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Monitoring NO2 Production of a Diesel Oxidation Catalyst

2012-01-24
A combination of laboratory reactor measurements and vehicle FTP testing has been combined to demonstrate a method for diagnosing the formation of NO2 from a diesel oxidation catalyst (DOC). Using small cores from a production DOC and simulated diesel exhaust, the laboratory reactor experiments are used to support a model for DOC chemical reaction kinetics. The model we propose shows that the ability to produce NO2 is chemically linked to the ability of the catalyst to oxidize hydrocarbon (HC). For thermally damaged DOCs, loss of the HC oxidation function is simultaneous with loss of the NO2 production function. Since HC oxidation is the source of heat generated in the DOC under regeneration conditions, we conclude that a diagnostic of the DOC exotherm is able to detect the failure of the DOC to produce NO2. Vehicle emissions data from a 6.6 L Duramax HD pick-up with DOC of various levels of thermal degradation is provided to support the diagnostic concept.
Journal Article

Development of a Predictive Model for Gasoline Vehicle Particulate Matter Emissions

2010-10-25
2010-01-2115
The relationship between gasoline properties and vehicle particulate matter emissions was investigated, for the purpose of constructing a predictive model. Various chemical species were individually blended with an indolene base fuel, and the solid particulate number (PN) emissions from each blend were measured over the New European Driving Cycle (NEDC). The results indicated that aromatics with a high boiling point and a high double bond equivalent (DBE) value tended to produce more PN emissions. However, high boiling point components with low DBE values, such as paraffins, displayed only a minor effect on PN. Upon further analysis of the test results, it was also confirmed that low vapor pressure components correlated with high PN emissions, as might be expected based on their combustion behavior. A predictive model, termed the “PM Index,” was constructed based on the weight fraction, vapor pressure, and DBE value of each component in the fuel.
Journal Article

Self-Pierce Riveting of Magnesium to Aluminum Alloys

2011-04-12
2011-01-0074
Magnesium and aluminum alloys offer lightweighting opportunities in automotive applications. Joining of dissimilar materials, however, generally requires methods that do not involve fusion. This paper explores the use of self-pierce riveting (SPR) to join magnesium to aluminum alloys for structural and closure applications. The preliminary results indicate that SPR is a viable option for joining aluminum extrusions to magnesium die castings, as well as stamped sheet aluminum to quick-plastic-formed (QPF) sheet magnesium.
Journal Article

A Comparison of Spray-Guided Stratified-Charge Combustion Performance with Outwardly-Opening Piezo and Multi-Hole Solenoid Injectors

2011-04-12
2011-01-1217
This investigation was aimed at measuring the relative performance of two spray-guided, single-cylinder, spark-ignited direct-injected (SIDI) engine combustion system designs. The first utilizes an outwardly-opening poppet, piezo-actuated injector, and the second a conventional, solenoid operated, inwardly-opening multi-hole injector. The single-cylinder engine tests were limited to steady state, warmed-up conditions. The comparison showed that these two spray-guided combustion systems with two very different sprays had surprisingly close results and only differed in some details. Combustion stability and smoke emissions of the systems are comparable to each other over most of the load range. Over a simulated Federal Test Procedure (FTP) cycle, the multi-hole system had 15% lower hydrocarbon and 18% lower carbon monoxide emissions.
Journal Article

Fatigue Behavior and Life Prediction for Aluminum Castings in the Absence of Casting Flaws

2011-04-12
2011-01-0193
Cast aluminum alloys are increasingly used in cyclically loaded automotive structural applications for light weight and fuel economy. The fatigue resistance of aluminum castings strongly depends upon the presence of casting flaws and characteristics of microstructural constituents. The existence of casting flaws significantly reduces fatigue crack initiation life. In the absence of casting flaws, however, crack initiation occurs at the fatigue-sensitive microstructural constituents. Cracking and debonding of large silicon (Si) and Fe-rich intermetallic particles and crystallographic shearing from persistent slip bands in the aluminum matrix play an important role in crack initiation. This paper presents fatigue life models for aluminum castings free of casting flaws, which complement the fatigue life models for aluminum castings containing casting flaws published in [1].
Journal Article

Modeling of Residual Stresses in Quenched Cast Aluminum Components

2011-04-12
2011-01-0539
Cast aluminum alloys are normally quenched after solution treatment or solidification process to improve aging responses. Rapid quenching can lead to high residual stress and severe distortion which significantly affects dimension stability, functionality and particularly performance of the product. To simulate residual stress and distortion induced during quenching, a finite element based approach was developed by coupling an iterative zone-based transient heat transfer algorithm with material thermo-viscoplastic constitutive model. With the integrated models, the numeric predictions of residual stresses and distortion in the quenched aluminum castings are in a good agreement with experimental measurements.
Journal Article

Numerical Investigation of Buoyancy-Driven Flow in a Simplified Underhood with Open Enclosure

2013-04-08
2013-01-0842
Numerical results are presented for simulating buoyancy driven flow in a simplified full-scale underhood with open enclosure in automobile. The flow condition is set up in such a way that it mimics the underhood soak condition, when the vehicle is parked in a windbreak with power shut-down after enduring high thermal loads due to performing a sequence of operating conditions, such as highway driving and trailer-grade loads in a hot ambient environment. The experimental underhood geometry, although simplified, consists of the essential components in a typical automobile underhood undergoing the buoyancy-driven flow condition. It includes an open enclosure which has openings to the surrounding environment from the ground and through the top hood gap, an engine block and two exhaust cylinders mounted along the sides of the engine block. The calculated temperature and velocity were compared with the measured data at different locations near and away from the hot exhaust plumes.
Journal Article

Particle Emissions from a 2009 Gasoline Direct Injection Engine Using Different Commercially Available Fuels

2010-10-25
2010-01-2117
Total and solid particle mass, size, and number were measured in the dilute exhaust of a 2009 vehicle equipped with a gasoline direct injection engine along with an exhaust three-way-catalyst. The measurements were performed over the FTP-75 and the US06 drive cycles using three different U.S. commercially available fuels, Fuels A, B, and C, where Fuel B was the most volatile and Fuel C was the least volatile with higher fractions of low vapor pressure hydrocarbons (C10 to C12), compared to the other two fuels. Substantial differences in particle mass and number emission levels were observed among the different fuels tested. The more volatile gasoline fuel, Fuel B, resulted in the lowest total (solid plus volatile) and solid particle mass and number emissions. This fuel resulted in a 62 percent reduction in solid particle number and an 88 percent reduction in soot mass during the highest emitting cold-start phase, Phasel, of the FTP-75, compared to Fuel C.
Technical Paper

Balance of Electrical Power Requirements through Smart Electric Power Management

2011-04-12
2011-01-0042
This paper examines Smart Electric Power Management as it pertains to when the vehicle charging system is active. Over the past decade there have been several factors at play which have stressed the demands placed upon the vehicle electrical power system. Many of these factors present challenges to electrical power that are at cross-purposes with one another. For example, demands of new and existing electrical loads, customer expectations about load performance and battery life, and the push by governments' world-wide for increased fuel economy (FE) and reduced CO2 emissions all have direct impact and can be directly impacted by decisions made in electric power design. As the electrification of the vehicle has progressed we now have much more specific vehicle state data available and the means to share this information among on-board computers through serial data link connectivity.
Technical Paper

Experimental Study of NOx Reduction by Passive Ammonia-SCR for Stoichiometric SIDI Engines

2011-04-12
2011-01-0307
As vehicle fuel economy requirements continue to increase it is becoming more challenging and expensive to simultaneously improve fuel consumption and meet emissions regulations. The Passive Ammonia SCR System (PASS) is a novel aftertreatment concept which has the potential to address NOx emissions with application to both lean SI and stoichiometric SI engines. PASS relies on an underfloor (U/F) SCR for storage of ammonia which is generated by the close-coupled (CC) TWCs. For lean SI engines, it is required to operate with occasional rich pulses in order to generate the ammonia, while for stoichiometric application ammonia is passively generated through the toggling of air/fuel ratio. PASS serves as an efficient and cost-effective enhancement to standard aftertreatment systems. For this study, the PASS concept was demonstrated first using lab reactor results which highlight the oxygen tolerance and temperature requirements of the SCR.
Technical Paper

Three-Way Catalyst Design for Urealess Passive Ammonia SCR: Lean-Burn SIDI Aftertreatment System

2011-04-12
2011-01-0306
Lean-burn SIDI engine technology offers improved fuel economy; however, the reduction of NOx during lean-operation continues to be a major technical hurdle in the implementation of energy efficient technology. There are several aftertreatment technologies, including the lean NOx trap and active urea SCR, which have been widely considered, but they all suffer from high material cost and require customer intervention to fill the urea solution. Recently reported passive NH₃-SCR system - a simple, low-cost, and urea-free system - has the potential to enable the implementation of lean-burn gasoline engines. Key components in the passive NH₃-SCR aftertreatment system include a close-coupled TWC and underfloor SCR technology. NH₃ is formed on the TWC with short pulses of rich engine operation and the NH₃ is then stored on the underfloor SCR catalysts.
Technical Paper

Wrought Magnesium Components for Automotive Chassis Applications

2011-04-12
2011-01-0077
Automotive structural components are exposed to high loads, impact situations and corrosion. In addition, there may be temperature excursions that introduce creep as well as reduced modulus (stiffness). These issues have limited the use of light metals in automotive structural applications primarily to aluminum alloys, and primarily to cast wheels and knuckles (only a few of which are forged), cast brake calipers, and cast control arms. This paper reports on research performed at Chongqing University, Chongqing China, under the auspices of General Motors engineering and directed by the first author, to develop a protocol that uses wrought magnesium in control arms. The goal was to produce a chassis part that could provide the same engineering function as current cast aluminum applications; and since magnesium is 33% less dense than aluminum, would be lighter.
Technical Paper

The Influence of DISI Engine Operating Parameters on Particle Number Emissions

2011-04-12
2011-01-0143
The future EURO 6 emission standard will limit the particle number and mass for gasoline engines. The proposed limit for particle mass is 4.5 mg/km. For particle number there is not yet a limit defined but a wide range of proposals are under discussion (6E11 - 8E12 Particles/km) The particle emissions on a homogeneous SIDI engine are mainly caused by insufficient mixture preparation. A combustion improvement could be achieved by a careful recalibration as well as a hardware optimization that mainly avoids wall impingement and substoichiometric zones in the combustion chamber. The analyses of current SIDI vehicles show significant PN emission peaks during cold start and transient operation on a NEDC cycle. To give a better understanding of cause and effect of the particle formation at steady state results so as transient load steps were performed at an engine dynamometer.
Technical Paper

Particle Number, Size and Mass Emissions of Different Biodiesel Blends Versus ULSD from a Small Displacement Automotive Diesel Engine

2011-04-12
2011-01-0633
Experimental work was carried out on a small displacement Euro 5 automotive diesel engine alternatively fuelled with ultra low sulphur diesel (ULSD) and with two blends (30% vol.) of ULSD and of two different fatty acid methyl esters (FAME) obtained from both rapeseed methyl ester (RME) and jatropha methyl ester (JME) in order to evaluate the effects of different fuel compositions on particle number (PN) emissions. Particulate matter (PM) emissions for each fuel were characterized in terms of number and mass size distributions by means of two stage dilutions system coupled with a scanning mobility particle sizer (SMPS). Measurements were performed at three different sampling points along the exhaust system: at engine-out, downstream of the diesel oxidation catalyst (DOC) and downstream of the diesel particulate filter (DPF). Thus, it was possible to evaluate both the effects of combustion and after-treatment efficiencies on each of the tested fuels.
Technical Paper

Particle Size and Number Emissions from Modern Light-Duty Diesel Vehicles

2011-04-12
2011-01-0632
This paper focuses on measuring particle emissions of a representative light-duty diesel vehicle equipped with different engine exhaust aftertreatment in close-coupled position, including one designed to meet the upcoming Euro 6 emission standards. The latter combines a lean NOx trap (LNT) and a diesel particulate filter (DPF) in series to simultaneously reduce NOx and PM. Particle Matter (PM) and particle number emissions are measured throughout testing procedure and instrumentation which are compliant with the UN-ECE Regulation 83 proposals. Specifically measuring devices for particle number emissions, provided by two different suppliers, are alternatively used. No significant differences are observed due to the different system employed. On the other hand particle size distributions are measured by means of a specific experimental set-up including a two stage dilution system and an electrical low pressure impactor (ELPI).
Technical Paper

Electrically Heated Catalysts for Cold-Start Emissions in Diesel Aftertreatment

2012-04-16
2012-01-1092
With a tighter regulatory environment, reduction of hydrocarbon (HC) and NOx emissions during cold-start has emerged as a major challenge for diesel engines. In the complex diesel aftertreatment system, more than 90% of engine-out NOx is removed in the underfloor SCR. However, the combination of low temperature exhaust and heat sink over DOC delays the SCR light-off during the cold start. In fact, the first 350 seconds during the cold light-duty FTP75 cycle contribute more than 50% of the total NOx tailpipe emission due to the low SCR temperature. For a fast SCR light-off, electrically heated catalyst (EHC) technology has been suggested to be an effective solution as a rapid warm-up strategy. In this work, the EHC, placed in front of DOC, utilizes both electrical power and hydrocarbon fuel. The smart energy management during the cold-start was crucial to optimize the EHC integrated aftertreatment system.
Technical Paper

Effects of Gage Section Geometry on Tensile Material Properties by Digital Image Correlation

2012-04-16
2012-01-0184
Accurate material property data in both the elastic and plastic ranges of deformation is essential for accurate material representation in finite element simulations of vehicle systems. Variation of post formed material properties across a part are often of interest in different types of analyses, such as metal forming or fatigue life, for example. Depending on a part's shape it is not always possible to cut standard size tensile test specimens from all areas of interest across the part. Smaller size specimens with curved or tapered gage section may have to be used to promote strain localization and fracture at or near the gage center. This paper presents comparison of quasi-static tensile properties determined using two specimen gage section geometries, straight and tapered. Specifically, the following questions are addressed. How do the engineering strains computed from two-dimensional strain fields obtained by DIC compare to strains measured during standard tensile tests?
Technical Paper

Comparisons of Current Concepts for Press Hardened Steel Tailor Welded Blanks and Tailor Rolled Blanks on Center Pillar Reinforcements

2011-04-12
2011-01-1059
Press hardened steels (PHS) are commonly used in automotive structural applications because of their combination of extremely high strength, load carrying capacity and the ability to form complex shapes in the press hardening process. Recent adoption of increased roof crush standards, side impact requirements and the increased focus on CO2 emissions and mass reduction have led autmotive manufacturers to significantly increase the amount of PHS being designed into future vehicle designs. As a way to further optimize the use of these steels, multi-gauge welded blanks of PHS and multi-material blanks of PHS to microalloyed steels of various thickness have been developed to help achieve these requirements. More recently, tailor rolled PHS, whereby the steel is rolled such that the thickness changes across the width of the sheet, have been developed.
Technical Paper

The Development of Advanced 2-Way SCR/DPF Systems to Meet Future Heavy-Duty Diesel Emissions

2011-04-12
2011-01-1140
Diesel engines have the potential to significantly increase vehicle fuel economy and decrease CO₂ emissions; however, efficient removal of NOx and particulate matter from the engine exhaust is required to meet stringent emission standards. A conventional diesel aftertreatment system consists of a Diesel Oxidation Catalyst (DOC), a urea-based Selective Catalyst Reduction (SCR) catalyst and a diesel particulate filter (DPF), and is widely used to meet the most recent NOx (nitrogen oxides comprising NO and NO₂) and particulate matter (PM) emission standards for medium- and heavy-duty sport utility and truck vehicles. The increasingly stringent emission targets have recently pushed this system layout towards an increase in size of the components and consequently higher system cost. An emerging technology developed recently involves placing the SCR catalyst onto the conventional wall-flow filter.
Technical Paper

Conditional Analysis of Enhanced Combustion Luminosity Imaging in a Spray-Guided Gasoline Engine with High Residual Fraction

2011-04-12
2011-01-1281
High-speed (12 kHz) imaging of combustion luminosity (enhanced by using a sodium fuel additive) has been analyzed and compared to crank angle resolved heat release rates and mass fraction burn profiles in a spray-guided spark-ignited direct-injection (SG-SIDI) optical single-cylinder engine. The addition of a sodium-containing additive to gasoline greatly increases the combustion luminosity, which allows unintensified high-speed (12 kHz) imaging of early partially premixed flame kernel growth and overall flame propagation with excellent signal-to-noise ratio for hundreds of consecutive engine cycles. Ignition and early flame kernel growth are known to be key to understanding and eliminating poor burn cycles in SG-SIDI engines.
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