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The performance of a commercial Cu-zeolite SCR catalyst after differing degrees of hydrothermal aging (aged for 72 hours at 500, 700 and 800°C with 10% moisture balanced with air) was studied by spatially resolving different key reactions using gas-phase FTIR measurements. Gases were sampled along a channel at different positions and analyzed using FTIR, which overcomes the interference of water and nitrogen on ammonia concentration detection encountered in standard mass spectrometer-based spatial resolution measurements. The NO:NO₂ concentration ratio was changed so that the standard (NO:NO₂ = 1:0), fast (NO:NO₂ = 1:1) and NO₂ (NO:NO₂ = 0:1) SCR reactions could be investigated as a function of the catalyst's hydrothermal aging extent. In addition, the effects of hydrothermal aging on the activity of NH₃ and NO oxidation were also investigated. Hydrothermal aging had little effect on NO oxidation activity.

In this paper, a closed loop path planning and tracking control approach of collision avoidance for autonomous vehicle is proposed. The two-level model predictive control (MPC) is proposed for the path planning and tracking. The upper-level MPC is designed based on the simple vehicle kinematic model to calculate the collision-free trajectory and the potential field method is adopted to evaluate the collision risk and generate the cost function of the optimization problem. The lower-level MPC is the trajectory-tracking controller based on the vehicle dynamics model that calculates the desired control inputs. Finally the control inputs are distributed to steering wheel angle and motor torque via optimal control vectoring algorithm. Test cases are established on the Simulink/CarSim platform to evaluate the performance of the controller.