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Honda has developed, in collaboration with Hitachi Metals and Daido Steel, two types of low-nickel heat-resistant alloys for exhaust valves which are more cost effective than the conventional nickel alloys. They are NCF4015 that contains approximately 40% nickel and NCF3015 with approximately 30% nickel content. The two types of new alloys were developed based on our unique alloy design concept. Both alloys feature superb high-temperature strength and are capable of maintaining favorable material properties, even after an high-temperature exposure. The NCF4015 is compatible with the conventional Inconel 751 and 60Ni alloys in terms of high-temperature strength. The NCF3015 falls slightly behind the two metals, but overwhelms the 21-4N (SUH35) in high-temperature strength. The exhaust valves made of the two alloys developed have been used for mass production engines.

SUS301-EH is widely used as a material for exhaust system gaskets, however, at temperatures in excess of 400°C, it can not be used as gas-seal ability of the material declines due to its reduced hardness. The following methods were found to be effective in controlling the softening of stainless steel at high temperatures: (1) The addition of a nitrogen component; (2) Stabilization of the austenite structure; (3) The addition of a molybdenum component. The addition of 0.5% nitrogen to austenitic stainless steel containing molybdenum has enabled the speed of softening at high temperatures to be significantly reduced, due to strain aging by solid nitrogen below 600°C and the combined effects of precipitation hardening and control of growth of recrystallized grains through the precipitation of fine Cr2N on the dislocations and the grain boundary above 600°C.

Engine valve development trends are to first, reduce the costly metal content and secondly, increase strength or reduce weight. These developments can be used to reduce valve cost or fuel consumption or increase power. The authors developed a new strain age hardening type alloy, NCF2415C, which has both good cold forgeability and heat resistance. Its chemical composition is Fe-24Ni-15Cr-2.2Ti-1.5Al-0.5Nb-0.02C-.006B-2Cu. This new alloy and the establishment f cold forging technology made it possible to develop cold forged exhaust valves having durability equal or better than the conventional hot forged exhaust valves.