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The low-temperature performance characteristics of a commercial lean NOX trap catalyst were evaluated using infra-red thermography (IRT) before and after a high-temperature aging step. Reaction tests included propylene oxidation, oxygen storage capacity measurements, and simulated cycling conditions for NOX reduction, using H₂ as the reductant during the regeneration step of the cycle. Testing with and without NO in the lean phase showed thermal differences between the reductant used in reducing the stored oxygen and that for nitrate decomposition and reduction. IRT clearly demonstrated where NOX trapping and regeneration were occurring spatially as a function of regeneration conditions, with variables including hydrogen content of the regeneration phase and lean- and rich-phase cycle times.

Meeting regulated tailpipe emission standards requires a full system approach by automotive engineers encompassing: engine design, combustion system metrics, exhaust heat management, aftertreatment design and exhaust system packaging. Engine and combustion system design targets define desired engine out exhaust constituents, exhaust gas temperatures and oil consumption rates. Protecting required catalytic converter volume in the engine bay for stricter tailpipe emission standards is becoming more difficult. Future fuel economy mandates are leading to vehicle downsizing which is affecting all aspects of vehicle component packaging. In this study, we set out to determine the potential palladium (Pd) cost penalty as a result of increased light-off time required as a catalyst is positioned further away from the engine. Two aged converter systems with different Pd loadings were considered, and EPA FTP-75 emission tested at six different catalyst positions.

The current work aims to develop a reliable numerical model simulating the depletion and decomposition process of urea-water solution (UWS) droplets injected in a hot exhaust stream as experienced in an automotive urea-based selective catalytic reduction (SCR) system. The depleting process of individual UWS droplets in heated environment is simulated using a multicomponent vaporization model with separate depletion law for each component. While water depletion is modeled as a vaporization process, urea depletion from the UWS droplet is modeled using two different approaches. The first approach models urea depletion as a vaporization process with an experimentally determined saturation pressure. The second approach models urea depletion as a direct thermolysis process from molten urea to ammonia and isocyanic acid using various sets of kinetic parameters. Comparison with experimental data shows the superiority of modeling urea depletion as a vaporization process.

Improving the NOx removal efficiency of an automotive urea-based SCR system requires optimized injection system to minimize wall deposition while providing uniform distribution of exhaust gases and reductant mixture at the entrance of the catalyst. The focus of the current study is to develop and validate a three-dimensional computational model capable of simulating the urea-water-solution (UWS) spray/wall interaction. The interaction between the injected UWS spray droplets and the surrounding gas is modeled using the Eulerian-Lagrangian approach,. A specially developed multicomponent vaporization model is implemented to simulate the depletion mechanism of individual UWS droplets. The spray/wall interaction mechanism involves spray/wall impingement and wall film formation. While the spray/wall impingement mechanism is modeled using a standard criteria, the O'Rourke and Amsden model for wall film formation is modified to account for the multicomponent nature of the UWS spray.

Improvements to 1D engine modeling accuracy and computational speed have led to greater reliance on this simulation technology during the engine development process. The benefits of modeling show up in many ways: increased simulation iterations for better optimization, reduction in prototype hardware iterations, reduction in program timing and overall cost. In this study a 1D GT-Power model of a turbocharged engine system was used to assist in the initial design phase and throughout the program. The model was developed using Chrysler Group LLC proprietary modeling features for predictive combustion and knock event prediction. In all stages of this project the model's accuracy was improved through regular correlation with dynamometer data. This paper mainly focuses on engine compression ratio selection, turbocharger selection, and cycle-to-cycle variation/cylinder-to-cylinder variation reduction through the combination of 1D GT-Power model optimization and dynamometer tests.

CAE tools are increasingly important in the automotive design process. In part, CAE tools can be useful in reducing the number of physical prototypes required during a product development effort. CFD tools can assess and predict cylinder charge motion for proposed designs, thereby limiting the need for prototype work. Though detailed combustion simulation results could help guide product development, the time required for such simulations limits their usefulness in the context of a production program. However equally valuable information can be obtained from gas exchange analyses which require less computation time and are run only from Intake Valve opening (IVO) to spark timing. Chemical kinetics is not included in this type of analysis. Using this approach, large numbers of configurations can be evaluated in a short period of time. Every passing year automotive engineers are challenged to attain higher fuel economy targets.

To meet TierII/LEVII emissions standards, light duty diesel (LDD) vehicles require high conversion efficiencies from the Aftertreatment Systems (ATS) for the removal of both Hydrocarbon (HC) and Nitrogen Oxide (NOx) species. The most populous configuration for LDD ATS have the Selective Catalytic Reduction (SCR) catalyst positioned on the vehicle behind the close coupled Diesel Oxidation Catalyst (DOC) and Catalyzed Diesel Particulate Filter (CDPF). This SCR position may require active heating measures which rely on the DOC/CDPF to provide heat through the combustion of HC and CO in the exhaust. Although DOCs are always impacted by their aging conditions, some aging conditions are shown to be both reversible and irreversible.

The effects of propylene (C₃H₆) and dodecane (n-C₁₂H₂₆) exposure on the NH₃-based selective catalytic reduction (SCR) performance of two Cu-exchanged zeolite catalysts were investigated. The first sample was a model Cu/beta zeolite sample and the second a state-of-the-art Cu/zeolite sample, with the zeolite material characterized by relatively small pores. Overall, the state-of-the-art sample performed better than the model sample, in terms of hydrocarbon inhibition (which was reduced) and N₂O formation (less formed). The state-of-the-art sample was completely unaffected by dodecane at temperatures lower than 300°C, and only slightly inhibited (less than 5% conversion loss), for standard SCR, by C₃H₆. There was no evidence of coke formation on this catalyst with C₃H₆ exposure. The model sample was more significantly affected by hydrocarbon exposure. With C₃H₆, inhibition is associated with its partial oxidation intermediates adsorbed on the catalyst surface.