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Further improvements of internal combustion engines to reduce fuel consumption and to face future legislation constraints are strictly related to the study of mixture formation. The reason for that is the desire to supply the engine with homogeneous charge, towards the direction of a global stoichiometric blend in the combustion chamber. Fuel evaporation and thus mixture quality mostly depend on injector atomization features and charge motion within the cylinder. 3D-CFD simulations offer great potential to study not only injector atomization quality but also the evaporation behavior. Nevertheless coupling optical measurements and simulations for injector analysis is an open discussion because of the large number of influencing parameters and interactions affecting the fuel injection’s reproducibility. For this purpose, detailed numerical investigations are used to describe the injection phenomena.

There is a growing need for low-emissions concepts due to stricter emission regulations, more stringent homologation cycles, and the possibility of a ban on new engines by 2035. Of particular concern are the conditions during a cold start, when the Three-Way Catalyst is not yet heated to its light-off temperature. During this period, the catalyst remains inactive, thereby failing to convert pollutants. Reducing the time needed to reach this temperature is crucial to comply with the more stringent emissions standards. The post oxidation by means of secondary air injection, illustrated in this work, is a possible solution to reduce the time needed to reach the above-mentioned temperature. The strategy consists of injecting air into the exhaust manifold via secondary air injectors to oxidize unburned fuel that comes from a rich combustion within the cylinder.