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Technical Paper

The Study of NOx and PM Reduction Using Urea Selective Catalytic Reduction System for Heavy Duty Diesel Engine

2007-04-16
2007-01-1576
To reduce NOx and Particulate Matter (PM) emissions from a heavy-duty diesel engine, the effects of urea selective catalytic reduction (SCR) systems were studied. Proto type urea SCR system was composed of NO oxidation catalyst, SCR catalyst and ammonia (NH3) reduction catalyst. The NOx reduction performance of urea SCR system was improved by a new zeolite type catalyst and mixer for urea distribution at the steady state operating conditions. NOx and PM reduction performance of the urea SCR system with DPF was evaluated over JE05 mode of Japan. The NOx reduction efficiency of the urea SCR catalyst system was 72% at JE05 mode. The PM reduction efficiency of the urea SCR catalyst system with DPF was 93% at JE05 mode. Several kinds of un-regulated matters were detected including NH3 and N2O leak from the exhaust gas. It is necessary to have further study for detailed measurements for un-regulated emissions from urea solution.
Technical Paper

Evaluation of Diesel Exhaust Emission of Advanced Emission Control Technologies using various Diesel Fuels, and Sulfur Effect on Performance after Mileage Accumulation. -JCAP Diesel WG (fuel) Report for Step II study-

2003-05-19
2003-01-1907
To investigate the future direction of diesel emission control technologies and fuel technologies, exhaust emissions tests of diesel vehicles/engines with advanced after-treatments such as NSR catalyst, CR-DPF, and Urea-SCR or a combination of these, were conducted using various fuels, and fuel sulfur effect on performance of the after-treatments after mileage accumulation was also evaluated in step II study of JCAP Diesel WG. Overall results shows that the after-treatments have significant effects on reducing emission and reducing fuel sulfur have significant effects on function of the after-treatments in term of decrease of sulfate and SOF, and less deterioration of function of after-treatments after mileage accumulation.
Technical Paper

Development of New Diesel Particulate Active Reduction System for both NOx and PM Reduction

2011-04-12
2011-01-1277
The new Diesel Particulate active Reduction (DPR) system was developed for a medium-duty commercial vehicle as a deNOx catalyst combined with the conventional DPR system to achieve the Japan Post New-Long-Term (JPNLT) emissions regulations. It consists of a catalyst converter named as the new DPR cleaner, a fuel dosing injector, NOx sensors, temperatures and pressure sensors. The new DPR cleaner was constructed from a Front Diesel Oxidation Catalyst (F-DOC), a catalyzed particulate Filter (Filter), and a Rear Diesel Oxidation Catalyst (R-DOC). A newly developed Hydrocarbon Selective Catalyst Reduction (HC-SCR) catalyst was employed for each catalyst aiming to reduce NOx emissions with diesel fuel supplied from the fuel dosing injector. While the total volume of the catalyst was increased, the compact and easy-to-install catalyst converter was realized through the optimization of the flow vector and flow distribution in it by means of Computational Fluid Dynamics (CFD) analysis.
Technical Paper

Impacts on Engine Oil Performance by the Use of Waste Cooking Oil as Diesel Fuel

2011-08-30
2011-01-2115
Technical impacts on engine oil performance by the use of waste cooking oil as bio-diesel fuel (BDF) are not well understood while the industry has made significant progress in studies on quality specifications and infrastructure. The authors, who consist of a consortium organized by Japan Lubricating Oil Society (JALOS), examined technical effects of waste cooking oil as BDF on engine oil performance such as wear and high temperature corrosion using vehicle fleets and bench tests to identify technical issues of engine oil meeting the use of BDF. The study brings fundamental information about technical impacts of BDF on engine oils.
Technical Paper

Study of 2-LEG NOx Storage-Reduction Catalyst System for HD Diesel Engine

2006-04-03
2006-01-0211
A 2-LEG NOx Storage-Reduction (NSR) catalyst system is one of potential after-treatment technology to meet stringent NOx and PM emissions standards as Post New Long Term (Japanese 2009 regulation) and US'10. Concerning NOx reduction using NSR catalyst, a secondary fuel injection is necessary to make fuel-rich exhaust condition during the NOx reduction, and causes its fuel penalty. Since fuel injected in the high-temperature (∼250 degrees Celsius) exhaust instantly reacts with oxygen in common diesel exhaust, the proportion of fuel consumption to reduce the NOx stored on NSR catalyst is relatively small. A 2-LEG NSR catalyst system has the decreasing exhaust flow mechanism during NOx reduction, and the potential to improve the NOx reduction and fuel penalty. Therefore, this paper studies the 2-LEG NSR catalyst system. The after-treatment system consists of NSR catalysts, a secondary fuel injection system, flow controlled valves and a Catalyzed Diesel Particulate Filter (CDPF).
Technical Paper

Improvement of Low-Temperature Performance of The NOx Reduction Efficiency on the Urea-SCR Catalysts

2013-04-08
2013-01-1076
Diesel engine has a good fuel economy and high durability and used widely for power source such as heavy duty in the world. On the other hand, it is required to reduce NOx (Nitrogen Oxides) and PM (Particulate Matter) emissions further from diesel exhaust gases to preserve atmosphere. The urea-SCR (Selective Catalytic Reduction) system is the most promising measures to reduce NOx emissions. DPF (Diesel Particulate Filter) system is commercialized for PM reduction. However, in case that a vehicle has a slow speed as an urban area driving, a diesel exhaust temperature is too low to activate SCR catalyst for NOx reduction in diesel emissions. Moreover, the diesel exhaust temperature becomes lower as a future engine has less fuel consumption. The purpose of this study is reduction of NOx emission from a heavy-duty diesel engine using the Urea SCR system at the low temperature.
Technical Paper

Impact of Oil-derived Sulfur and Phosphorus on Diesel NOx Storage Reduction Catalyst - JCAP II Oil WG Report

2006-10-16
2006-01-3312
Emission regulations for diesel-powered vehicles have been gradually tightening. Installation of after-treatment devices such as diesel particulate filters (DPF), NOx storage reduction (NSR) catalysts, and so on is indispensable to satisfy rigorous limits of particulate matter (PM) and nitrogen oxides (NOx). Japan Clean Air Program II Oil Working Group (JCAPII Oil WG) has been investigating the effect of engine oil on advanced diesel after-treatment devices. First of all, we researched the impact of oil-derived ash on continuous regeneration-type diesel particulate filter (CR-DPF), and already reported that the less sulfated ash in oil gave rise to lower pressure drop across CR-DPF [1]. In this paper, impact of oil-derived sulfur and phosphorus on NSR catalyst was investigated using a 4L direct injection common-rail diesel engine with turbo-intercooler. This engine equipped with NSR catalyst meets the Japanese new short-term emission regulations.
Technical Paper

Oxidative Deterioration Properties of FAME-Blended Diesel Fuel

2018-04-03
2018-01-0924
The correlation between newly approved EN 15751 and the internal diesel injector deposits (IDID) due to fuel oxidative deterioration has not been made clear. In the present research, the Rancimat method was slightly modified to research the relationship between fuel oxidative deterioration and the deterioration products generated from the fuel. After heating fuel at 120 to 150°C for a set period, insoluble deterioration products (IDID-like substances) were generated and their weights were measured. At the same time, the shifts of the conductivity in trap water were analyzed from a new perspective, and its relationship with the deterioration products was investigated. At 120°C and 130°C, conductivity rising rates after the inflection point (this set of data represents the rate of organic acid generation in the fuel, and we named “Oxidation rate”) exhibited a strong correlation with the quantity of deterioration products.
Technical Paper

The Reduction of Diesel Engine Emissions by Using the Oxidation Catalysts of Japan Diesel 13 Mode Cycle

1999-03-01
1999-01-0471
To reduce emissions from diesel engines, the effects of oxidation catalysts on the emissions reductions were studied. The effectiveness of several oxidation catalysts on both the regulated and unregulated emissions was evaluated. The oxidation activity of the catalysts was varied by changing Pt loading. The regulated emissions include particulate (PM), hydrocarbon (HC), and carbon monoxide (CO), and the unregulated emissions include benzene, formaldehyde, acetaldehyde, and benzo[a]pyrene (B[a]P). An 8 litter, turbocharged and aftercooled diesel engine was operated under the Japan Diesel 13 (D13) mode cycle for the evaluations. As the first step, evaluations were conducted with a commercially available JIS #2 diesel fuel (0.046 wt% sulfur). All the regulated and unregulated emissions except PM were reduced as the Pt loading (i.e. oxidation activity) increased. However, PM emissions were increased by the generation of sulfate when the Pt loading exceeded 0.2 g/l.
Technical Paper

Effects of Alloying Elements on Wear Resistance of Automobile Cast Iron Materials

2014-04-01
2014-01-1011
Wear resistance is the important characteristics of cast iron materials for automobile components. Because the phenomenon of wear is a highly complicated mechanism involving many factors such as surface conditions, chemical reactions with lubricants, metals, and physics, it has not been fully explained. Therefore, it will be necessary to confirm and explain the wear mechanism to develop effective improvements. The purpose of this study was to investigate the structural change behavior and effects of alloying elements when the material top surface becomes worn, in order to improve the wear resistance of cylinder liners and other cast iron materials. For this purpose, several types of prototype materials were produced, and the relationship between components and wear resistance was investigated by using a laser microscope for quantitative observation of the degree of pearlite microstructure fineness.
Technical Paper

Research on a DPF Regeneration Burner System for Use when Engine is not in Operation

2019-12-19
2019-01-2237
An on board burner that enables DPF regeneration even when an engine is at standstill has been researched. By employing pre evaporative combustion with a wick burner, miniaturization of the burner system was successfully accomplished as well as stable ignition and combustion. Total heat necessary for DPF regeneration was reduced in comparison to the active DPF regeneration by means of engine control and an oxidation catalyst. Uneven temperature distribution in DPF and excessive temperature rise, which had been recognized as issues in the regeneration of a DPF while engine is at standstill, were solved by increase of combustion air amount and multi-step control of regeneration temperature and reliable regeneration was accomplished.
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