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A combination of laboratory reactor measurements and vehicle FTP testing has been combined to demonstrate a method for diagnosing the formation of NO2 from a diesel oxidation catalyst (DOC). Using small cores from a production DOC and simulated diesel exhaust, the laboratory reactor experiments are used to support a model for DOC chemical reaction kinetics. The model we propose shows that the ability to produce NO2 is chemically linked to the ability of the catalyst to oxidize hydrocarbon (HC). For thermally damaged DOCs, loss of the HC oxidation function is simultaneous with loss of the NO2 production function. Since HC oxidation is the source of heat generated in the DOC under regeneration conditions, we conclude that a diagnostic of the DOC exotherm is able to detect the failure of the DOC to produce NO2. Vehicle emissions data from a 6.6 L Duramax HD pick-up with DOC of various levels of thermal degradation is provided to support the diagnostic concept.

An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

Magnesium and aluminum alloys offer lightweighting opportunities in automotive applications. Joining of dissimilar materials, however, generally requires methods that do not involve fusion. This paper explores the use of self-pierce riveting (SPR) to join magnesium to aluminum alloys for structural and closure applications. The preliminary results indicate that SPR is a viable option for joining aluminum extrusions to magnesium die castings, as well as stamped sheet aluminum to quick-plastic-formed (QPF) sheet magnesium.

Experimental decklids for the Cadillac STS sedan were made with Al AA5083 sheet outer panels and Mg AZ31B sheet inner panels using regular-production forming processes and hardware. Joining and coating processes were developed to accommodate the unique properties of Mg. Assembled decklids were evaluated for dimensional accuracy, slam durability, and impact response. The assemblies performed very well in these tests. Explicit and implicit finite element simulations of decklids were conducted, and showed that the Al/Mg decklids have good stiffness and strength characteristics. These results suggest the feasibility of using Mg sheet closure panels from a structural perspective.

Organic acid degradation products and other anions in engine oil were speciated by capillary electrophoresis (CE) and liquid chromatography-mass spectrometry (LCMS) with electrospray ionization. The sample preparation procedure involved selectively extracting the acids and other water soluble salts into 0.05M aqueous potassium hydroxide. Samples of engine-aged mineral oil and synthetic engine oil contained formic acid, acetic acid, and complex mixtures of fatty acid degradation products. CE analysis of formic acid, acetic acid and selected fatty acids is proposed as a new chemical analysis method for evaluating the condition of engine oil and for studying the effects of high temperature-high load (HTHL) oxidation. Because the overall pattern of CE peaks in the electropherogram changes with oil age or condition, CE-fingerprint (i.e., pattern recognition) techniques may also be useful for evaluating an aged oil's condition or remaining service life.

One of the issues in stamping of advanced high strength steels (AHSS) is the stretch bending fracture on a sharp radius (commonly referred to as shear fracture). Shear fracture typically occurs at a strain level below the conventional forming limit curve (FLC). Therefore it is difficult to predict in computer simulations using the FLC as the failure criterion. A modified Mohr-Coulomb (M-C) fracture criterion has been developed to predict shear fracture. The model parameters for several AHSS have been calibrated using various tests including the butter-fly shaped shear test. In this paper, validation simulations are conducted using the modified (M-C) fracture criterion for a dual phase (DP) 780 steel to predict fracture in the stretch forming simulator (SFS) test and the bending under tension (BUT) test. Various deformation fracture modes are analyzed, and the range of usability of the criterion is identified.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

Due to magnesium alloy's poor weldability, other joining techniques such as laser assisted self-piercing rivet (LSPR) are used for joining magnesium alloys. This research investigates the fatigue performance of LSPR for magnesium alloys including AZ31 and AM60. Tensile-shear and coach peel specimens for AZ31 and AM60 were fabricated and tested for understanding joint fatigue performance. A structural stress - life (S-N) method was used to develop the fatigue parameters from load-life test results. In order to validate this approach, test results from multijoint specimens were compared with the predicted fatigue results of these specimens using the structural stress method. The fatigue results predicted using the structural stress method correlate well with the test results.

One approach of reducing weight of vehicles is using composite materials, and short glass fiber reinforced polypropylene is one of most popular composite materials. To more accurately predict durability performance of structures made of this kind of composite material, static and fatigue performance of coupons and components made of a short glass fiber reinforced polypropylene has been physically studied. CAE simulations have been conducted accordingly. This paper described details of CAE model setup, procedures, analysis results and correlations to test results for static, fiber orientation flow and fatigue of coupons and a battery tray component. The material configurations include fiber orientations (0, 20 and 90 degrees), and mean stress effect (R = -1.0, -0.5, -0.2, 0.1 and 0.4). The battery tray component samples experience block cycle loading with loading ratio of R = -0.3 and 0.3. The CAE predictions have reasonable correlations to the test results.

As CAFE requirements increase, automotive OEMs are pursuing innovative methods to lightweight their Body In Whites (BIWs). Within FCA US, this lightweighting research and development activity often occurs through Decoupled Innovation projects. A Decoupled Innovation team comprised of engineers from the BIW Structures Group, in collaboration with Tier 1 supplier Magna Exteriors, sought to re-design a loadbearing component on the BIW that would offer significant weight savings when the current steel component was replaced with a carbon fiber composite. This paper describes the design, development, physical validation and partnership that resulted in a composite Rear Package Shelf Assembly solution for a high-volume production vehicle. As the CAFE requirements loom closer and closer, these innovation-driven engineering activities are imperative to the successful lightweighting of FCA US vehicles.

Engine mount is one of the temperature sensitive components in the vehicle under-hood. Due to increasing requirements for improved fuel economy, the under-hood thermal management has become very challenging in recent years. In order to study the effects of material thermal degradation on engine mount performance and durability; it is required to estimate the temperature of engine mount rubber during various driving conditions. The effect of temperature on physical properties of natural rubber can then be evaluated and the life of engine mount can be estimated. In this paper, a bench test is conducted where the engine mount is exposed to a step change in the environment around it, and the temperature of the rubber section is recorded at several points till a steady state temperature is reached. A time response curve is generated, from which a time constant is determined.

Several popular frequency-based fatigue damage models (Wirsching and Light, Ortiz and Chen, Larsen and Lutes, Benascuitti and Tovo, Benascuitti and Tovo with α.75, Dirlik, Zhao and Baker, and Lalanne) are reviewed and assessed. Seventy power spectrum densities with varied amplitude, shape, and irregularity factors from Dirlik’s dissertation are used to study the accuracies of these methods. Recommendations on how to set up the inverse fast Fourier transform to synthesize load data and obtain accurate rainflow cycle counts are given. Since Dirlik’s method is the most commonly used one in industry, a comprehensive investigation of parameter setups for Dirlik’s method is presented. The mean error and standard deviation of the error between the frequency-based model and the rainflow cycle counting method was computed for fatigue slope exponent m ranging from 3 to 12.

An engine exhaust manifold undergoes repeated thermal expansion and contraction due to temperature variation. Thermomechanical fatigue (TMF) arises due to the boundary constraints on thermal expansion so that mechanical strain is introduced. Therefore, TMF evaluation is very important in engine design. In this work, the mechanical properties important for TMF assessment and modeling of a silicon (Si)- and molybdenum (Mo)-containing ductile cast iron used for exhaust manifold have been evaluated. Tensile, creep, isothermal low cycle fatigue (LCF), and TMF tests have been conducted. Parameters for material modeling, such as the viscoplastic constitutive model and the Neu-Sehitoglu TMF damage model, have been calibrated, validated, and used to evaluate the TMF life of the exhaust manifold.

Multiaxial loading on mechanical products is very common in the automotive industry, and how to design and analyze these products for durability becomes an important, urgent task for the engineering community. Due to the complex nature of the fatigue damage mechanism for a product under multiaxial state of stresses/strains which are dependent upon the modes of loading, materials, and life, modeling this behavior has always been a challenging task for fatigue scientists and engineers around the world. As a result, many multiaxial fatigue theories have been developed. Among all the theories, an existing equivalent stress theory is considered for use for the automotive components that are typically designed to prevent Case B cracks in the high cycle fatigue regime.

This article is concerned with identification of true stress-strain curve under biaxial tension of thermoplastic polymers. A new type of biaxial tension attachment was embedded first in a universal material test machine, which is able to transform unidirectional loading of the test machine to biaxial loading on the specimen with constant velocity. Cruciform specimen geometry was optimized via FE modeling. Three methods of calculating true stress in biaxial tension tests were compared, based on incompressibility assumption, linear elastic theory and inverse engineering method, respectively. The inverse engineering method is more appropriate for thermoplastic polymers since it considers the practical volume change of the material during biaxial tension deformation. The strategy of data processing was established to obtain biaxial tension true stress-strain curves of different thermoplastic polymers.

This work examines the effect of valve timing during cold crank-start and cold fast-idle (1200 rpm, 2 bar NIMEP) on the emissions of hydrocarbons (HC) and particulate mass and number (PM/PN). Four different cam-phaser configurations are studied in detail: 1. Baseline stock valve timing. 2. Late intake opening/closing. 3. Early exhaust opening/closing. 4. Late intake phasing combined with early exhaust phasing. Delaying the intake valve opening improves the mixture formation process and results in more than 25% reduction of the HC and of the PM/PN emissions during cold crank-start. Early exhaust valve phasing results in a deterioration of the HC and PM/PN emissions performance during cold crank-start. Nevertheless, early exhaust valve phasing slightly improves the HC emissions and substantially reduces the particulate emissions at cold fast-idle.

A new ring pack model has been developed based on the curved beam finite element method. This paper describes the first part of this model: simulating gas pressure in different regions above piston skirt and ring dynamic behavior of two compression rings and a twin-land oil control ring. The model allows separate grid divisions to resolve ring structure dynamics, local force/pressure generation, and gas pressure distribution. Doing so enables the model to capture both global and local processes at their proper length scales. The effects of bore distortion, piston secondary motion, and groove distortion are considered. Gas flows, gas pressure distribution in the ring pack, and ring structural dynamics are coupled with ring-groove and ring-liner interactions, and an implicit scheme is employed to ensure numerical stability. The model is applied to a passenger car engine to demonstrate its ability to predict global and local effects on ring dynamics and oil transport.

Developing lightweight, stiff and crash-resistant vehicle body structures requires a balance between part geometry and material properties. High strength materials suitable for crash resistance impose geometry limitations on depth of draw, radii and wall angles that reduce geometric efficiency. The introduction of 3rd generation Advanced High Strength Steels (AHSS) can potentially change the relationship between strength and geometry and enable simultaneous improvements in both. This paper will demonstrate applicability of 3rd generation AHSS with higher strength and ductility to replace the 780 MPa Dual Phase steel in a sill reinforcement on the current Jeep Cherokee. The focus will be on formability, beginning with virtual simulation and continuing through a demonstration run on the current production stamping tools and press.

The Hotelling multivariate control chart and the sample generalized variance |S| are used to monitor the mean and dispersion of vehicle build vision data including the pallet information to identify the non-conforming pallets that are used in body shops of FCA US LLC assembly plants. An iterative procedure and the Gaussian mixture model (GMM) are used to rank the non-conforming or bad pallets in the order of severity. The Hotelling multivariate T2 test statistic along with Mason-Tracy-Young (MYT) signal decomposition method is used to identify the features that are affected by the bad pallets. These algorithms were implemented in the Advanced Pallet Analysis module of the FCA US software Body Shop Analysis Toolbox (BSAT). The identified bad pallets are visualized in a scatter plot with a different color for each of the top bad pallets. The run chart of an affected feature confirms the bad pallet by highlighting data points from the bad pallet.

This paper describes an experimental study on the performance of self-piercing riveted (SPR) joints and adhesively bonded SPR joints connecting steel and aluminum components under both quasi-static and cyclic loading. The joint configurations cover a wide range of material gauges, types and grades. Two and three thickness joints, with and without adhesive are also part of this study. Load versus deflection behavior, load carrying capacity, fatigue life and the failure modes for each type of joint are discussed. This study focuses on the influence of dissimilar material and adhesives to the joint performance.