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In this research, simulation and experimental investigation of H2 emission formation and its influence during the post-oxidation phenomenon were conducted on a turbo-charged spark ignition engine. During the post-oxidation phenomenon phase, rich air-fuel ratio (A/F) is used inside the cylinder. This rich excursion gives rise to the production of H2 emission by various reactions inside the cylinder. It is expected that the generation of this H2 emission can play a key role in the actuation of the post-oxidation and its reaction rate if enough temperature and mixing strength are attained. It is predicted that when rich combustion inside the cylinder will take place, more carbon monoxide (CO)/ Total Hydro Carbon (THC)/ Hydrogen (H2) contents will arrive in the exhaust manifold. This H2 content facilitates in the production of OH radical which contributes to the post-oxidation reaction and in-turn can aid towards increasing the enthalpy.