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An operational scheme with fuel-lean and exhaust gas dilution in spark-ignited engines increases thermal efficiency and decreases NOx emission, while these operations inherently induce combustion instability and thus large cycle-to-cycle variation in engine. In order to stabilize combustion variations, the development of an advanced ignition system is becoming critical. To quantify the impact of spark-ignition discharge, ignitability tests were conducted in an optically accessible combustion vessel to characterize the flame kernel development of lean methane-air mixture with CO₂ simulating exhaust diluent. A shrouded fan was used to generate turbulence in the vicinity of J-gap spark plug and a Variable Output Ignition System (VOIS) capable of producing a varied set of spark discharge patterns was developed and used as an ignition source. The main feature of the VOIS is to vary the secondary current during glow discharge including naturally decaying and truncated with multiple strikes.

A Ford 2.4-liter 115PS light-duty diesel engine was modified to allow solenoid control of the oil feed to the piston cooling jets, enabling these to be switched on or off on demand. The influence of the jets on piston temperatures, engine thermal state, gaseous emissions and fuel economy has been investigated. With the jets switched off, piston temperatures were measured to be between 23 and 88°C higher. Across a range of speed-load points, switching off the jets increased engine-out emissions of NOx typically by 3%, and reduced emissions of CO by 5-10%. Changes in HC were of the same order and were reductions at most conditions. Fuel consumption increased at low-speed, high-load conditions and decreased at high-speed, low-load conditions. Applying the results to the NEDC drive cycle suggests active on/off control of the jets could reduce engine-out emissions of CO by 6%, at the expense of a 1% increase in NOx, compared to the case when the jets are on continuously.

A two-brick gasoline engine aftertreatment system with advanced washcoat technology was developed for LEV2 PZEV2 legislation, and its application to the upcoming LEV3 SULEV30 emission standard was demonstrated. The system was comprised of 1) a palladium only catalyst in the close coupled position with improved catalytic performance and high phosphorus poisoning resistance compared with 09MY technology, and 2) an underfloor palladium rhodium catalyst technology in which the nitric oxides (NOx) reduction activity was enhanced by preventing the deactivation of rhodium under rich conditions. As a result, the palladium only + palladium rhodium catalysts system met the LEV2 PZEV standard with three quarters of the PGM and half the rhodium of the system used on the Honda 09MY Accord vehicle. The system was also demonstrated to meet the LEV3 SULEV30 standard with some margin.

U.S. federal vehicle emission standards effective in 2007 require tight control of NOx and hydrocarbon emissions. For light-duty vehicles, the current standard of Tier 2 Bin 5 is about 0.07 g/mi NOx and 0.09 g/mi NMOG (non-methane organic gases) at 120,000 mi. However, the proposed future standard is 0.03 g/mi for NMOG + NOx (~SULEV30) at 150,000 mi. There is a significant improvement needed in catalyst system efficiencies for diesel vehicles to achieve the future standard, mainly during cold start. In this study, a less than 6000 lbs diesel truck equipped with an advanced urea Selective Catalytic Reduction (SCR) system was used to pursue lower tailpipe emissions with an emphasis on vehicle calibration and catalyst package. The calibration was tuned by optimizing exhaust gas recirculation (EGR) fuel injection and cold start strategy to generate desirable engine-out emissions balanced with reasonable temperatures.

Exhaust gas recirculation (EGR) coolers are commonly used in diesel engines to reduce the temperature of recirculated exhaust gases in order to reduce NOx emissions. The presence of a cool surface in the hot exhaust causes particulate soot deposition as well as hydrocarbon and water condensation. Fouling experienced through deposition of particulate matter and hydrocarbons results in degraded cooler effectiveness and increased pressure drop. In this study, a visualization test setup is designed and constructed so that the effect of water condensation on the deposit formation and growth at various coolant temperatures can be studied. A water-cooled surrogate rectangular channel is employed to represent the EGR cooler. One side of the channel is made of glass for visualization purposes. A medium duty diesel engine is used to generate the exhaust stream.

For spark-ignition gasoline engines operating under the wide speed and load conditions required for light duty vehicles, ignition quality limits the ability to minimize fuel consumption and NOx emissions via dilution under light and part load conditions. In addition, during transients including tip-outs, high levels of dilution can occur for multiple combustion events before either the external exhaust gas can be adjusted and cleared from the intake or cam phasing can be adjusted for correct internal dilution. Further improvement and a thorough understanding of the impact of the ignition system on combustion near the dilution limit will enable reduced fuel consumption and robust transient operation. To determine and isolate the effects of multiple parameters, a variable output ignition system (VOIS) was developed and tested on a 3.5L turbocharged V6 homogeneous charge direct-injection gasoline engine with two spark plug gaps and three ignition settings.

As a renewable energy source, the ethanol fuel was employed with a diesel fuel in this study to improve the cylinder charge homogeneity for high load operations, targeting on ultra-low nitrogen oxides (NOx) and smoke emissions. A light-duty diesel engine is configured to adapt intake port fuelling of the ethanol fuel while keeping all other original engine components intact. High load experiments are performed to investigate the combustion control and low emission enabling without sacrificing the high compression ratio (18.2:1). The intake boost, exhaust gas recirculation (EGR) and injection pressure are independently controlled, and thus their effects on combustion and emission characteristics of the high load operation are investigated individually. The low temperature combustion is accomplished at high engine load (16~17 bar IMEP) with regulation compatible NOx and soot emissions.

Alkali and alkaline earth metal impurities found in diesel fuels are potential poisons for diesel exhaust catalysts. Using an accelerated aging procedure, a set of production exhaust systems from a 2011 Ford F250 equipped with a 6.7L diesel engine have been aged to an equivalent of 150,000 miles of thermal aging and metal exposure. These exhaust systems included a diesel oxidation catalyst (DOC), selective catalytic reduction (SCR) catalyst, and diesel particulate filter (DPF). Four separate exhaust systems were aged, each with a different fuel: ULSD containing no measureable metals, B20 containing sodium, B20 containing potassium and B20 containing calcium. Metals levels were selected to simulate the maximum allowable levels in B100 according to the ASTM D6751 standard. Analysis of the aged catalysts included Federal Test Procedure emissions testing with the systems installed on a Ford F250 pickup, bench flow reactor testing of catalyst cores, and electron probe microanalysis (EPMA).

Diesel engines provide a solution for the reduction of carbon dioxide (CO2) from motor vehicles. For diesel engines, however, technology to reduce nitrogen oxide (NOx) emissions is essential. This report focuses on Urea - Selective Catalytic Reduction (SCR) as an aftertreatment system for NOx reduction. The NOx conversion performance of SCR catalyst depends on exhaust gas temperature and the NO2/NOX ratio. In order to raise the NO2/NOX ratio, it is essential to raise the temperature of oxidation catalyst. For these purposes, it is necessary to raise the temperature of oxidation catalyst and SCR catalyst to high level in order to enhance NOx conversion. Temperature rising is implemented by in-cylinder fuel injection (post-injection).

A diesel engine is possible solution for carbon dioxide (CO2) reduction from automobiles. However, it is necessary for a diesel engine vehicle to reduce nitrogen oxide (NOx) emission. Therefore, this research focused on a Urea-selective catalytic reduction (urea-SCR) system as an after-treatment system to convert NOx and proposes the control method of the urea-SCR system based on the output of an ammonia (NH3) sensor. By maximizing NH3 storage rate of the SCR, conversion performance is maximized. To maximize the NH3 storage rate, an NH3 sensor is installed downstream of the SCR. The amount of urea-solution is controlled to keep NH3 slip detected by the sensor. Thus, the NH3 storage amount in the SCR or the SCRF (SCR on filter) can be maximized. The estimation and the control of NH3 storage amount is also used to cause NH3 slip immediately. NH3 storage capacity changes with catalyst temperature. In a transient state, temperature distribution occurs in the SCR catalyst.