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An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

The high load limit of a boosted homogeneous-charge-compression-ignition (HCCI) engine operating on negative-valve-overlap (NVO) was assessed. When operating under stoichiometric condition with no external dilution, the load, as measured by the net indicated mean effective pressure (NIMEP), increased with increase in manifold absolute pressure (MAP), and with decrease in trapped amount of residual gas. The maximum pressure rise rate (MPRR), however, also increased correspondingly. When the MAP and the amount of residual gas were adjusted so that the engine operating point could be held at a constant MPRR value, the NIMEP increased with the simultaneous decrease in MAP and residual until the misfire limit was reached. Therefore if a MPRR ceiling is imposed, the high load limit of an HCCI engine is at the intersection of the constraining MPRR line and the misfire line.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

The effects of charge motion and laminar flame speeds on combustion and exhaust temperature have been studied by using an air jet in the intake flow to produce an adjustable swirl or tumble motion, and by replacing the nitrogen in the intake air by argon or CO₂, thereby increasing or decreasing the laminar flame speed. The objective is to examine the "Late Robust Combustion" concept: whether there are opportunities for producing a high exhaust temperature using retarded combustion to facilitate catalyst warm-up, while at the same time, keeping an acceptable cycle-to-cycle torque variation as measured by the coefficient of variation (COV) of the net indicated mean effective pressure (NIMEP). The operating condition of interest is at the fast idle period of a cold start with engine speed at 1400 RPM and NIMEP at 2.6 bar. A fast burn could be produced by appropriate charge motion. The combustion phasing is primarily a function of the spark timing.

The increasing use of gasoline direct injection (GDI) engines coupled with the implementation of new particulate matter (PM) and particle number (PN) emissions regulations requires new emissions control strategies. Gasoline particulate filters (GPFs) present one approach to reduce particle emissions. Although primarily composed of combustible material which may be removed through oxidation, particle also contains incombustible components or ash. Over the service life of the filter the accumulation of ash causes an increase in exhaust backpressure, and limits the useful life of the GPF. This study utilized an accelerated aging system to generate elevated ash levels by injecting lubricant oil with the gasoline fuel into a burner system. GPFs were aged to a series of levels representing filter life up to 150,000 miles (240,000 km). The impact of ash on the filter pressure drop and on its sensitivity to soot accumulation was investigated at specific ash levels.

To meet future particle mass and particle number standards, gasoline vehicles may require particle control, either by way of an exhaust gas filter and/or engine modifications. Soot levels for gasoline engines are much lower than diesel engines; however, non-combustible material (ash) will be collected that can potentially cause increased backpressure, reduced power, and lower fuel economy. The purpose of this work was to examine the ash loading of gasoline particle filters (GPFs) during rapid aging cycles and at real time low mileages, and compare the filter performances to both fresh and very high mileage filters. Current rapid aging cycles for gasoline exhaust systems are designed to degrade the three-way catalyst washcoat both hydrothermally and chemically to represent full useful life catalysts. The ash generated during rapid aging was low in quantity although similar in quality to real time ash. Filters were also examined after a low mileage break-in of approximately 3000 km.

The effects of cooled exhaust gas recirculation (EGR) on a boosted direct-injection (DI) spark ignition (SI) engine operating at stoichiometric equivalence ratio, gross indicated mean effective pressure of 14-18 bar, and speed of 1500-2500 rpm, are studied under constant fuel condition at each operating point. In the presence of EGR, burn durations are longer and combustion is more retard. At the same combustion phasing, the indicated specific fuel consumption improves because of a decrease in heat loss and an increase in the specific heat ratio. The knock limited spark advance increases substantially with EGR. This increase is due partly to a slower combustion which is equivalent to a spark retard, as manifested by a retarded value of the 50% burn point (CA50), and due partly to a slower ignition chemistry of the diluted charge, as manifested by the knock limited spark advance to beyond the value offered by the retarded CA50.

Selective catalytic reduction (SCR) of nitrogen oxides (NOx) is used in diesel-fueled mobile applications where urea is an added reducing agent. We show that the Ultera® dual-stage catalyst, with intercooling aftertreatment system, intrinsically performs the function of the SCR method in nominally stoichiometric gasoline vehicle engines without the need for an added reductant. We present that NOx is reduced during the low-temperature operation of the dual-stage system, benefiting from the typically periodic transient operation (acceleration and decelerations) with the associated swing in the air/fuel ratio (AFR) inherent in mobile applications, as commonly expected and observed in real driving. The primary objective of the dual-stage aftertreatment system is to remove non-methane organic gases (NMOG) and carbon monoxide (CO) slip from the vehicle’s three-way catalyst (TWC) by oxidizing these constituents in the second stage catalyst.

In order to meet more stringent evaporative emissions requirements, multiple advancements in vehicle fuel system and carbon canister technologies have been made. Regardless of technological advancements, the vapor pressure of the fuel remains a vital property in controlling evaporative emissions. A series of tests were performed to explore the effects of vapor pressure on multiday diurnal evaporative emissions for 9 and 10 psi Reid Vapor Pressure (RVP) 10% ethanol (E10) gasoline-blend fuels, followed by tests with 7 psi RVP E10 gasoline on a subset of the same vehicles. A test procedure was developed to monitor evaporative emissions, canister loading profiles and breakthrough emissions for each of the fuels. A total of five vehicles were tested on all 3 fuels, blended to represent 7, 9, and 10 psi at sea level. Tests were run over 14 days using the United States (U.S.)

This paper reviews the relevant literature on the effects of sulfated ash, phosphorus, and sulfur on DPF, LNT, and SCR catalysts. Exhaust backpressure increase due to DPF ash accumulation, as well as the rate at which ash is consumed from the sump, were the most studied lubricant-derived DPF effects. Based on several studies, a doubling of backpressure can be estimated to occur within 270,000 to 490,000 km when using a 1.0% sulfated ash oil. Postmortem DPF analysis and exhaust gas measurements revealed that approximately 35% to 65% less ash was lost from the sump than was expected based on bulk oil consumption estimates. Despite significant effects from lubricant sulfur and phosphorus, loss of LNT NOX reduction efficiency is dominated by fuel sulfur effects. Phosphorus has been determined to have a mild poisoning effect on SCR catalysts. The extent of the effect that lubricant phosphorus and sulfur have on DOCs remains unclear, however, it appears to be minor.

A novel engine management strategy for achieving fast catalyst light-off without the use of an exhaust air pump in a port-fuel-injected, spark ignition engine was developed. A conventional 4-cylinder engine was operated with three cylinders running rich and the fourth one as an air pump to supply air to the exhaust manifold. Under steady-state cold coolant conditions, this strategy achieved near total oxidation of CO and HC with sufficiently retarded spark timing, resulting in a 400% increase in feedgas enthalpy flow and a 90% reduction in feedgas HC emissions compared to conventional operation. The strategy was also evaluated for crank starts. Using the existing engine hardware, implementing the strategy resulted in a reduction in catalyst light-off time from 28.0 seconds under conventional operation to 9.1 seconds.

Introduction of an array of new electrical and electronic features into future vehicles is generating vehicle electrical power requirements that exceed the capabilities of today's 14 volt electrical systems. In the near term (5 to 10 years), the existing 14V system will be marginally capable of supporting the expected additional loads with escalating costs for the associated charging system. However, significant increases in vehicle functional content are expected as future requirements to meet longer-term (beyond 10 years) needs in the areas of emission control, fuel economy, safety, and passenger comfort. A higher voltage electrical system will be required to meet these future requirements. This paper explores the functional needs that will mandate a higher voltage system and the benefits derivable from its implementation.

This paper explores the combined effects of boosting, intake air temperature, trapped residual gas fraction, and dilution on the Maximum Pressure Rise Rate (MPRR) in a boosted single cylinder gasoline HCCI engine with combustion controlled by negative valve overlap. Dilutions by both air and by cooled EGR were used. Because of the sensitivity of MPRR to boost, the MPRR constrained maximum load (as measured by the NIMEP) did not necessarily increase with boosting. At the same intake temperature and trapped residual gas fraction, dilution by recirculated burn gas was effective in reducing the MPRR, but dilution by air increased the value of MPRR. The dependence of MPRR on the operating condition was interpreted successfully by a simple thermodynamic analysis that related the MPRR value to the volumetric heat release rate.

A new diesel engine, called the 6.7L Power Stroke® V-8 Turbo Diesel and code named "Scorpion" was designed and developed by Ford Motor Company for the full-size pickup truck and light commercial vehicle markets. A high pressure Exhaust Gas Recirculation (EGR) layout in combination with a Variable Geometry Turbine (VGT) is used to deliver cooled EGR for in-cylinder NOx reduction. The cylinder-to-cylinder variation of EGR and swirl ratio is tightly controlled by the careful design of the EGR mixer and intake system flow path to reduce variability of cylinder-out PM and NOx emissions. 3D-CFD studies were used to quickly screen several EGR mixer designs based on mixing efficiency and pressure drop considerations. To optimize the intake system, 1D-3D co-simulation methodology with AVL-FIRE and AVL-BOOST has been used to assess the cylinder-to-cylinder EGR distribution and dynamic swirl.

The combustion process after auto-ignition is investigated. Depending on the non-uniformity of the end gas, auto-ignition could initiate a flame, produce pressure waves that excite the engine structure (acoustic knock), or result in detonation (normal or developing). For the “acoustic knock” mode, a knock intensity (KI) is defined as the pressure oscillation amplitude. The KI values over different cycles under a fixed operating condition are observed to have a log-normal distribution. When the operating condition is changed (over different values of λ, EGR, and spark timing), the mean (μ) of log (KI/GIMEP) decreases linearly with the correlation-based ignition delay calculated using the knock-point end gas condition of the mean cycle. The standard deviation σ of log(KI/GIMEP) is approximately a constant, at 0.63. The values of μ and σ thus allow a statistical description of knock from the deterministic calculation of the ignition delay using the mean cycle properties

U.S. federal vehicle emission standards effective in 2007 require tight control of NOx and hydrocarbon emissions. For light-duty vehicles, the current standard of Tier 2 Bin 5 is about 0.07 g/mi NOx and 0.09 g/mi NMOG (non-methane organic gases) at 120,000 mi. However, the proposed future standard is 0.03 g/mi for NMOG + NOx (~SULEV30) at 150,000 mi. There is a significant improvement needed in catalyst system efficiencies for diesel vehicles to achieve the future standard, mainly during cold start. In this study, a less than 6000 lbs diesel truck equipped with an advanced urea Selective Catalytic Reduction (SCR) system was used to pursue lower tailpipe emissions with an emphasis on vehicle calibration and catalyst package. The calibration was tuned by optimizing exhaust gas recirculation (EGR) fuel injection and cold start strategy to generate desirable engine-out emissions balanced with reasonable temperatures.

Exhaust gas recirculation (EGR) coolers are commonly used in diesel engines to reduce the temperature of recirculated exhaust gases in order to reduce NOx emissions. The presence of a cool surface in the hot exhaust causes particulate soot deposition as well as hydrocarbon and water condensation. Fouling experienced through deposition of particulate matter and hydrocarbons results in degraded cooler effectiveness and increased pressure drop. In this study, a visualization test setup is designed and constructed so that the effect of water condensation on the deposit formation and growth at various coolant temperatures can be studied. A water-cooled surrogate rectangular channel is employed to represent the EGR cooler. One side of the channel is made of glass for visualization purposes. A medium duty diesel engine is used to generate the exhaust stream.

For spark-ignition gasoline engines operating under the wide speed and load conditions required for light duty vehicles, ignition quality limits the ability to minimize fuel consumption and NOx emissions via dilution under light and part load conditions. In addition, during transients including tip-outs, high levels of dilution can occur for multiple combustion events before either the external exhaust gas can be adjusted and cleared from the intake or cam phasing can be adjusted for correct internal dilution. Further improvement and a thorough understanding of the impact of the ignition system on combustion near the dilution limit will enable reduced fuel consumption and robust transient operation. To determine and isolate the effects of multiple parameters, a variable output ignition system (VOIS) was developed and tested on a 3.5L turbocharged V6 homogeneous charge direct-injection gasoline engine with two spark plug gaps and three ignition settings.

As a renewable energy source, the ethanol fuel was employed with a diesel fuel in this study to improve the cylinder charge homogeneity for high load operations, targeting on ultra-low nitrogen oxides (NOx) and smoke emissions. A light-duty diesel engine is configured to adapt intake port fuelling of the ethanol fuel while keeping all other original engine components intact. High load experiments are performed to investigate the combustion control and low emission enabling without sacrificing the high compression ratio (18.2:1). The intake boost, exhaust gas recirculation (EGR) and injection pressure are independently controlled, and thus their effects on combustion and emission characteristics of the high load operation are investigated individually. The low temperature combustion is accomplished at high engine load (16~17 bar IMEP) with regulation compatible NOx and soot emissions.

A model has been developed which predicts engine-out hydrocarbon (HC) emissions for spark-ignition engines. The model consists of a set of scaling laws that describe the individual processes that contribute to HC emissions. The model inputs are the critical engine design and operating variables. This set of individual process scaling relations was then calibrated using production spark-ignition engine data at a fixed light-load operating point. The data base consisted of engine-out HC emissions from two-valve and four-valve engine designs with variations in spark timing, valve timing, coolant temperature, crevice volume, and EGR, for five different engines. The model was calibrated separately for the three different engines to accommodate differences in engine design details and to determine the relative magnitudes of each of the major sources. A good fit to this database was obtained.