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Monitoring NO2 Production of a Diesel Oxidation Catalyst

2012-01-24
A combination of laboratory reactor measurements and vehicle FTP testing has been combined to demonstrate a method for diagnosing the formation of NO2 from a diesel oxidation catalyst (DOC). Using small cores from a production DOC and simulated diesel exhaust, the laboratory reactor experiments are used to support a model for DOC chemical reaction kinetics. The model we propose shows that the ability to produce NO2 is chemically linked to the ability of the catalyst to oxidize hydrocarbon (HC). For thermally damaged DOCs, loss of the HC oxidation function is simultaneous with loss of the NO2 production function. Since HC oxidation is the source of heat generated in the DOC under regeneration conditions, we conclude that a diagnostic of the DOC exotherm is able to detect the failure of the DOC to produce NO2. Vehicle emissions data from a 6.6 L Duramax HD pick-up with DOC of various levels of thermal degradation is provided to support the diagnostic concept.
Journal Article

Visualization of Propane and Natural Gas Spark Ignition and Turbulent Jet Ignition Combustion

2012-10-23
2012-32-0002
This study focuses on the combustion visualization of spark ignition combustion in an optical single cylinder engine using natural gas and propane at several air to fuel ratios and speed-load operating points. Propane and natural gas fuels were compared as they are the most promising gaseous alternative fuels for reciprocating powertrains, with both fuels beginning to find wide market penetration on the fleet level across many regions of the world. Additionally, when compared to gasoline, these gaseous fuels are affordable, have high knock resistance and relatively low carbon content and they do not suffer from the complex re-fueling and storage problems associated with hydrogen.
Technical Paper

Experimental Study of NOx Reduction by Passive Ammonia-SCR for Stoichiometric SIDI Engines

2011-04-12
2011-01-0307
As vehicle fuel economy requirements continue to increase it is becoming more challenging and expensive to simultaneously improve fuel consumption and meet emissions regulations. The Passive Ammonia SCR System (PASS) is a novel aftertreatment concept which has the potential to address NOx emissions with application to both lean SI and stoichiometric SI engines. PASS relies on an underfloor (U/F) SCR for storage of ammonia which is generated by the close-coupled (CC) TWCs. For lean SI engines, it is required to operate with occasional rich pulses in order to generate the ammonia, while for stoichiometric application ammonia is passively generated through the toggling of air/fuel ratio. PASS serves as an efficient and cost-effective enhancement to standard aftertreatment systems. For this study, the PASS concept was demonstrated first using lab reactor results which highlight the oxygen tolerance and temperature requirements of the SCR.
Technical Paper

Particle Size and Number Emissions from Modern Light-Duty Diesel Vehicles

2011-04-12
2011-01-0632
This paper focuses on measuring particle emissions of a representative light-duty diesel vehicle equipped with different engine exhaust aftertreatment in close-coupled position, including one designed to meet the upcoming Euro 6 emission standards. The latter combines a lean NOx trap (LNT) and a diesel particulate filter (DPF) in series to simultaneously reduce NOx and PM. Particle Matter (PM) and particle number emissions are measured throughout testing procedure and instrumentation which are compliant with the UN-ECE Regulation 83 proposals. Specifically measuring devices for particle number emissions, provided by two different suppliers, are alternatively used. No significant differences are observed due to the different system employed. On the other hand particle size distributions are measured by means of a specific experimental set-up including a two stage dilution system and an electrical low pressure impactor (ELPI).
Technical Paper

The Development of Advanced 2-Way SCR/DPF Systems to Meet Future Heavy-Duty Diesel Emissions

2011-04-12
2011-01-1140
Diesel engines have the potential to significantly increase vehicle fuel economy and decrease CO₂ emissions; however, efficient removal of NOx and particulate matter from the engine exhaust is required to meet stringent emission standards. A conventional diesel aftertreatment system consists of a Diesel Oxidation Catalyst (DOC), a urea-based Selective Catalyst Reduction (SCR) catalyst and a diesel particulate filter (DPF), and is widely used to meet the most recent NOx (nitrogen oxides comprising NO and NO₂) and particulate matter (PM) emission standards for medium- and heavy-duty sport utility and truck vehicles. The increasingly stringent emission targets have recently pushed this system layout towards an increase in size of the components and consequently higher system cost. An emerging technology developed recently involves placing the SCR catalyst onto the conventional wall-flow filter.
Technical Paper

Conditional Analysis of Enhanced Combustion Luminosity Imaging in a Spray-Guided Gasoline Engine with High Residual Fraction

2011-04-12
2011-01-1281
High-speed (12 kHz) imaging of combustion luminosity (enhanced by using a sodium fuel additive) has been analyzed and compared to crank angle resolved heat release rates and mass fraction burn profiles in a spray-guided spark-ignited direct-injection (SG-SIDI) optical single-cylinder engine. The addition of a sodium-containing additive to gasoline greatly increases the combustion luminosity, which allows unintensified high-speed (12 kHz) imaging of early partially premixed flame kernel growth and overall flame propagation with excellent signal-to-noise ratio for hundreds of consecutive engine cycles. Ignition and early flame kernel growth are known to be key to understanding and eliminating poor burn cycles in SG-SIDI engines.
Technical Paper

Detection of Urea Injection System Faults for SCR Systems

2012-04-16
2012-01-0431
The urea injection is a key function in Urea-SCR NOx reduction system. As the tailpipe NOx emission standard becomes increasingly stringent, it is critical to diagnose the injection faults in order to guarantee the SCR DeNox functionality and performance. Particularly, a blocked injector may cause under-dosing of urea thus reduced DeNox functionality. Monitoring urea injection rate is one of the efficient methods for injection fault diagnosis. However, direct measurement of the urea mass flow is not feasible due to its high cost. This paper presents methods that are promising for detecting and isolating faults in urea injection by processing certain actuator signal and existing sensory measurements, e.g., the injector Pulse Amplitude Modulated (PAM) command and the pressure of the urea delivery line. No additional dedicated sensor is required. Three methods are discussed to detect urea injection system faults.
Technical Paper

Experimental Investigation of Light-Medium Load Operating Sensitivity in a Gasoline Compression Ignition (GCI) Light-Duty Diesel Engine

2013-04-08
2013-01-0896
The light-medium load operating range (4-7 bar net IMEP) presents many challenges for advanced low temperature combustion strategies utilizing low cetane fuels (specifically, 87-octane gasoline) in light-duty, high-speed engines. The overly lean overall air-fuel ratio (Φ≺0.4) sometimes requires unrealistically high inlet temperatures and/or high inlet boost conditions to initiate autoignition at engine speeds in excess of 1500 RPM. The objective of this work is to identify and quantify the effects of variation in input parameters on overall engine operation. Input parameters including inlet temperature, inlet pressure, injection timing/duration, injection pressure, and engine speed were varied in a ~0.5L single-cylinder engine based on a production General Motors 1.9L 4-cylinder high-speed diesel engine.
Technical Paper

Visualization and Analysis of Condensation in Exhaust Gas Recirculation Coolers

2013-04-08
2013-01-0540
Cooled exhaust gas recirculation (EGR) is widely used in diesel engines to control engine-out NOx (oxides of nitrogen) emissions. A portion of the exhaust gases is re-circulated into the intake manifold of the engine after cooling it through a heat exchanger. EGR cooler heat exchangers, however, tend to lose efficiency and have increased pressure drop as deposit forms on the heat exchanger surface due to transport of soot particles and condensing species to the cooler walls. In this study, condensation of water vapor and hydrocarbons at the exit of the EGR cooler was visualized using a fiberscope coupled to a camera equipped with a complementary metal oxide semiconductor (CMOS) color sensor. A multi-cylinder diesel engine was used to produce a range of engine-out hydrocarbon concentrations. Both surface and bulk gas condensation were observed with the visualization setup over a range of EGR cooler coolant temperatures.
Technical Paper

An Investigation of Diesel EGR Cooler Fouling and Effectiveness Recovery

2013-04-08
2013-01-0533
Diesel engine developers are continually striving to reduce harmful NOx emissions through various calibration and hardware strategies. One strategy being implemented in production Diesel engines involves utilizing cooled exhaust gas recirculation (EGR). Although there is a significant NOx reduction potential by utilizing cooled EGR, there are also several issues associated with it, such as EGR cooler fouling and a reduction in cooler effectiveness that can occur over time. The exact cause of these issues and many others related to cooler fouling are not clearly understood. One such unanswered issue or phenomenon that has been observed in both field tested and lab tested EGR coolers is that of a recovery in EGR cooler effectiveness after a shutdown or after cycling between various conditions.
Technical Paper

The Impact of Engine Displacement on Efficiency Loss Pathways in a Highly Dilute Jet Ignition Engine

2019-04-02
2019-01-0330
Internal combustion engines currently face increasing regulatory reform which has motivated investigation of alternative combustion modes, particularly for spark ignition engines. Fuel economy regulations, among others, are presently driving the need for technological advances in the automotive sector. Stationary power generation is facing emissions standards that will be increasingly difficult to achieve with combustion-based current practices, particularly in the case of nitrogen oxides (NOx). Ultra-lean (λ > ~1.6; air-fuel ratio > 23:1) combustion via air dilution is one such combustion mode that provides the benefits of reduced fuel consumption and reduced NOx emissions. Jet ignition is a pre-chamber-based combustion system that enables enleanment beyond what is achievable with traditional spark ignition engines. Previous studies of MAHLE’s Jet Ignition® concept have primarily focused on light-duty gasoline engines.
Technical Paper

RANS Based Multidimensional Modeling of an Ultra-Lean Burn Pre-Chamber Combustion System with Auxiliary Liquid Gasoline Injection

2015-04-14
2015-01-0386
Evolving emissions and fuel efficiency legislation has driven the development of ultra-lean burn engine concepts that combine high efficiency with low criteria emissions, including nitrogen oxides (NOx). Traditional spark ignition (SI) systems have limitations in terms of available ignition energy and its distribution. Turbulent Jet Ignition (TJI) is a pre-chamber-based combustion system that enables ultra-lean operation through high energy jets acting as a distributed ignition source. Combustion is initiated in the pre-chamber (with or without auxiliary fuel injection) using a spark plug. The resulting flame is quenched in the pre-chamber nozzle thereby generating chemically active turbulent jets which penetrate and reignite in the main-chamber at multiple points after a time delay.
Technical Paper

The Effects of Turbulent Jet Characteristics on Engine Performance Using a Pre-Chamber Combustor

2014-04-01
2014-01-1195
Increasingly stringent US fuel economy regulation has emphasized the need for automotive engines to achieve greater levels of efficiency. Lean operation in spark ignition engines has demonstrated the ability to increase thermal efficiency, but this is typically accompanied by increased nitrogen oxides (NOx) emissions. Ultra-lean operation (λ > 2), however, has demonstrated increased thermal efficiency and the potential for significant reductions in NOx. Turbulent Jet Ignition (TJI) enables ultra-lean operation by utilizing radical turbulent jets emerging from a pre-chamber combustor as the ignition source for main chamber combustion in a spark ignition engine. This study seeks to better understand the interaction between the pre-chamber and main chamber combustion events, specifically the effect that particular TJI design parameters have on this interaction.
Technical Paper

Active Pre-Chamber as a Technology for Addressing Fuel Slip and its Associated Challenges to Lambda Estimation in Hydrogen ICEs

2023-09-29
2023-32-0041
Heavy duty hydrogen (H2) internal combustion engines (ICEs), typically conversions from base diesel engines, can experience significant deterioration of combustion efficiency with enleanment despite relative engine stability due in part to non-optimized combustion chamber geometry for spark ignited (SI) combustion. This causes un-combusted H2 to “slip” into the exhaust largely undetected since it is not a typically measured exhaust species. In this study, several implications of H2 slip in H2 ICEs are explored. The sensitivity of air fuel ratio (AFR) measurement to H2 slip is discussed. The challenge this poses for closed-loop transient controls and the impact on nitrogen oxides (NOx) emissions are also shown. Finally, test results from an H2 ICE using an active pre-chamber highlight the improvement in combustion efficiency and transient stability relative to a baseline SI engine.
Journal Article

Lambda Determination Challenges for Ultra-Lean Hydrogen-Fueled Engines and the Impact on Engine Calibration

2023-04-11
2023-01-0286
An increasing number of zero emission powertrain technologies will be required for meeting future CO2 targets. While this demand will be met by battery and fuel cell electric vehicles in several markets, other solutions are needed for harder to electrify sectors. Hydrogen (H2) internal combustion engines (ICEs) have become an attractive option for high power, high duty cycle vehicles and are expected to play a strong role in achieving zero emission goals. A unique characteristic of H2 ICEs is their ability to operate extremely lean, with lambda (λ) greater than 2. At such conditions, a multitude of benefits are observed including higher thermal efficiency, lower engine-out nitrogen oxides (NOx) emissions, and mitigating common problems with H2 abnormal combustion such pre-ignition and knock. However, two critical issues arise during extreme enleanment of H2 ICEs which have practical implications on controls and calibration of these engines.
Technical Paper

Development of a High Power, Low Emissions Heavy Duty Hydrogen Engine

2024-04-09
2024-01-2610
The hydrogen (H2) internal combustion engine (ICE) is emerging as an attractive low life-cycle carbon powertrain configuration for applications that require high power, high duty cycle operation. Owing to the relative ease of conversion of heavy duty (HD) diesel ICEs to H2 and the potential for low exhaust emissions, H2 ICEs are expected to play a strong role in rapidly decarbonizing hard-to-electrify markets such as off-road, rail, and marine. The conversion of HD diesel ICEs to spark ignited H2 with port fuel injection is typically accompanied by a de-rating of engine power and torque. This is due to several fuel- and system-related challenges, including the high risk of abnormal combustion resulting from the low auto-ignition energy threshold of H2, and boost system requirements for highly dilute operation that is used to partially mitigate this abnormal combustion risk.
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