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Intensified emission regulations as well as consumption demands lead to an increasing significance of unburned hydrocarbon (UHC) emissions for diesel engines. On the one hand, the quantity of hydrocarbon (HC) raw emissions is important for emission predictions as well as for the exhaust after treatment. On the other hand, HC emissions are also important for predicting combustion efficiency and thus fuel consumption, since a part of unreleased chemical energy of the fuel is still bound in the HC molecules. Due to these reasons, a simulation model for predicting HC raw emissions was developed for diesel engines based on a phenomenological two-zone model. The HC model takes three main sources of HC emissions of diesel engines into account: Firstly, it contains a sub-model that describes the fuel dribble out of the injector after the end of injection. Secondly, HC emissions from cold peripheral zones near cylinder walls are determined in another sub-model.

For long haul transport, diesel engine due to its low fuel consumption and low operating costs will remain dominant over a long term. In order to achieve CO2 neutrality, the use of electricity-based, synthetic fuels (e-fuels) provides a solution. Especially the group of oxymethylene ethers (OME) is given much attention because of its soot-free combustion. However, the new fuel properties and the changed combustion characteristics place new demands on engine design. Meanwhile, the use of new fuels also creates new degrees of freedom to operate diesel engines. In this work, the application of dimethoxymethane (OME1) is investigated by means of 1D simulation at three operating points in a truck diesel engine. The subsystems of fuel injection, air path and exhaust gas are sequentially adjusted for the purpose of low emissions, especially for low nitrogen oxides (NOx).

Several different possibilities will be described and discussed on the processes of reducing NOx in lean-burn gasoline and diesel engines. In-company studies were conducted on zeolitic catalysts. With lean-burn spark-ignition engines, hydrocarbons in the exhaust gas act as a reducing agent. In stationary conditions at λ = 1.2, NOx conversion rates of approx. 45 % were achieved. With diesel engines, the only promising variant is SCR technology using urea as a reducing agent. The remaining problems are still the low space velocity and the narrow temperature window of the catalyst. The production of reaction products and secondary reactions of urea with other components in the diesel exhaust gas are still unclarified.

Flow control by fluidic devices - without moving parts - offers advantages of reliability and low cost. As an example of their automobile application based on authors'' long-time experience the paper describes a fluidic valve for switching exhaust gas flow in a NOx absorber into a by-pass during regeneration phase. The unique feature here is the fluidic valve being of monostable and of axisymmetric design, integrated into the absorber body. After development in aerodynamic laboratory, the final design was tested on engine test stand and finally in a car. This proved that the performance under high temperature and pulsation existing in exhaust systems is reliable and promising. Fluidic valves require, however, close matching with aerodynamic load. To optimize the exhaust system layout for the whole load-speed range and reaching minimum counter- pressure, both the components of exhaust system and control strategy have to be properly adopted.

The EPEFE study (European Programme on Emissions, Fuels and Engine Technologies), /1/ and other programmes have identified an increase in tailpipe NOx emissions with reduced gasoline aromatics content for modern 3-way controlled catalyst vehicles. This effect occurs with fully warmed-up catalyst under closed-loop operation. In order to understand the reasons for this effect VW and Shell have mechanistically investigated the effects of fuel properties on EMS (engine management system) and catalyst performance. Fuels with independent variation of oxygen, aromatics and mid-range volatility were tested in different VW engines. λ was monitored using sensors located both pre and post catalyst. The results confirmed that reducing gasoline aromatics content reduced engine-out emissions but increased tailpipe NOx emissions. It could be shown that differences in H/C ratio led to differences in the hydrogen content of engine-out emissions which affected the reading of the λ sensor.

Within the European research programme IDEA (Integrated Diesel European Action), detailed experimental and theoretical studies of the fundamental phenomena of the Diesel engine like flow, injection, mixture formation, auto-ignition, combustion and pollutant formation were carried out to improve knowledge and to set up models for a simulation code. Because this basic research of the Diesel combustion process is very complex and cost intensive, it was carried out jointly by the JRC (Joint Research Committee), an association of European car manufacturers (Fiat, Peugeot SA, Renault, Volvo and Volkswagen). The activities were also subsidized by the Commission of the European Communities and the Swedish National Board of Technical Development. The results of the research work will support the design of even more efficient engines and the further reduction of soot and NOx emissions and will also enable the companies to reduce time and cost in developing new engines.

The NO formation is essentially determined by the flame temperature. In an engine the latter depends on the composition of the fuel and the intake gas. In this study the efficiency of various NO reducing measures is analysed by means of a comparison of measurements and computations for the Most frequent operation point of a 1.9 1 DI Diesel engine. The O2 concentration, which is shown to be the dominant source of influence on the flame temperature and NO formation, is varied using synthetic gas mixtures or by EGR. The molar heat capacity of CO2 and H2O in the recirculated exhaust gas, the intake temperature and the H/C ratio in the fuel are less important for the formation of NO. Measures which reduce the NO formation increase the ignition delay and thereby the fraction of the premixed combustion. The impact of EGR on the combustion process is illustrated by high speed filming.

Strategic Materials at Reaction Temperatures (SMART) is an approach used to design washcoat systems for passive 4-way emission control catalysts. Light duty diesel vehicles need to meet the European Motor Vehicle Emissions Group (MVEG) cycle or U. S. Federal test procedure (FTP 75). Emissions that are monitored include hydrocarbon (HC), nitrogen oxides (NOx), carbon monoxide (CO) and total particulate matter (TPM). Low engine-exhaust temperatures (< 200°C during city driving) and high temperatures (> 500-800°C under full load and wide-open throttle) make emission control a formidable task for the catalyst designer Gas phase HC, CO and NOx reactions must be balanced with the removal of the soluble organic fraction for the vehicle to be in compliance with regulations. The SMART approach uses model gases under typical operating conditions in the laboratory to better understand the function of individual washcoat components.

In a joint research project between industrial companies and a number of research institutes, nitrogen oxide conversion in oxygen containing exhaust gas has been investigated according to the following procedure Basic investigations of elementary steps of the chemical reaction Production and prescreening of different catalytic material on laboratory scale Application oriented screening of industrial catalyst material Catalyst testing on a lean bum gasoline engine, passenger car diesel engines (swirl chamber and DI) and on a DI truck engine Although a number of solid body structures show nitrogen oxide reduction by hydrocarbons, only noble metal containing catalysts and transition metal exchanged zeolites gave catalytic efficiencies of industrial relevance. A maximum of 25 % NOx reduction was found in the European driving cycle for passenger cars, about 40 % for truck engines in the respective European test.

In direct-injection gasoline (GDI) engines with charge stratification, minimizing engine-out nitrogen oxide (NOx) emission is crucial since exhaust-gas aftertreatment tolerates only limited amounts of NOx. Reduced NOx production directly lowers the frequency of energy-inefficient catalyst regeneration cycles. In this paper we investigate NO formation in a realistic GDI engine. Quantitative in-cylinder measurements of NO concentrations are carried out via laser-induced fluorescence imaging with excitation of NO (A-X(0,2) band at 248 nm), and subsequent fluorescence detection at 220-240 nm. Engine modifications were kept to a minimum in order to provide results that are representative of practical operating conditions. Optical access via a sapphire ring enabled identical engine geometry as a production line engine. The engine is operated with commercial gasoline (“Super-Plus”, RON 98).

In order to decarbonize and lower the overall emissions of the transport sector, immediate and cost-effective powertrain solutions are needed. Natural gas offers the advantage of a direct reduction of carbon dioxide (CO2) emissions due to its better Carbon to Hydrogen ratio (C/H) compared to common fossil fuels, e.g. gasoline or diesel. Moreover, an optimized engine design suiting the advantages of natural gas in knock resistance and lean mixtures keeping in mind the challenges of power density, efficiency and cold start manoeuvres. In the public funded project MethMag (Methane lean combustion engine) a gasoline fired three-cylinder-engine is redesigned based on this change of requirements and benchmarked against the previous gasoline engine.

In a consortium of European industrial partners and research institutes, a combination of industrial development and scientific research was organised. The objective was to improve the catalytic NOx conversion for lean burn cars and heavy-duty trucks, taking into account boundary conditions for the fuel consumption. The project lasted for three years. During this period parallel research was conducted in research areas ranging from basic research based on a theoretical approach to full scale emission system development. NOx storage catalysts became a central part of the project. Catalysts were evaluated with respect to resistance towards sulphur poisoning. It was concluded that very low sulphur fuel is a necessity for efficient use of NOx trap technology. Additionally, attempts were made to develop methods for reactivating poisoned catalysts. Methods for short distance mixing were developed for the addition of reducing agent.

Intensified emission regulations as well as consumption demands lead to an increasing significance of carbon monoxide (CO) emissions for diesel engines. On the one hand, the quantity of CO raw emissions is important for emission predictions as well as for the exhaust gas after treatment. On the other hand, CO emissions are also important for predicting combustion efficiency and thus fuel consumption, since a part of unreleased chemical energy of the fuel is still bound in the CO molecules. Due to these reasons, a simulation model for predicting CO raw emissions was developed for diesel engines based on a phenomenological two-zone model. The CO model takes three main sources of CO emissions of diesel engines into account: Firstly, it contains a sub model that describes CO from local understoichiometric areas. Secondly, CO emissions from overmixed regions are considered.

The reduction of both harmful emissions (CO, HC, NOx, etc.) and gases responsible for greenhouse effects (especially CO2) are mandatory aspects to be considered in the development process of any kind of propulsion concept. Focusing on ICEs, the main development topics are today not only the reduction of harmful emissions, increase of thermodynamic efficiency, etc. but also the decarbonization of fuels which offers the highest potential for the reduction of CO2 emissions. Accordingly, the development of future ICEs will be closely linked to the development of CO2 neutral fuels (e.g. biofuels and e-fuels) as they will be part of a common development process. This implies an increase in development complexity, which needs the support of engine simulations. In this work, the virtual modeling of real fuel behavior is addressed to improve current simulation capabilities in studying how a specific composition can affect the engine performance.