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In this research, a new wire material made using surface-reforming heat treatment was developed in order to enhance the corrosion fatigue resistance of suspension springs. The aim of surface reforming is to improve hydrogen embrittlement characteristics through grain refinement and to improve crack propagation resistance by partial softening of hardness. The grain refinement method used an α'→γ reversed transformation by rapid short-term heating in repeated induction heating and quenching (R-IHQ) to refine the crystal grain size of SAE 9254 steel spring wire to 4 μm or less. In order to simultaneously improve the fatigue crack propagation characteristics, the possibility of reducing the hardness immediately below the spring surface layer was also examined. By applying contour hardening in the second IHQ cycle, a heat affected zone (HAZ) is obtained immediately below the surface.

Recent trends to downsize engines have resulted in lighter weight and greater compactness. At the same time, however, power density has increased due to the addition of turbocharger and other such means to supplement engine power and torque, and this has increased the thermal and mechanical load. In this kind of environment, corrosion of the copper alloy bushing (piston pin bushing) that is press-fitted in the small end of the connecting rod becomes an issue. The material used in automobile bearings, of which the bushing is a typical example, is known to undergo sulfidation corrosion through reaction with an extreme-pressure additive Zinc Dialkyldithiophosphate (ZnDTP) in the lubricating oil. However, that reaction path has not been clarified. The purpose of the present research, therefore, is to clarify the reaction path of ZnDTP and copper in an actual engine environment.

Since 2000, an Aluminum Cosmetic Corrosion task group within the SAE Automotive Corrosion and Protection (ACAP) Committee has existed. The task group has pursued the goal of establishing a standard test method for in-laboratory cosmetic corrosion evaluations of finished aluminum auto body panels. A cooperative program uniting OEM, supplier, and consultants has been created and has been supported in part by USAMP (AMD 309) and the U.S. Department of Energy. Prior to this committee's formation, numerous laboratory corrosion test environments have been used to evaluate the performance of painted aluminum closure panels. However, correlations between these laboratory test results and in-service performance have not been established. Thus, the primary objective of this task group's project was to identify an accelerated laboratory test method that correlates well with in-service performance.

There is an increasing global realization about the need for fuel efficient vehicles. An inexpensive way to accomplish this is through mass reduction, and one of the most effective ways that this can occur is through substituting current materials with magnesium, the lightest structural metal. This document describes the results of a U.S. Automotive Materials Partnership (USAMP) sponsored study [1] that examines why magnesium use has only grown 10% per year and identifies how to promote more widespread commercial applications beyond the 5-6 kg of component currently in vehicles. The issues and concerns which have limited magnesium use are discussed via a series of research and development themes. These address concerns associated with corrosion, fastening, and minimal metalworking/non-traditional casting processing. The automotive and magnesium supplier industries have only a limited ability to develop implementation-ready magnesium components.

Conventionally, the Ni-based superalloys NCF3015 (30Ni-15Cr) and the high nickel content NCF440 (70Ni-19Cr) (with its outstanding wear resistance and corrosion resistance), have been used as engine exhaust valve materials. In recent years, automobile exhaust gases have become hotter because of exhaust gas regulations and enhanced fuel consumption efficiency. Resource conservation and cost reductions also factor into global environmental challenges. To meet these requirements, NCF5015 (50Ni-15Cr), a new resource-conserving, low-cost Ni-based heat-resistant alloy with similar high-temperature strength and wear resistance as NCF440, has been developed. NCF5015's ability to simultaneously provide wear resistance, corrosion resistance and strength when NCF5015 is used with diesel engines was verified and the material was then used in exhaust valves.

The environmental performance of automobiles and automobile engines in particular is the foremost issue in the automotive industry today. In addition, engine durability performance is an essential aspect of engine oil performance. Four-cycle motorcycle engine oils formulated with dialkyl phosphate, a sulfur-free additive developed as an alternative to ZDDP, provide excellent environmental and durability performance in terms of longer drain intervals, cleanliness and low corrosion properties.

The equipment for collecting dilute exhaust samples involves the use of bag materials (i.e., Tedlar®) that emit hydrocarbons that contaminate samples. This study identifies a list of materials and treatments to produce bags that reduce contamination. Based on the average emission rates, baked Tedlar®, Capran® treated with alumina deposition, supercritical CO2 extracted Kynar® and supercritical CO2 extracted Teflon NXT are capable of achieving the target hydrocarbon emission rate of less than 15 ppbC per 30 minutes. CO2 permeation tests were also performed. Tedlar, Capran, Kynar and Teflon NXT showed comparable average permeation rates. Based on the criteria of HC emission performance, changes in measured CO2 concentration, ease of sealing, and ease of surface treatment, none of the four materials could be distinguished from one another.

The International Lubricant Standardization and Approval Committee (ILSAC) ATF subcommittee members have compared the two oxidation bench test methods, Aluminum Beaker Oxidation Test (ABOT) and Indiana Stirring Oxidation Stability Test (ISOT), using a number of factory-fill and service-fill ATFs obtained in Japan and in the US. In many cases, the ATFs were more severely oxidized after the ABOT procedure than after the same duration of the ISOT procedure. The relative severity of these two tests was influenced by the composition of the ATFs. The bench test oxidation data were compared with the transmission and the vehicle oxidation test data.

The Automotive Aluminum Alliance in conjunction with SAE ACAP founded a corrosion task group in 2000 with a goal to establish an in-laboratory cosmetic corrosion test for finished aluminum auto body panels, which provides a good correlation with in-service performance. Development of this test involves a number of key steps that include: (1) Establishing a reservoir of standard test materials to provide a well-defined and consistent frame of reference for comparing test results; (2) Defining a real-world performance for the reference materials through on-vehicle tests conducted in the U.S. and Canada; (3) Evaluating existing laboratory, proving ground, and outdoor tests; (4) Conducting statistically designed experiments to evaluate the effects of cyclic-test variables; (5) Comparing corrosion mechanisms of laboratory and on-vehicle tests; and (6) Conducting a round robin test program to determine the precision of the new test. Several of these key steps have been accomplished.

A new type of lean NOx catalyst has been developed with improved thermal resistance. This lean NOx catalyst contains precious metals and NO2 adsorbents. The precious metals are used mainly for the oxidation reaction of NO, and the NO2 adsorbents are for the adsorption removal of generated NO2. The thermal resistance of the catalyst was raised by paying attention to the following points. 1) Improvement of thermal resistance for the NO oxidation activity by addition of a different precious metal element. 2) Prevention of thermal degradation of the NO2 adsorbent by addition of a new metal oxide. For item 1, Pd was added to the catalyst which had already included Pt. By having Pd coexist with Pt, the precious metal dispersion was kept high even after heat treatment, so the NO oxidizing ability was improved. For item 2, thermal degradation of NO2 adsorbent was prevented by addition of the new metal oxide (B) to the adsorbent.

The PVC(poly-vinyl chloride) underbody coating was specifically designed for the automotive underfloor area in order to prevent chipping damage as well as the onset of rust propagation from a scratched point. This superior anti-chipping performance can also be achieved without increasing film thickness of the PVC by balancing film strength and adhesion strength. Also, by incorporating plastic balloons in the PVC formulation, a dried film specific gravity of less than 1.0 is achieved, and consequently a 2 kg weight reduction becomes possible when compared to conventional materials used for underbody coating.

For the purpose of developing onboard gasoline reforming technology for higher octane number fuel on demand, octane number enhancement of gasoline surrogate by aerobic oxidation using N-hydroxyphthalimide catalyst was investigated. At first, octane numbers of the oxygen-containing products from alkane and aromatic compound were estimated using a fuel ignition analyzer. As a result, not only alcohol but also ketones and aldehydes have higher octane numbers than the original alkanes and aromatic compound. Next, gasoline surrogate was oxidized aerobically with N-hydroxyphthalimide derivative catalyst and cobalt catalyst at conditions below 100 °C. As a result, fuel molecules were oxidized to produce alcohols, ketones, aldehydes, and carboxylic acids. N-hydroxyphthalimide derivative catalyst with higher solubility in gasoline surrogate has higher oxidation ability. Furthermore, the estimated octane number of the oxidized gasoline surrogate improves 17 RON.

Manganese oxides show high catalytic activity for CO and HC oxidation without including platinum group metals (PGM). However, there are issues with both thermal stability and resistance to sulfur poisoning. We have studied perovskite-type YMnO₃ (YMO) with the aim of simultaneously achieving both activity and durability. This paper describes the oxidation activity of PGM-free Ag/i-YMO, which is silver supported on improved-YMO (i-YMO). The Ag/i-YMO was obtained by the following two methods. First, Mn⁴+ ratio and specific surface area of YMO were increased by optimizing composition and preparation method. Second, the optimum amount of silver was supported on i-YMO. In model gas tests and engine bench tests, the Ag/i-YMO catalyst showed the same level of activity as that of the conventional Pt/γ-Al₂O₃ (Pt = 3.0 g/L). In addition, there was no degradation with respect to either heat treatment (700°C, 90 h, air) or sulfur treatment (600°C to 200°C, total 60 h, 30 ppm SO₂).

As automobile power needs increase 42-volt electrical systems are being proposed for use in consumer vehicles. One concern when using these new systems is the corrosion resistance of these components, especially in underhood environments. Corrosion is an electrochemical phenomenon and as such can be altered (increased or decreased) by the application of an external current or voltage. Although unintentional, the use of a higher voltage electrical system has the ability to increase corrosion through its normal use. This program evaluated the impact of corrosion on electrical components powered by 14 and 42-volt DC systems. Accelerated corrosion test findings suggested that 42-volt systems may be more susceptible to corrosion, but without proper environmental shielding both supply system can have unacceptable degradation.

High viscosity index(HVI) petroleum base stock, with excellent temperature-viscosity characteristics, oxidation resistance, and low-evaporation properties, offers advantages as the base stock for high fuel economy engine oils, particularly because of its low-friction properties in the boundary and/or “E.H.L (Elastohydrodynamic Lubrication)” area due to its rheological characteristics. This research evaluated HVI base stock's low-friction properties. Upgrading the oil from 5W-30 to 5W-20 was also investigated. The friction properties of the HVI base stock were measured by a unit friction platform. The results show a 28% reduction in friction coefficient compared with the conventional, solvent refined oil, which is attributable to the high-pressure viscosity of the base oil.

Gas shielded metal arc welding is generally applied to automobile chassis parts. However, the weld parts with the E-coat show poor corrosion resistance. Therefore, the corrosion mechanism of the weld parts was investigated. The results found two reasons why the weld parts corroded faster than the non weld parts:(1)inadequate phosphating (2)defects in the E-coat. After detailed investigation, it was clarified that the major cause of poor corrosion resistance was the defects in the E-coat caused by slags formed on the surface of the weld bead. Therefore the amount of slag has to be decreased to improve the corrosion resistance. The effect of shielding gas composition on the amount of slag was then investigated. In the case of Ar and oxidizing gas mixture, the corrosion resistance improved as the oxidizing gas content decreased. This was due to the reduction of slags.

The use of low-density materials in body panels is increasing as a measure to reduce the weight of the vehicle body. Honda has developed an aluminum/steel sheet hybrid door that is more effective in reducing weight than an all-aluminum door. Because aluminum was used in the door skin, bimetallic corrosion at the connection between the aluminum and the steel sheets represented an issue. It was possible that the difference in the electrical potential of the two metals might promote corrosion at the connection between the aluminum door skin and the steel sheet door panel, in particular at the lower edge of the door, where rainwater and other moisture tend to accumulate, with the result that the appeal of the exterior of the door might decline.

Durability requirements for exhaust materials have resulted in the increased use of stainless steels throughout the exhaust system. The conversion of carbon steel exhaust flanges to stainless steel has occurred on many vehicles. Ferritic stainless steels are commonly used for exhaust flanges. Flange construction methods include stamped sheet steel, thick plate flanges and powder metal designs. Flange material selection criteria may include strength, oxidation resistance, weldability and cold temperature impact resistance. Flange geometry considerations include desired stiffness criteria, flange rotation, gasket/sealing technique and vehicle packaging. Both the material selection and flange geometry are considered in terms of meeting the desired durability and cost. The cyclic oxidation performance of the material is a key consideration when selecting flange materials.

General Motor's Corvette product engineering was given the challenge to find mass reduction opportunities on the painted body panels of the C6 Z06 through the utilization of carbon fiber reinforced composites (CFRC). The successful implementation of a carbon fiber hood on the 2004 C5 Commemorative Edition Z06 Corvette was the springboard for Corvette Team's appetite for a more extensive application of CFRC on the C6 Z06 model. Fenders were identified as the best application for the technology given their location on the front of the vehicle and the amount of mass saved. The C6 Z06 CFRC fenders provide 6kg reduction of vehicle mass as compared to the smaller RRIM fenders used on the Coupe and Convertible models.

A co-operative program initiated by the Automotive Aluminum Alliance and supported by USAMP continues to pursue the goal of establishing an in-laboratory cosmetic corrosion test for finished aluminum auto body panels that provides a good correlation with in-service performance. The program is organized as a task group within the SAE Automotive Corrosion and Protection (ACAP) Committee. Initially a large reservoir of test materials was established to provide a well-defined and consistent specimen supply for comparing test results. A series of laboratory procedures have been conducted on triplicate samples at separate labs in order to evaluate the reproducibility of the various lab tests. Exposures at OEM test tracks have also been conducted and results of the proving ground tests have been compared to the results in the laboratory tests. Outdoor tests and on-vehicle tests are also in progress. An optical imaging technique is being utilized for evaluation of the corrosion.