and high temperature loads in the engine compartment.

The study of oil emission is of essential interest for the engine development of modern cars, as well as for the understanding of hydrocarbon emissions especially during cold start conditions. A laser mass spectrometer has been used to measure single aromatic hydrocarbons in unconditioned exhaust gas of a H2-fueled engine at stationary and transient motor operation. These compounds represent unburned oil constituents. The measurements were accompanied by FID and GC-FID measurements of hydrocarbons which represent the burned oil constituents. The total oil consumption has been determined by measuring the oil sampled by freezing and weighing. It has been concluded that only 10 % of the oil consumption via exhaust gas has burned in the cylinders. A correlation of the emission of single oil-based components at ppb level detected with the laser mass spectrometer to the total motor oil emission has been found.

Flame Ionization Detectors (FID) can be used to detect organic hydrocarbons that occur in plastics, lacquers, adhesives, solvents and gasoline. These substances are ionized in the hydrogen flame of the FID. The ionization current that is produced depends on the amount of hydrocarbon in the sample. With the lowering of emissions limits, measuring instruments, including the FID, have to be able to detect very low values. For SULEV (Super-Ultra Low Emissions Vehicle) measurements the accuracy and also the general applicability of the CVS (Constant Volume Sampling) measuring technique are now questioned. Basic understanding is necessary to ask the right questions. One important issue is the science behind the measurement principle of the FID. And in this case especially the influence of contamination of the operating gases, cross sensitivity and data processing on the Limit of Detection (LOD).

A sensitive laser mass spectrometer is being developed for fast multicomponent engine exhaust analyses. The features of the system meet the requirements of the analysis problems at dynamic motor test stands: detection of all organic and inorganic exhaust constituents of concentrations higher than 1 ppm simultaneous detection of up to 12 selectable exhaust compounds with 100 Hz repetition rate 2 millisecond time precision relative to the motor phase. precise sampling location everywhere in the exhaust pipe system, e.g. single valve or cylinder exhaust gas analysis ruggedness for operation at engine test facilities The time and space resolution allows the tracking of the different exhaust components during one and more motor cycle in static and transient engine operations. This information is essential for an understanding of the combustion processes, which is necessary for the development of the engine and engine control and other efforts to reduce emission of pollutants.

A new multicomponent exhaust gas analyzer has been applied to investigate the time-resolved concentrations of the aromatic hydrocarbon exhaust components benzene, toluene, xylene, trimethyl benzene under dynamic engine operation, such as sudden change of speed and load, misfiring and switching off the fuel mixture control. The analyzer consisting of a compact laser mass spectrometer is capable of measuring the concentrations of the individual aromatic hydrocarbon compounds simultaneously with 1 ppm sensitivity at a sampling rate of 50 Hz corresponding to a sampling period of 20 ms. High concentration peaks are observed for these substances at instationary motor operation. However, whereas the real-time concentrations of toluene, xylene, and trimethyl benzene show equal dependence on motor speed and load a different behavior has been observed for benzene even during the emission phase of single combustion cycles.

In a joint research project between industrial companies and a number of research institutes, nitrogen oxide conversion in oxygen containing exhaust gas has been investigated according to the following procedure Basic investigations of elementary steps of the chemical reaction Production and prescreening of different catalytic material on laboratory scale Application oriented screening of industrial catalyst material Catalyst testing on a lean bum gasoline engine, passenger car diesel engines (swirl chamber and DI) and on a DI truck engine Although a number of solid body structures show nitrogen oxide reduction by hydrocarbons, only noble metal containing catalysts and transition metal exchanged zeolites gave catalytic efficiencies of industrial relevance. A maximum of 25 % NOx reduction was found in the European driving cycle for passenger cars, about 40 % for truck engines in the respective European test.

The real-time concentrations of benzene, toluene, xylene, trimethyl-benzene and naphthalene in vehicle exhaust have been monitored during the FTP-cycle with a time-resolution of 20 ms and a sensitivity of 50 ppb. Using a laser mass spectrometer, the aromatic hydrocarbons in unconditioned exhaust gas at sampling positions behind the exhaust valve, before and behind the catalytic converter have been analyzed. The comparison of the emissions sampled before and behind the catalytic converter reveals the effect of dealkylation of the aromatic hydrocarbons in the catalytic converter. Whereas most of the aromatic hydrocarbons are burned in the hot catalytic converter, however, bursts of aromatic hydrocarbons are released at transient motor operation. In these moments, which can be attributed to phases of closed throttle valve and very low engine load at gear changes, a significant part of the C1-, C2- and C3- benzenes has been converted into benzene.

For development of new engines a ‘general purpose ECU’ for spark ignition engines with up to 12 cylinders has been developed. As part of this ECU a DSP (Digital Signal Processor)-based measurement unit for high frequency combustion analysis has been integrated. In this paper, details about this signal processing platform are given. The DSP-unit has 24 analog input channels. 12 channels are used for cylinder pressure measurement; the other 12 channels are general purpose ones. For example, they can be used for ionic current analysis. Additional digital inputs allow measurement of crank speed and crank speed variations. This is an important topic for misfire detection as part of the OBD regulations.

Synthetic fuels for internal combustion engines offer CO2-neutral mobility if produced in a closed carbon cycle using renewable energies. C1-based synthetic fuels can offer high knock resistance as well as soot free combustion due to their molecular structure containing oxygen and no direct C-C bonds. Such fuels as, for example, dimethyl carbonate (DMC) and methyl formate (MeFo) have great potential to replace gasoline in spark-ignition (SI) engines. In this study, a mixture of 65% DMC and 35% MeFo (C65F35) was used in a single-cylinder research engine to determine friction losses in the piston group using the floating-liner method. The results were benchmarked against gasoline (G100). Compared to gasoline, the density of C65F35 is almost 40% higher, but its mass-based lower heating value (LHV) is 2.8 times lower. Hence, more fuel must be injected to reach the same engine load as in a conventional gasoline engine, leading to an increased cooling effect.