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Future stringent emission legislation will require high efficient catalytical systems. Along with engine out emission reduction and advanced wash coat solution the substrate technology will play a key role in order to keep system costs as low as possible. The development of metallic substrates over the past few years has shown that turbulent-like substrates increase specific catalytic efficiency. This has made it possible to enhance overall performance for a specific catalytic volume or reduce the volume while keeping catalytic efficiency constant. This paper focuses on the emission efficiency of standard, TS (Transversal Structure) and LS (Longitudinal Structure) metallic substrates. In a first measurement program, standard TS and LS substrates have been compared using a 150cc 4 Stroke engine in dynamic (ECE R40) conditions. In a second test standard and LS substrate have been tested.

When performing catalyst modeling and parameter tuning it is desirable that the experimental data contain both transient and stationary points and can be generated over a short period of time. Here a method of creating such concentration transients for a full scale engine rig system is presented. The paper describes a valuable approach for changing the composition of engine exhaust gas going to a DOC (or potentially any other device) by conditioning the exhaust gas with an additional upstream DOC and/or SCR. By controlling the urea injection and the DOC bypass a wide range of exhaust compositions, not possible by only controlling the engine, could be achieved. This will improve the possibilities for parameter estimation for the modeling of the DOC.

This paper gives a thorough review of the HC/CO emissions challenge and discusses the effects of different diesel oxidation catalyst designs in a pre turbine and post turbine position on steady state and transient turbo charger performance as well as on HC and CO tailpipe emissions, fuel economy and performance of modern Diesel engines. Results from engine dynamometer testing are presented. Both classical diffusive and advanced premixed Diesel combustion modes are investigated to understand the various effects of possible future engine calibration strategies.

The increasing severity in emission standards around the world has been accompanied by the development of more active, durable catalysts. With a view to investigating the effects of high thermal aging on the catalyst performance and structure, the relationships of washcoat composition, washcoat structure, and PGM location with respect to catalyst activity were clarified using a model gas test, as well as physical and chemical characterization methods. The influence of newly developed washcoat components and PGM location on catalyst performance are also demonstrated by engine bench tests. The results obtained in this study indicate the newly developed Pt/Rh catalyst techologies are appropriate for future applications in which the catalyst will be exposed to extremely high temperature and flowrates.

It has long been recognized that the key to achieving stringent emission standards such as ULEV is the control of cold-start hydrocarbons. This paper describes a new approach for achieving excellent cold-start hydrocarbon control. The most important component in the system is a catalyst that is highly active at ambient temperature for the exothermic CO oxidation reaction in an exhaust stream under net lean conditions. This catalyst has positive order kinetics with respect to CO for CO oxidation. Thus, as the concentration of CO in the exhaust is increased, the rate of this reaction is increased, resulting in a faster temperature rise over the catalyst.

State of the art technologies of 2 and 4 stroke engines have to fulfill severe future exhaust emission regulations, with special focus on the aspects of rising performance and low cost manufacturing, leading to an important challenge for the future. In special fields of applications (e.g. mopeds, hand held or off-road equipment) mainly engines with simple mixture preparation systems, partially without exhaust gas after treatment are used. The comparison of 2 and 4 stroke concepts equipped with different exhaust gas after treatment systems provides a decision support for applications in a broad field of small capacity engine classes.

The molecular filtration of sulfur components in ultra low sulfur diesel (ULSD) fuel is described. A comprehensive screening of potential sulfur removal chemistries has yielded a sorbent which has the capability to efficiently remove organo-sulfur components in ULSD fuel. This sorbent has been used to treat ULSD fuel on a heavy duty engine equipped with NOx adsorber after-treatment technology and has been shown to lengthen the time between desulfation steps for the NOx adsorber. The fuel properties, cetane number and aromatics content, etc., have not been changed by the removal of the sulfur in the fuel with the exception of the lubricity which is reduced.

The implementations of the Tier 2 and LEVII emission levels require fast catalyst light-off and fast closed loop control through high-speed engine management. The paper describes the development of innovative catalyst designs. During the development thermal and mechanical boundary conditions were collected and component tests conducted on test rigs to identify the emission and durability performance. The products were evaluated on a Super Imposed Test Setup (SIT) where thermal and mechanical loads are applied to the test piece simultanously and results are compared to accelerated vehicle power train endurance runs. The newly developed light-off catalyst with Perforated Foil Technology (PE) showed superior emission light-off characteristic and robustness.

The SNR-technique is a new NOx aftertreatment system for lean burn gasoline and diesel applications. The objective of SNR is NOx removal from lean exhaust gas by NOx adsorption and subsequent selective external recirculation and decomposition of NOx in the combustion process. The SNR-project is composed of two major parts. Firstly the development of NOx adsorbents which are able to store large quantities of NOx in lean exhaust gas, and secondly the NOx decomposition by the combustion process. Emphasis of this paper is the investigation of NOx reduction in the combustion process, including experimental investigation and numerical simulation. The NOx decomposition process has been proven in diesel and lean-burn gasoline engines. Depending on the type of engine NOx-conversion rates up to 90 % have been observed. Regarding the complete SNR-system, including the efficiency of the adsorbing material and the NOx decomposition by the combustion, a NOx removal of more than 50% is achievable.

Selective NOx recirculation (SNR), involving adsorption, selective external recirculation and decomposition of the NOx by the combustion process, is itself a promising technique to abate NOx emissions. Three types of materials containing Ba: barium aluminate, barium tin perovskite and barium Y-zeolites have been developed to adsorb NOx under lean-burn or Diesel conditions, with or without the presence of S02. All these materials adsorb NO2 selectively (lean-burn conditions), and store it as nitrate/nitrite species. The desorption takes place by decomposition of these species at higher temperatures. Nitrate formation implies also sulfate formation in the presence of SO2 and SO3, while the NO2/SO2 competition governs the poisoning of such catalysts.

The objective of this effort was to develop an understanding of how different converter substrate cell structures impact tailpipe emissions and pressure drop from a total systems perspective. The cell structures studied were the following: The catalyst technologies utilized were a new technology palladium only catalyst in combination with a palladium/rhodium catalyst. A 4.0-liter, 1997 Jeep Cherokee with a modified calibration was chosen as the test platform for performing the FTP test. The experimental design focused on quantifying emissions performance as a function of converter volume for the different cell structures. The results from this study demonstrate that the 93 square cell/cm2 structure has superior performance versus the 62 square cell/cm2 structure and the 46 triangle cell/cm2 structure when the converter volumes were relatively small. However, as converter volume increases the emissions differences diminish.

The performance characteristics of a commercial lean-NOX trap catalyst were evaluated between 200 and 500°C, using H2, CO, and a mixture of both H2 and CO as reductants before and after different high-temperature aging steps, from 600 to 750°C. Tests included NOX reduction efficiency during cycling, NOX storage capacity (NSC), oxygen storage capacity (OSC), and water-gas-shift (WGS) and NO oxidation reaction extents. The WGS reaction extent at 200 and 300°C was negatively affected by thermal degradation, but at 400 and 500°C no significant change was observed. Changes in the extent of NO oxidation did not show a consistent trend as a function of thermal degradation. The total NSC was tested at 200, 350 and 500°C. Little change was observed at 500°C with thermal degradation but a steady decrease was observed at 350°C as the thermal degradation temperature was increased.

This paper gives an overview of the development work for an aftertreatment system, used in hand held powertools to fulfil the corporate average US Limits. The paper will start with a description of the annual reductions in US Limits with differences in CARB and EPA legislation and the consequences of the legislation in Europe from 2007 onwards. There then follows a chapter describing space restrictions in the given muffler leading to a maximum size for the substrate. Tests results are shown, giving an idea of additional measures taken to avoid dangerous temperatures on the muffler surface and of the emitted exhaust gas. The exothermic temperature increase created under service conditions imposes an additional thermal load from the catalyst back towards the engine itself. Therefore, some modifications regarding gas flow and positioning of the catalyst had to be made to find an adequate solution for series production.

Future US emissions limits are likely to mean a sophisticated nitrogen oxide (NOx) reduction technique is required for all vehicles with a diesel engine, which is likely to be either NOx trap or selective catalytic reduction (SCR) technology. To investigate the potential of SCR for NOx reduction on a light duty vehicle, a current model vehicle (EUII M1 calibration), of inertia weight 1810 kg, was equipped with an urea-based SCR injection system and non-vanadium, non-zeolitic SCR catalysts. To deal with carbon monoxide (CO), hydrocarbon (HC) and volatile organic fraction (VOF), a diesel oxidation catalyst was also incorporated into the system for most tests. Investigations into the effect of placing the oxidation catalyst at different positions in the system, changing the volume of the SCR catalysts, increasing system temperature through road load changes, varying the SCR catalyst composition, and changing the urea injection calibration are discussed.

The structural design of current vehicle front units has to account for an increasing number of constraints: improvement of real-world performance in safety for occupants and others road users, perform in the various ratings and meet future regulations. Therefore the structural car design is the result of a compromise between pedestrian protection, car-to-car compatibility and self- protection. In addition to these safety considerations, reparability constraints are becoming more and more demanding and intrusive toward the other safety requirements. The need to reduce emissions through fuel consumption control requires a reduction of the overall body weight which leads usually to more difficulties to achieve a correct structural behavior. Some of these constraints lead to solutions which are in opposition and in general to unsatisfactory compromises. It is suggested to develop a more comprehensive approach in order to better take into account both safety requirements and reparability.

This paper describes the development of new high performance three-way catalyst (TWC) formulations with improved activity and enhanced thermal stability. These new TWC formulations enable the converter to be fitted closer to the engine and allow this future legislation to be met with catalysts using PGM levels significantly lower than those currently being employed. The performance benefits of these advanced platinum- and palladium-based catalysts are demonstrated on a number of different vehicles after bench-engine ageing.

The influence of catalyst volume, cell density and precious metal loading on the catalyst efficiency were investigated to design a low cost catalyst system. In a first experiment the specific loading was kept constant for a 500cpsi and a 900cpsi substrate. In a second experiment the palladium loading was reduced on the 900cpsi substrate and the same PM loading was applied to a 1200cpsi substrate with lower volume. Finally the loading was further reduced for the 1200cpsi substrate. The following parameters were studied after aging: Catalyst performance of standard cell density compared to high cell density technology Light-off performance and catalyst efficiency as a function of Palladium loading and substrate cell density Catalyst efficiency as a function of AFR biasing The performance of the aged catalysts was investigated in a lambda sweep test and in light-off tests at an engine bench.

This paper presents a prospective combustion study about dilution effects on turbocharged SI engine at full load. It proposes a comparative analysis between lean burn and cooled exhaust gas recirculation (EGR) operation as knock improvement artifice in substitute of enrichment. The study was led on a four cylinder 2L engine on stationary test bench. A specific EGR circuit was designed in order to achieve high control of the temperature and mass flow of the recirculated gas. Thanks to instantaneous pressure cylinder transducers, a combustion analysis was carried out using an home-made code. 1-D simulations (WAVE code) were used to complete the analysis on volumetric efficiency and turbocharger behaviour. A real advantage of cooled EGR was observed in the study compared to lean burn or enrichment in terms of performance, heat exchange and specific fuel consumption.

The clear objective of future powertrain development is strongly characterized by lowest emission impact and minimum overall system cost penalty to the customer. In the past decades emission impact has been primarily related to both optimization of combustion process and exhaust after-treatment system efficiency. Nowadays, weight reduction is one of the main objectives for vehicular applications, considering the related improvements both in fuel consumption (i.e. CO2 production) and engine-out emissions. The state of the art of catalytic converter systems for automotive ZEV-oriented applications has yet to be introduces into mass production. This paper investigates the successful application o metallic turbulent structures for catalytic converters along with innovative packaging considerations, such as structured outer mantle, which lead to significant weight reductions, exhaust backpressure minimization and improved overall emission conversion efficiency.

The influence of SCR (selective catalytic reduction) activity on soot regeneration was investigated using engine test measurements with and without urea dosing on a vanadia-SCRF®1, also known as a vanadia SCR coated diesel particulate filter (V.SCR-DPF). The extent and rate of passive soot regeneration is significantly reduced in the presence of SCR activity especially at high temperatures (>250 °C). The reduction in soot regeneration is because some of the NO2, which would otherwise react with the soot, is consumed by SCR reactions and consequently the rate of soot regeneration is lower when urea is dosed. The converse effects of soot oxidation on SCR activity were studied separately by analysing steady-state light-off engine measurements with different initial soot loadings on the V.SCR-DPF. The measurements show an increase in NOX conversion with increasing soot loading.