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Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

Research has been conducted on Controlled Auto-Ignition (CAI) engine with natural gas. CAI engine has the potential to be highly efficient and to produce low emissions. CAI engine is potentially applicable to automobile engine. However due to narrow operating range, CAI engine for automobile engine which require various speed and load in real world operation is still remaining at research level. In comparison some natural gas engines for electricity generation only require continuous operation at constant load. There is possibility of efficiency enhancement by CAI combustion which is running same speed at constant load. Since natural gas is primary consisting of methane (CH4), high auto-ignition temperature is required to occur stable auto-ignition. Usually additional intake heat required to keep stable auto-ignition. To keep high compression temperature, single cylinder natural gas engine with high compression ratio (CR=26) was constructed.

In this research, a new wire material made using surface-reforming heat treatment was developed in order to enhance the corrosion fatigue resistance of suspension springs. The aim of surface reforming is to improve hydrogen embrittlement characteristics through grain refinement and to improve crack propagation resistance by partial softening of hardness. The grain refinement method used an α'→γ reversed transformation by rapid short-term heating in repeated induction heating and quenching (R-IHQ) to refine the crystal grain size of SAE 9254 steel spring wire to 4 μm or less. In order to simultaneously improve the fatigue crack propagation characteristics, the possibility of reducing the hardness immediately below the spring surface layer was also examined. By applying contour hardening in the second IHQ cycle, a heat affected zone (HAZ) is obtained immediately below the surface.

Bio-ethanol is used in many areas of the world as ethanol blended gasoline at low concentrations such as “E10 gasoline”. In this study, a method was examined to effectively use this small amount of ethanol within ethanol blended gasoline to improve thermal efficiency and high-load performance in a high-compression-ratio engine. Ethanol blended gasoline was separated into high-concentration ethanol fuel and gasoline using a fuel separation system employing a membrane. High-ethanol-concentration fuel was selectively used at high-load conditions to suppress knocking. In this system, a method to decrease ethanol consumption is necessary to cover the wide range of engine operation. Lower ethanol consumption could be achieved by Miller-cycle operation because decrease of the effective compression ratio suppresses knocking. However, high-load operation was limited due to the decrease in intake air volume with Miller-cycle operation.

Research to respond to demands for improving usability of passenger vehicles has played important roles. Some aspects can be attributed to friction behavior of the steering and suspension components. In this study, we focus on an approach to improve handling, steering feel and ride-comfort of a vehicle by applying the appropriate friction behavior to tie-rod end ball joint. To control not only friction coefficient but also static-kinetic transient behavior, we investigate the potential use of diamond-like carbon (DLC) coatings. Different DLC coatings varied widely in hydrogen content, mechanical properties and micro-surface roughness are applied to the ball studs. Friction behavior corresponds to material characteristics and surface roughness of DLC.

The gasoline direct injection (GDI) engine particulate emission sources are assessed under cold start conditions: the fast idle and speed/load combinations representative of the 1st acceleration in the US FTP. The focus is on the accumulation mode particle number (PN) emission. The sources are non-fuel, combustion of the premixed charge, and liquid fuel film. The non-fuel emissions are measured by operating the engine with premixed methane/air or hydrogen/air. Then the PN level is substantially lower than what is obtained with normal GDI operation; thus non-fuel contribution to PN is small. When operating with stoichiometric premixed gasoline/air, the PN level is comparable to the non-fuel level; thus premixed-stoichiometric mixture combustion does not significantly generate particulates. For fuel rich premixed gasoline/air, PN increases dramatically when lambda is less than 0.7 to 0.8.

A new hydrogen fueling protocol named MC Formula Moto was developed for fuel cell motorcycles (FCM) with a smaller hydrogen storage capacity than those of light duty FC vehicles (FCV) currently covered in the SAE J2601 standard (over than 2kg storage). Building on the MC Formula based protocol from the 2016 SAE J2601 standard, numerous new techniques were developed and tested to accommodate the smaller storage capacity: an initial pressure estimation using the connection pulse, a fueling time counter which begins the main fueling time prior to the connection pulse, a pressure ramp rate fallback control, and other techniques. The MC Formula Moto fueling protocol has the potential to be implemented at current hydrogen stations intended for fueling of FCVs using protocols such as SAE J2601. This will allow FCMs to use the existing and rapidly growing hydrogen infrastructure, precluding the need for exclusive dispensers or stations.

Bioethanol is being used as an alternative fuel throughout the world based on considerations of reduction of CO2 emissions and sustainability. It is widely known that ethanol has an advantage of high anti-knock quality. In order to use the ethanol in ethanol-blended gasoline to control knocking, the research discussed in this paper sought to develop a fuel separation system that would separate ethanol-blended gasoline into a high-octane-number fuel (high-ethanol-concentration fuel) and a low-octane-number fuel (low-ethanol-concentration fuel) in the vehicle. The research developed a small fuel separation system, and employed a layout in which the system was fitted in the fuel tank based on considerations of reducing the effect on cabin space and maintaining safety in the event of a collision. The total volume of the components fitted in the fuel tank is 6.6 liters.

This paper quantifies the potential of electric propulsion systems to reduce petroleum use and greenhouse gas (GHG) emissions in the 2030 U.S. light-duty vehicle fleet. The propulsion systems under consideration include gasoline hybrid-electric vehicles (HEVs), plug-in hybrid vehicles (PHEVs), fuel-cell hybrid vehicles (FCVs), and battery-electric vehicles (BEVs). The performance and cost of key enabling technologies were extrapolated over a 25-30 year time horizon. These results were integrated with software simulations to model vehicle performance and tank-to-wheel energy consumption. Well-to-wheel energy and GHG emissions of future vehicle technologies were estimated by integrating the vehicle technology evaluation with assessments of different fuel pathways. The results show that, if vehicle size and performance remain constant at present-day levels, these electric propulsion systems can reduce or eliminate the transport sector's reliance on petroleum.

The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under cold fast idle condition. For E10 to E85, PN increases modestly when the ECT is lowered. The distributions, however, are insensitive to the ethanol content of the fuel. The PN for E0 is substantially higher than the gasohol fuels at ECT below 20° C. The total PN values (obtained from integrating the PN distribution from 15 to 350 run) are approximately the same for all fuels (E0 to E85) when ECT is above 20° C. When ECT is decreased below 20° C, the total PN values for E10 to E85 increase modestly, and they are insensitive to the ethanol content. For E0, however, the total PN increases substantially. This sharp change in PN from E0 to E10 is confirmed by running the tests with E2.5 and E5. The midpoint of the transition occurs at approximately E5.

In 2006, Nissan began limited leasing of the X-TRAIL FCV equipped with their in-house developed Fuel Cell (FC) stack. Since then, the FC stack has been improved in cost, size, durability and cold start-up capability with the aim of promoting full-scale commercialization of FCVs. However, reduction of cost and size has remained a significant challenge because limited mass transport through the membrane electrode assembly (MEA) has made it difficult to increase the rated current density of the FC. Furthermore, it has been difficult to reduce the variety of FC stack components due to the complex stack configuration. In this study, improvements have been achieved mainly by adopting an advanced MEA to overcome these difficulties. First, the adoption of a new MEA and separators has improved mass transport through the MEA for increased rated current density. Second, an integrated molded frame (IMF) has been adopted as the MEA support.

A highly efficient two-motor plug-in hybrid system is developed to satisfy the global demands of CO2 reduction. This system switches three operation modes, what is called “EV Drive”, “Hybrid Drive” and “Engine Drive”, to maximize fuel efficiency according to the driving condition of the vehicle. Practical plug-in EV (Electric Vehicle) capability is also realized by adding a high-power on-board charger and a high capacity Li-ion battery to the original system. The outlines of the system components including a newly developed Atkinson cycle engine, a highly efficient electric coupled CVT (Continuously Variable Transmission) with built-in motor and generator, an integrated PCU (Power Control Unit) and an exclusive battery for plug-in HEV (Hybrid Electric Vehicle) are described in this paper. In addition to the switching of three driving modes and the efficiency improvement of each device, cooperative control of the hybrid system is introduced.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. This report is designed to determine how high biodiesel blends affect oil quality through testing on 2005 regulations engines with DPFs. When blends of 10-20% rapeseed methyl ester (RME) with diesel fuel are employed with 10W-30 engine oil, the oil change interval is reduced to about a half due to a drop in oil pressure. The oil pressure drop occurs because of the reduced kinematic viscosity of engine oil, which resulting from dilution of poorly evaporated RME with engine oil and its accumulation, however, leading to increased wear of piston top rings and cylinder liners.

Recently, the use of ethanol blended fuel is growing worldwide. Therefore, there is increasing needs for addressing issues relating to ethanol blended fuel use in gasoline engine fuel supply systems. In this paper, we focused on one of such issues, which is the reduced life of a multi-layered fuel filter used at inlet side of a fuel pump when it is used with ethanol blended fuel. In this study, we clarified that ethanol blended fuel tends to disperse dust particles contained in fuel to a greater extent than gasoline, and that it has a mechanism to accelerate clogging by concentrating the clogging only on the finest layer of the multi-layered filter. Also, in the process of clarifying this principle, we confirmed that dust particles dispersed by ethanol are coagulated when passing through the filter layers.

To improve the fuel economy via high EGR, combustion stability is enhanced through the addition of hydrogen, with its high flame-speed in air-fuel mixture. So, in order to realize on-board hydrogen production we developed a fuel reformer which produces hydrogen rich gas. One of the main issues of the reformer engine is the effects of reformate gas components on combustion performance. To clarify the effect of reformate gas contents on combustion stability, chemical kinetic simulations and single-cylinder engine test, in which hydrogen, CO, methane and simulated gas were added to intake air, were executed. And it is confirmed that hydrogen additive rate is dominant on high EGR combustion. The other issue to realize the fuel reformer was the catalyst deterioration. Catalyst reforming and exposure test were carried out to understand the influence of actual exhaust gas on the catalyst performance.

Bio-ethanol is one of the candidates for automotive alternative fuels. For reduction of carbon dioxide emissions, it is important to investigate its optimum combustion procedure. This study has explored effect of ethanol fuels on HCCI-SI hybrid combustion using dual fuel injection (DFI). Steady and transient characteristics of the HCCI-SI hybrid combustion were evaluated using a single cylinder engine and a four-cylinder engine equipped with two port injectors and a direct injector. The experimental results indicated that DFI has the potential for optimizing ignition timing of HCCI combustion and for suppressing knock in SI combustion under fixed compression ratio. The HCCI-SI hybrid combustion using DFI achieved increasing efficiency compared to conventional SI combustion.

Biodiesel Fuel (BDF) Research Work Group works on identifying technological issues on the use of high biodiesel blends (over 5 mass%) in conventional diesel vehicles under the Japan Auto-Oil Program started in 2007. The Work Group conducts an analytical study on the issues to develop measures to be taken by fuel products and vehicle manufacturers, and to produce new technological findings that could contribute to the study of its introduction in Japan, including establishment of a national fuel quality standard covering high biodiesel blends. For evaluation of the impacts of high biodiesel blends on performance of diesel particulate filter system, a wide variety of biodiesel blendstocks were prepared, ranging from some kinds of fatty acid methyl esters (FAME) to another type of BDF such as hydrotreated biodiesel (HBD). Evaluation was mainly conducted on blend levels of 20% and 50%, but also conducted on 10% blends and neat FAME in some tests.

It is important in the application of bio-ethanol in homogeneous-charge compression ignition (HCCI) engines to investigate the HCCI combustion characteristics of ethanol. As the inhibitory mechanism of ethanol on HCCI combustion is a key factor, simulated chemical reactions are necessary. In this study, chemical reaction simulations in the combustion chamber of a rapid compression machine (RCM) were performed in order to investigate the inhibitory mechanism of ethanol on the HCCI combustion of heptane. The sensitivity analysis results suggested that the OH radical consumption reaction by ethanol that occurs would inhibit the cool flame reaction of heptane. Furthermore, visualization of HCCI combustion with the RCM was conducted using a quartz glass combustion chamber head and ICCD camera. As a result, the cool flame luminescence intensity of heptane was reduced by the addition of ethanol.

At present, biodiesel fuels using natural-origin materials are expanding in share, and there are many different kinds. Biodiesel fuel generates organic acid when it deteriorates, so care is needed when evaluating the influence of the fuel on automotive fuel-line materials. A model biodiesel fuel was designed taking into account deterioration of the fuel and mixing of impurities into it. Durability of automotive fuel-line rubber and plastic materials were evaluated by using the model fuel. From the evaluation results, it was found that fluoroelastomer (hereafter referred to as FKM) and polyacetal resin (hereafter referred to as POM) deteriorate depending on specific fuel properties and deterioration state. In this paper, we report evaluating results of biodiesel fuels on the automotive fuel-line rubber and plastic materials, and the importance of biodiesel fuel property management.