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A Study of PGM-Free Oxidation Catalyst YMnO3 for Diesel Exhaust Aftertreatment

2012-06-18
Currently, two consolidated aftertreatment technologies are available for the reduction of NOx emissions from diesel engines: Urea SCR (Selective Catalytic Reduction) systems and LNT (Lean NOx Trap) systems. Urea SCR technology, which has been widely used for many years at stationary sources, is becoming nowadays an attractive alternative also for light-duty diesel applications. However, SCR systems are much more effective in NOx reduction efficiency at high load operating conditions than light load condition, characterized by lower exhaust gas temperatures.
Journal Article

Effect of Surface Heat Treatment on Corrosion-Related Failure of the Suspension Spring

2015-04-14
2015-01-0518
In this research, a new wire material made using surface-reforming heat treatment was developed in order to enhance the corrosion fatigue resistance of suspension springs. The aim of surface reforming is to improve hydrogen embrittlement characteristics through grain refinement and to improve crack propagation resistance by partial softening of hardness. The grain refinement method used an α'→γ reversed transformation by rapid short-term heating in repeated induction heating and quenching (R-IHQ) to refine the crystal grain size of SAE 9254 steel spring wire to 4 μm or less. In order to simultaneously improve the fatigue crack propagation characteristics, the possibility of reducing the hardness immediately below the spring surface layer was also examined. By applying contour hardening in the second IHQ cycle, a heat affected zone (HAZ) is obtained immediately below the surface.
Technical Paper

Improvement of Heat Resistance for Lean NOx Catalyst

2004-03-08
2004-01-1495
When the alkali metal-supported catalyst was treated at 830°C, the NOx conversion decreased because the alkali metals in the catalyst layer gradually moved to the cordierite honeycomb layer and reacted with the cordierite elements. This phenomena decreased to be added the basic metal oxide (α) in the catalyst layer. The improved catalyst with α 2 showed higher performance than the conventional catalyst in the model gas test. Moreover, the emission values of NOx, HC, and CO were 50% or less than Japanese domestic regulation values even after 830°C×60h heat treatment in a vehicle test.
Technical Paper

Development of Metal Pushing V-Belt for Continuously Variable Transmission - Investigation for Clearance Between Elements, Strength of Element and Strength of Ring Material

2003-03-03
2003-01-0968
HONDA completed research and development of the Metal V-Belt for CVTs in-house for the purpose of reducing the minimum pitch radius. The newly developed belt is essential to the compactness of a CVT and increases the speed ratio range. Increase of ring stress caused by reducing the minimum pitch radius is treated by improvement of element shape, optimizing clearance between elements and between element and ring and improving materials.(1) In this paper, the optimization of clearance between elements, heat treatment of elements and optimization of ring material are described in detail. Optimum total clearance between elements for a virgin belt is defined by test results during operation using a specially engraved gap sensor and a telemeter system. Tolerance and conditions of heat treatment for elements are optimized concerning fatigue strength of the element nose.
Technical Paper

Improvement of Thermal Resistance for Lean NOx Catalyst

2003-03-03
2003-01-1166
A new type of lean NOx catalyst has been developed with improved thermal resistance. This lean NOx catalyst contains precious metals and NO2 adsorbents. The precious metals are used mainly for the oxidation reaction of NO, and the NO2 adsorbents are for the adsorption removal of generated NO2. The thermal resistance of the catalyst was raised by paying attention to the following points. 1) Improvement of thermal resistance for the NO oxidation activity by addition of a different precious metal element. 2) Prevention of thermal degradation of the NO2 adsorbent by addition of a new metal oxide. For item 1, Pd was added to the catalyst which had already included Pt. By having Pd coexist with Pt, the precious metal dispersion was kept high even after heat treatment, so the NO oxidizing ability was improved. For item 2, thermal degradation of NO2 adsorbent was prevented by addition of the new metal oxide (B) to the adsorbent.
Technical Paper

Temperature Prediction of Actual Contact Portion of the Metal Belt CVT

2018-04-03
2018-01-0122
In a previous study by the authors, austenite (γ phase) formed on the topmost of pulleys after long term operation of continuously variable transmission (CVT) [1]. In general, martensite arising from heat treatment forms on the surface of pulleys and gears. Therefore, the sliding surface has a body-centered cubic (BCC) metal structure, and transformation into and existence of austenite (γ phase) is difficult unless there is a thermal history exceeding the eutectoid point. For the verification of that possibility, it was crucial to obtain temperature variation on the sliding surface. The major problem for such measurements was rotation of parts inside an operating CVT. In this study, uniquely developed measurement system enabled non-contact temperature measurement near the contact portion. Results were substituted to heat conduction equation to predict the temperature at the exact contact portion.
Technical Paper

A Study of PGM-Free Oxidation Catalyst YMnO3 for Diesel Exhaust Aftertreatment

2012-04-16
2012-01-0365
Manganese oxides show high catalytic activity for CO and HC oxidation without including platinum group metals (PGM). However, there are issues with both thermal stability and resistance to sulfur poisoning. We have studied perovskite-type YMnO₃ (YMO) with the aim of simultaneously achieving both activity and durability. This paper describes the oxidation activity of PGM-free Ag/i-YMO, which is silver supported on improved-YMO (i-YMO). The Ag/i-YMO was obtained by the following two methods. First, Mn⁴+ ratio and specific surface area of YMO were increased by optimizing composition and preparation method. Second, the optimum amount of silver was supported on i-YMO. In model gas tests and engine bench tests, the Ag/i-YMO catalyst showed the same level of activity as that of the conventional Pt/γ-Al₂O₃ (Pt = 3.0 g/L). In addition, there was no degradation with respect to either heat treatment (700°C, 90 h, air) or sulfur treatment (600°C to 200°C, total 60 h, 30 ppm SO₂).
Technical Paper

Research Into Surface Improvement for Low Friction Pistons

2005-04-11
2005-01-1647
1 A new surface modification heat treatment technology called Wonder Process Craft which is different from plating and coating, was applied to the skirt section, which is the sliding surface of the piston in an internal combustion engine. This was intended to improve fuel economy and mechanical characteristics by reducing sliding resistance. In the application of solid lubrication, this treatment does not require the usage of binder, which was necessary for conventional coating, leading to the highest level achievable for the low sliding resistance effect inherent of solid lubrication. Since this treatment does not involve any change in significant dimensions, shapes, surface roughness, and so on, applying this treatment is easy. The persistence of the effect, productivity and recyclability of waste and emissions during treatment were also taken into account.
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