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Quantitative planar laser-induced fluorescence (PLIF) of gaseous acetone as a fuel-tracer has been used in an optically accessible engine, fueled by direct hydrogen injection. The purpose of this article is to assess the accuracy and precision of the measurement and the associated data reduction procedures. A detailed description of the acetone seeding system is given as well. The key features of the experiment are a high-pressure bubbler saturating the hydrogen fuel with acetone vapor, direct injection into an optical engine, excitation of acetone fluorescence with an Nd:YAG laser at 266 nm, and detection of the resulting fluorescence by an unintensified camera. Key steps in the quantification of the single-shot imaging data are an in-situ calibration and a correction for the effect of local temperature on the fluorescence measurement.

This paper examines the interaction of bulk flow and jet-induced fuel convection in an optically accessible hydrogen-fueled engine with direct injection. Planar laser-induced fluorescence (PLIF) of gaseous acetone as a fuel tracer was performed to obtain quantitative images of the hydrogen mole-fraction in the operating engine. With the engine motored, fuel was injected into inert bulk gas from a centrally located injector during the compression stroke. The injector had a single-hole nozzle with the jet angled at 50 degrees with respect to the vertical injector axis. Two parameters were varied in the experiments, injector orientation and tumble intensity, and for each of these, the injection timing was varied. Image series of the mean fuel mole-fraction between injection and near-TDC crank angles capture the mixture-formation process for each configuration and injection timing.

A central challenge for efficient auto-ignition controlled low-temperature gasoline combustion (LTGC) engines has been achieving the combustion phasing needed to reach stable performance over a wide operating regime. The negative valve overlap (NVO) strategy has been explored as a way to improve combustion stability through a combination of charge heating and altered reactivity via a recompression stroke with a pilot fuel injection. The study objective was to analyze the thermal and chemical effects on NVO-period energy recovery. The analysis leveraged experimental gas sampling results obtained from a single-cylinder LTGC engine along with cylinder pressure measurements and custom data reduction methods used to estimate period thermodynamic properties. The engine was fueled by either iso-octane or ethanol, and operated under sweeps of NVO-period oxygen concentration, injection timing, and fueling rate.

Negative Valve Overlap (NVO) is a potential control strategy for enabling Low-Temperature Gasoline Combustion (LTGC) at low loads. While the thermal effects of NVO fueling on main combustion are well-understood, the chemical effects of NVO in-cylinder fuel reforming have not been extensively studied. The objective of this work is to examine the effects of fuel molecular structure on NVO fuel reforming using gas sampling and detailed speciation by gas chromatography. Engine gas samples were collected from a single-cylinder research engine at the end of the NVO period using a custom dump-valve apparatus. Six fuel components were studied at two injection timings: (1) iso-octane, (2) n-heptane, (3) ethanol, (4) 1-hexene, (5) cyclohexane, and (6) toluene. All fuel components were studied neat except for toluene - toluene was blended with 18.9% nheptane by liquid volume to increase the fuel reactivity.

Fuel cell vehicles are entering the automotive market with significant potential benefits to reduce harmful greenhouse emissions, facilitate energy security, and increase vehicle efficiency while providing customer expected driving range and fill times when compared to conventional vehicles. One of the challenges for successful commercialization of fuel cell vehicles is transitioning the on-board fuel system from liquid gasoline to compressed hydrogen gas. Storing high pressurized hydrogen requires a specialized structural pressure vessel, significantly different in function, size, and construction from a gasoline container. In comparison to a gasoline tank at near ambient pressures, OEMs have aligned to a nominal working pressure of 700 bar for hydrogen tanks in order to achieve the customer expected driving range of 300 miles.

High-strength aluminum alloys such as 7075 can be formed using advanced manufacturing methods such as hot stamping. Hot stamping utilizes an elevated temperature blank and the high pressure stamping contact of the forming die to simultaneously quench and form the sheet. However, changes in the thermal history induced by hot stamping may increase this alloy’s stress corrosion cracking (SCC) susceptibility, a common corrosion concern of 7000 series alloys. This work applied the breaking load method for SCC evaluation of hot stamped AA7075-T6 B-pillar panels that had been artificially aged by two different artificial aging practices (one-step and two-step). The breaking load strength of the specimens provided quantitative data that was used to compare the effects of tensile load, duration, alloy, and heat treatment on SCC behavior.

The SAE Fuel Cell Vehicle (FCV) Safety Working Group has been addressing FCV safety for over 9 years. The initial document, SAE J2578, was published in 2002. SAE J2578 has been valuable as a Recommended Practice for FCV development with regard to the identification of hazards and the definition of countermeasures to mitigate these hazards such that FCVs can be operated in the same manner as conventional gasoline internal combustion engine (ICE)-powered vehicles. SAE J2578 is currently being revised so that it will continue to be relevant as FCV development moves forward. For example, test methods were refined to verify the acceptability of hydrogen discharges when parking in residential garages and commercial structures and after crash tests prescribed by government regulation, and electrical requirements were updated to reflect the complexities of modern electrical circuits which interconnect both AC and DC circuits to improve efficiency and reduce cost.

As part of a continuous research and innovation effort, Ford Motor Company has been evaluating hydrogen as an alternative fuel option for vehicles with internal combustion engines since 1997. Ford has recently designed and built an Econoline (E-450) shuttle bus with a 6.8L Triton engine that uses gaseous hydrogen fuel. Safe practices in the production, storage, distribution, and use of hydrogen are essential for the widespread public and commercial acceptance of hydrogen vehicles. Hazards and risks inherent in the application of hydrogen fuel to internal combustion engine vehicles are explained. The development of a Hydrogen Management System (H2MS) to detect hydrogen leaks in the vehicle is discussed, including the evolution of the H2MS design from exploration and quantification of risks, to implementation and validation of a working system on a vehicle. System elements for detection, mitigation, and warning are examined.

The SAE FCV Safety Working Group has been addressing fuel cell vehicle (FCV) safety for over 8 years. The initial document, SAE J2578, was published in 2002. SAE J2578 has been valuable to FCV development with regard to the identification of hazards and the definition of countermeasures to mitigate these hazards such that FCVs can be operated in the same manner as conventional gasoline internal combustion engine (ICE)-powered vehicles. J2578 is currently being updated to clarify and update requirements so that it will continue to be relevant and useful in the future. An update to SAE J1766 for post-crash electrical safety was also published to reflect unique aspects of FCVs and to harmonize electrical requirements with international standards. In addition to revising SAE J2578 and J1766, the Working Group is also developing a new Technical Information Report (TIR) for vehicular hydrogen systems (SAE J2579).

In an optically accessible single-cylinder engine fueled with hydrogen, acetone planar laser-induced fluorescence (PLIF) and particle image velocimetry (PIV) are used to evaluate in-cylinder mixture formation. The experiments include measurements for engine operation with hydrogen injection in-cylinder either prior to or after intake valve closure (IVC). Pre-IVC injection is used to produce a near-homogeneous mixture for PLIF calibration experiments and to establish a baseline comparison for post-IVC injection. Calibration experiments and a temperature correction allow conversion of the acetone fluorescence signal to equivalence ratio. For post-IVC injection with start of injection (SOI) coincident with IVC, PLIF results are similar to pre-IVC injection. With retard of SOI from IVC, mixture inhomogeneities increase monotonically, with high hydrogen concentration spatially located near the injector and within a smaller volume.

Accounting for more than 90% of the molecules and more than 75% of the mass [1], hydrogen is the most abundant element in the universe. Due to the small molecule size and high buoyancy, it is not available in it’s free form on Earth. In recent years, hydrogen has gained the attention of the automotive industry [2–12] as an environmentally friendly alternative fuel. As a fuel, hydrogen is unique - it is odorless, colorless, tasteless, and burns invisibly in sunlight. Detection solutions such as the odorants used in natural gas are not yet feasible for automotive hydrogen because the available additives can poison the fuel cell catalyst. Additionally, the lower flammability limit of hydrogen is lower, and the flammability range wider, than fuels such as gasoline [13]. Hydrogen detection and its concentration measurement is usually done using hydrogen concentration sensors [13].

Within the Engine Combustion Network (ECN) spray combustion research frame, simultaneous line-of-sight laser extinction measurements and laser-induced incandescence (LII) imaging were performed to derive the soot volume fraction (fv). Experiments are conducted at engine-relevant high-temperature and high-pressure conditions in a constant-volume pre-combustion type vessel. The target condition, called "Spray A," uses well-defined ambient (900 K, 60 bar, 22.8 kg/m₃, 15% oxygen) and injector conditions (common rail, 1500 bar, KS1.5/86 nozzle, 0.090 mm orifice diameter, n-dodecane, 363 K). Extinction measurements are used to calibrate LII images for quantitative soot distribution measurements at cross sections intersecting the spray axis. LII images are taken after the start of injection where quasi-stationary combustion is already established.

Mechanisms responsible for enhanced charge reactivity with intake added ozone (O3) were explored in a single-cylinder, optically accessible, research engine configured for low-load advanced compression ignition (ACI) experiments. The influence of O3 concentration (0-40 ppm) on engine performance metrics was evaluated as a function of intake temperature and start of injection for the engine fueled by iso-octane, 1-hexene, or a 5-component gasoline surrogate. For the engine fueled by either the gasoline surrogate or 1-hexene, 25 ppm of added O3 reduced the intake temperature required for stable combustion by 65 and 80°C, respectively. An ultraviolet (UV) light absorption diagnostic was also used to measure crank angle (CA) resolved in-cylinder O3 concentrations for select motored and fired operating conditions. The O3 measurements were compared to results from complementary 0D chemical kinetic simulations that utilized detailed chemistry mechanisms augmented with O3 oxidation chemistry.

Fossil energy diversity and security along with environmental emission policies demand new energy carriers and associated technologies in the future. One of the major challenges of the automotive industry and research institutes worldwide currently is to develop and realize alternative fuel concepts for passenger cars. In line with Ford's global hydrogen vehicle program, different onboard hydrogen storage technologies are under investigation. In general, hydrogen storage methods can be categorized as either physical storage of hydrogen (i.e. compressed, liquid, or cryo-compressed) or material based hydrogen storage. Currently, automotive OEMs have only introduced hydrogen fleet vehicles that utilize physical-based hydrogen storage systems but they have recognized that hydrogen storage systems need to advance further to achieve the range associated with today's gasoline vehicle.

Knowledge of the concentration field and flammability envelope from a small-scale hydrogen leak is an issue of importance for the safe use of hydrogen. A combined experimental and modeling program is being carried out by Sandia National Laboratories to characterize and predict the behavior of small-scale hydrogen releases. In contrast to the previous work performed by Sandia on large, momentum-dominated hydrogen leaks, these studies are focusing on small leaks in the Froude number range where both buoyant and inertial forces are important or, in the limit, where buoyancy dominates leak behavior. In the slow leak regime buoyant forces affect the trajectory and rate of air entrainment of the hydrogen jet leak and significant curvature can occur in the jet trajectory. Slow leaks may occur from leaky fittings or o-ring seals on hydrogen vehicles or other hydrogen-based systems where large amounts of pressure drop occur across the leak path.

Sandia National Laboratories has been investigating a new, integrated approach to generating electricity with ultra low emissions and very high efficiency for low power (30 kW) applications such as hybrid vehicles and portable generators. Our approach utilizes a free piston in a double-ended cylinder. Combustion occurs alternately at each cylinder end, with intake/exhaust processes accomplished through a two stroke cycle. A linear alternator is mounted in the center section of the cylinder, serving to both generate useful electrical power and to control the compression ratio by varying the rate of electrical generation. Thus, a mechanically simple geometry results in an electronically controlled variable compression ratio configuration. The capability of the homogeneous charge compression ignition combustion process employed in this engine with regards to reduced emissions and improved thermal efficiency has been investigated using a rapid compression expansion machine.

Ford's H2RV is a Hydrogen engine propelled Hybrid Electric concept Vehicle that was unveiled and driven at Ford's Centennial Show in June 2003. This vehicle is an industry first by an OEM that demonstrates the concept and the marriage of a HEV powertrain with a supercharged Hydrogen ICE that propels the vehicle. Just as Model T was the car of the 20th century, Model U is the vehicle for the 21st century. The powertrain utilizes compressed gaseous hydrogen as fuel, a supercharged 2.3L internal combustion engine, a 25 kW traction motor drive, the electric converterless transmission, regenerative braking, an advanced lithium ion battery, electric power assist steering, electronic throttle and Vehicle System Controller (VSC). The vehicle could deliver a projected fuel economy of 45 mpg and near zero emissions without compromise to performance.

In recent times, the development of alternate-fuel vehicles, including those fueled by hydrogen, has become relatively common. While there are potential safety related issues with any combustible fuel, these have been resolved over the last 100+ years. The comfort level with gasoline fuel has resulted from the widespread application of simple safety procedures followed at every stage of gasoline refinement and handling. It is important to have analogous procedures for handling hydrogen-fueled vehicles safely and with confidence. The characteristics of hydrogen, including: a) wide flammability range, b) very low ignition energy, c) odorless and difficult to detect, d) high diffusion rate, e) high buoyancy, f) invisible flame, etc., bolster the need for safe practices and procedures.

Ford's H2RV (Hydrogen Hybrid Research Vehicle) uses a Hydrogen fueled Internal Combustion Engine. This engine has a higher compression ratio and a faster fuel-burning rate compared to a conventional gasoline engine. The conventional flywheel is replaced with an electric motor in the hybrid powertrain, which causes higher crankshaft torsionals and is a major NVH source. The engine has a centrifugal supercharger mounted on its front-end dress, which is a big source of NVH. Fans are used to cool the high voltage batteries and to provide ventilation of H2 in the case of a leakage. The body sheet metal has several holes for passive H2 ventilation, battery cooling, plumbing lines, and harness routing. Underhood hardware, due to the hybrid transmission and the H2 ICE, created major packaging challenges for the intake and FEAD NVH. The exhaust muffler volume was limited due to the installation of high voltage batteries and underbody H2 fuel tanks.

Ford's Hydrogen Hybrid Research Vehicle (H2RV) is an industry first parallel hybrid vehicle utilizing a hydrogen internal combustion engine. The goal of this drivable concept vehicle is to marry Ford's extensive hybrid powertrain experience with its hydrogen internal combustion engine technology to produce a low emission, fuel-efficient vehicle. This vehicle is seen as a possible bridge from the petroleum fueled vehicles of today to the fuel cell vehicles envisioned for tomorrow. A multi-layered hydrogen management strategy was developed for the H2RV. All aspects of the vehicle including the design of the fuel and electrical systems, placement of high-voltage subsystems, and testing, service, and storage procedures were examined to ensure the safe operation of the vehicle. The results of these reviews led to the design of the hydrogen sensing and mitigation system for the H2RV vehicle.