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Proposed LEV-III emission level will require improvements in NMOG, CO and NOx emissions as measured over FTP and US06 emission cycles. Incremental improvements in washcoat technologies, cold start calibration and catalyst system design are required to develop a cost effective solution set. New catalyst technologies demonstrated both lower HC and NOx emissions with 25% less platinum group metals (PGM). FTP and US06 emissions were measured on a 4-cylinder 2.4L application which compares a close-coupled converter and close-coupled + underfloor converter systems. A PGM placement study was performed with the close-coupled converter system employing these new catalyst technologies. Emissions results suggest that the placement of PGM is critical in minimizing emissions and PGM costs.

The fuel air ratio imbalance between individual cylinders can result in poor fuel economy and severe exhaust emissions. Individual cylinder fuel air ratio control is one of the important techniques used to improve fuel economy and reduce exhaust emission. California Air Resources Board (CARB) also has required automotive manufacturers to equip with on-board diagnosis system for cylinder fuel air ratio imbalance detection starting in 2011. However, one of the most challenging tasks for the individual cylinder fuel air ratio control and cylinder imbalance diagnosis is how to retrieve the cylinder fuel air ratio information effectively at low cost. This paper presents a novel and practical signal processing based fuel air ratio estimation method for individual cylinder fuel air ratio balance control and on-board fuel air ratio imbalance diagnosis.

PEM fuel cell is a promising alternative green power source for vehicular application. However, its performance, cost and durability are sensitively impacted by its sensitivity to impurities in both fuel and air streams. In this study, a multi-phase multi-dimensional model with carbon monoxide in the anode side has been developed. The present model includes flow channel, gas diffusion layer, catalyst layer, and polymer electrolyte membrane, considering carbon monoxide (CO) poisoning and oxygen bleeding in the fuel stream. The model equations, based on the conservation laws for mass, momentum, energy, and species, considered in a steady state, are solved by using Fluent software. The results of the effects of CO concentration, a series of 3D simulation in anode catalyst layer, as well as oxygen bleeding, are presented, which indicate that CO has a severe influence on the performance of PEM fuel cell.

The effects of the physical and chemical properties of biodiesel fuels on the combustion process and pollutants formation in Direct Injection (DI) engine are investigated numerically by using multi-dimensional CFD models. In the current study, methyl butanoate (MB) and n-heptane are used as the surrogates for the biodiesel fuel and the conventional diesel fuel. Detailed kinetic chemical mechanisms for MB and n-heptane are implemented to simulate the combustion process. It is shown that the differences in the chemical properties between the biodiesel fuel and the diesel fuel affect the whole combustion process more significantly than the differences in the physical properties. While the variations of both the chemical and the physical properties between the biodiesel and diesel fuel influence the soot formation at the equivalent level, the variations in the chemical properties play a crucial role in the NO emissions formation.

The importance of using biodiesel as an alternative in diesel engines has been demonstrated previously. A reduction in the soot, CO and HC emissions and an increase in the NO emission burning biodiesel fuels were reported consistently in previous technical papers. However, a widely accepted NO formation mechanism for biodiesel-fueled engines is currently lacking. As a result, in past multi-dimensional simulation studies, the NO emission of biodiesel combustion was predicted unsatisfactorily. In this study, the interaction between the soot and NO formations is considered during the prediction of the soot and NO emissions in a biodiesel-fueled engine. Meanwhile, a three-step soot model and an eight NO model which includes both the thermal NO mechanism and prompt mechanism are implemented.

Improving the NOx removal efficiency of an automotive urea-based SCR system requires optimized injection system to minimize wall deposition while providing uniform distribution of exhaust gases and reductant mixture at the entrance of the catalyst. The focus of the current study is to develop and validate a three-dimensional computational model capable of simulating the urea-water-solution (UWS) spray/wall interaction. The interaction between the injected UWS spray droplets and the surrounding gas is modeled using the Eulerian-Lagrangian approach,. A specially developed multicomponent vaporization model is implemented to simulate the depletion mechanism of individual UWS droplets. The spray/wall interaction mechanism involves spray/wall impingement and wall film formation. While the spray/wall impingement mechanism is modeled using a standard criteria, the O'Rourke and Amsden model for wall film formation is modified to account for the multicomponent nature of the UWS spray.

To meet the 2010 diesel engine emission regulations, an aftertreatment system was developed to reduce HC, CO, NOx and soot. In NOx reduction, a baseline SCR module was designed to include urea injector, mixing decomposition tube and SCR catalysts. However, it was found that the baseline decomposition tube had unacceptable urea mixing performance and severe deposit issues largely because of poor hardware design. The purpose of this article is to describe necessary development work to improve the baseline system to achieve desired mixing targets. To this end, an emissions Flow Lab and computational fluid dynamics were used as the main tools to evaluate urea mixing solutions. Given the complicated urea spray transport and limited packaging space, intensive efforts were taken to develop pre-injector pipe geometry, post-injector cone geometry, single mixer design modifications, and dual mixer design options.

Using gasoline and diesel simultaneously in a dual-fuel combustion system has shown effective benefits in terms of both brake thermal efficiency and exhaust emissions. In this study, the dual-fuel approach is applied to a light-duty spark ignition (SI) gasoline direct injection (GDI) engine. Three combustion modes are proposed based on the engine load, diesel micro-pilot (DMP) combustion at high load, SI combustion at low load, and diesel assisted spark-ignition (DASI) combustion in the transition zone. Major focus is put on the DMP mode, where the diesel fuel acts as an enhancer for ignition and combustion of the mixture of gasoline, air, and recirculated exhaust gas. Computational fluid dynamics (CFD) is used to simulate the dual-fuel combustion with the final goal of supporting the comprehensive optimization of the main engine parameters.

Flame ionization detector (FID) analyzers used in emission testing to measure total hydrocarbon emissions have been operating for the last forty years on a fuel mixture of 40% H₂ and 60% helium. These mixtures were selected based on research studies reported in the literature indicating that this particular mixed fuel combination gave the best sensitivity and relative response of the different hydrocarbons present in vehicle exhaust with respect to propane, the calibration gas. During the past few years, it was announced that there is a worldwide shortage of helium which triggered the automotive industry to look for alternatives for helium to be used in FID fuels. Helium which is produced as a byproduct from natural gas fields is non-renewable, expensive, and extremely rare on the earth. Current supply cannot keep up with demand. There are only few natural gas fields producing helium and unless new natural gas fields are found, current helium amounts will continue to dwindle.

Due to increased demand for improved fuel economy and reduction in CO2 emissions, active grille shutter (AGS) has been considered as one option to increase fuel economy by reducing vehicle drag resistance. An AGS system will allow airflow through the grille when demand on cooling system or air conditioning system is high. Under conditions of light load and moderate ambient temperatures and humidity, the grille does not have to be fully open. A reduction in the effective grille size opening can be achieved by either partially or fully closing the grille through a stepped speed motor actuator. When the grille opening size is reduced, under-hood airflow will decrease. Therefore, the operating points for the grille shutter should take into account the effect of temperature rise for under-hood and underbody components and the performance of the cooling and climate control systems.

To meet TierII/LEVII emissions standards, light duty diesel (LDD) vehicles require high conversion efficiencies from the Aftertreatment Systems (ATS) for the removal of both Hydrocarbon (HC) and Nitrogen Oxide (NOx) species. The most populous configuration for LDD ATS have the Selective Catalytic Reduction (SCR) catalyst positioned on the vehicle behind the close coupled Diesel Oxidation Catalyst (DOC) and Catalyzed Diesel Particulate Filter (CDPF). This SCR position may require active heating measures which rely on the DOC/CDPF to provide heat through the combustion of HC and CO in the exhaust. Although DOCs are always impacted by their aging conditions, some aging conditions are shown to be both reversible and irreversible.

Growing concerns about the environment, energy dependency, and unstable fuel prices have increased the market share of electric vehicles. This has led to an increased demand for energy efficient routing algorithms that are optimized for electric vehicles. Traditional routing algorithms are focused on finding the shortest distance or the least time route between two points. These approaches have been working well for fossil fueled vehicles. Electric vehicles, on the other hand, require different route optimization techniques. Negative edge costs, battery power and capacity limits, as well as vehicle parameters that are only available at query time, make the task of electric vehicle routing a challenging problem. In this paper, we present a simulated solution to the energy efficient routing for electric vehicles using Particle Swarm Optimization. Simulation results show improvements in the energy consumption of the electric vehicle when applied to a start-to-destination routing problem.

The effects of propylene (C₃H₆) and dodecane (n-C₁₂H₂₆) exposure on the NH₃-based selective catalytic reduction (SCR) performance of two Cu-exchanged zeolite catalysts were investigated. The first sample was a model Cu/beta zeolite sample and the second a state-of-the-art Cu/zeolite sample, with the zeolite material characterized by relatively small pores. Overall, the state-of-the-art sample performed better than the model sample, in terms of hydrocarbon inhibition (which was reduced) and N₂O formation (less formed). The state-of-the-art sample was completely unaffected by dodecane at temperatures lower than 300°C, and only slightly inhibited (less than 5% conversion loss), for standard SCR, by C₃H₆. There was no evidence of coke formation on this catalyst with C₃H₆ exposure. The model sample was more significantly affected by hydrocarbon exposure. With C₃H₆, inhibition is associated with its partial oxidation intermediates adsorbed on the catalyst surface.