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A 2007 Cummins ISL 8.9L direct-injection common rail diesel engine rated at 272 kW (365 hp) was used to load the filter to 2.2 g/L and passively oxidize particulate matter (PM) within a 2007 OEM aftertreatment system consisting of a diesel oxidation catalyst (DOC) and catalyzed particulate filter (CPF). Having a better understanding of the passive NO2 oxidation kinetics of PM within the CPF allows for reducing the frequency of active regenerations (hydrocarbon injection) and the associated fuel penalties. Being able to model the passive oxidation of accumulated PM in the CPF is critical to creating accurate state estimation strategies. The MTU 1-D CPF model will be used to simulate data collected from this study to examine differences in the PM oxidation kinetics when soy methyl ester (SME) biodiesel is used as the source of fuel for the engine.

An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.

Ash, primarily derived from diesel engine lubricants, accumulates in diesel particulate filters directly affecting the filter's pressure drop sensitivity to soot accumulation, thus impacting regeneration frequency and fuel economy. After approximately 33,000 miles of equivalent on-road aging, ash comprises more than half of the material accumulated in a typical cordierite filter. Ash accumulation reduces the effective filtration area, resulting in higher local soot loads toward the front of the filter. At a typical ash cleaning interval of 150,000 miles, ash more than doubles the filter's pressure drop sensitivity to soot, in addition to raising the pressure drop level itself. In order to evaluate the effects of lubricant-derived ash on DPF pressure drop performance, a novel accelerated ash loading system was employed to generate the ash and load the DPFs under carefully-controlled exhaust conditions.

In diesel engines the optimization of engine-out emissions, combustion noise and fuel consumption requires the experimental investigation of the effects of different injection strategies as well as of a large number of engine operating variables, such as scheduling of pilot and after pulses, rail pressure, EGR rate and swirl level. Due to the high number of testing conditions involved full factorial approaches are not viable, whereas Design of Experiment techniques have demonstrated to be a valid methodology. However, the results obtained with such techniques require a subsequent critical analysis, so as to investigate the cause and effect relationships between the set of engine operating variables and the combustion process characteristics that affect pollutant formation, noise of combustion and engine efficiency.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

The effects of using neat FAME (Fatty Acid Methyl Ester) in a modern small displacement passenger car diesel engine have been evaluated in this paper. In particular the effects on engine performance at full load with standard (i.e., without any special tuning) ECU calibration were analyzed, highlighting some issues in the low end torque due to the lower exhaust gas temperatures at the turbine inlet, which caused a remarkable decrease of the available boost, with a substantial decrease of the engine torque output, far beyond the expected engine derating due to the lower LHV of the fuel. However, further tests carried out after ECU recalibration, showed that the same torque levels measured under diesel operation can be obtained with neat biodiesel too, thus highlighting the potential for maintaining the same level of performance.

The aim of this work is to analyze particle number and size distribution from a small displacement Euro 5 common rail automotive diesel engine, equipped with a close coupled aftertreatment system, featuring a DOC and a DPF integrated in a single canning. In particular the effects of different combustion processes on PM characteristics were investigated, by comparing measurements made both under normal operating condition and under DPF regeneration mode. Exhaust gas was sampled at engine outlet, at DOC outlet and at DPF outlet, in order to fully characterize PM emissions through the whole exhaust line. After a two stage dilution system, sampled gas was analyzed by means of a TSI 3080 SMPS, in the range from 6 to 240 nm. Particle number and size distribution were evaluated at part load operating conditions, representative of urban driving.

The integration of the exhaust manifold in the engine cylinder head has received considerable attention in recent years for automotive gasoline engines, due to the proven benefits in: engine weight diminution, cost saving, reduced power enrichment, quicker engine and aftertreatment warm-up, improved packaging and simplification of the turbocharger installation. This design practice is still largely unknown in diesel engines because of the greater difficulties, caused by the more complex cylinder head layout, and the expected lower benefits, due to the absence of high-load enrichment. However, the need for improved engine thermomanagement and a quicker catalytic converter warm-up in efficient Euro 6 diesel engines is posing new challenges that an integrated exhaust manifold architecture could effectively address. A recently developed General Motors 1.6L Euro 6 diesel engine has been modified so that the intake and exhaust manifolds are integrated in the cylinder head.

The use of Ducted Fuel Injection (DFI) for attenuating soot formation throughout mixing-controlled diesel combustion has been demonstrated impressively effective both experimentally and numerically. However, the last research studies have highlighted the need for tailored engine calibration and duct geometry optimization for the full exploitation of the technology potential. Nevertheless, the research gap on the response of DFI combustion to the main engine operating parameters has still to be fully covered. Previous research analysis has been focused on numerical soot-targeted duct geometry optimization in constant-volume vessel conditions. Starting from the optimized duct design, the herein study aims to analyze the influence of several engine operating parameters (i.e. rail pressure, air density, oxygen concentration) on DFI combustion, having free spray results as a reference.

The potential of internal EGR (iEGR) and external EGR (eEGR) in reducing the engine-out NOx emissions in a heavy-duty diesel engine has been investigated by means of a refined 1D fluid-dynamic engine model developed in the GT-Power environment. The engine is equipped with Variable Valve Actuation (VVA) and Variable Geometry Turbocharger (VGT) systems. The activity was carried out in the frame of the CORE Collaborative Project of the European Community, VII FP. The engine model integrates an innovative 0D predictive combustion algorithm for the simulation of the HRR (heat release rate) based on the accumulated fuel mass approach and a multi-zone thermodynamic model for the simulation of the in-cylinder temperatures. NOx emissions are calculated by means of the Zeldovich thermal and prompt mechanisms.

A real-time mean-value engine model for the simulation of the HRR (heat release rate), in-cylinder pressure, brake torque and pollutant emissions, including NOx and soot, has been developed, calibrated and assessed at both steady-state and transient conditions for a Euro 6 1.6L GM diesel engine. The chemical energy release has been simulated using an improved version of a previously developed model that is based on the accumulated fuel mass approach. The in-cylinder pressure has been evaluated on the basis of the inversion of a single-zone model, using the net energy release as input. The latter quantity was derived starting from the simulated chemical energy release, and evaluating the heat transfer of the charge with the walls. NOx and soot emissions were simulated on the basis of semi-empirical correlations that take into account the in-cylinder thermodynamic properties, the chemical energy release and the main engine parameters.

This work examines the effect of valve timing during cold crank-start and cold fast-idle (1200 rpm, 2 bar NIMEP) on the emissions of hydrocarbons (HC) and particulate mass and number (PM/PN). Four different cam-phaser configurations are studied in detail: 1. Baseline stock valve timing. 2. Late intake opening/closing. 3. Early exhaust opening/closing. 4. Late intake phasing combined with early exhaust phasing. Delaying the intake valve opening improves the mixture formation process and results in more than 25% reduction of the HC and of the PM/PN emissions during cold crank-start. Early exhaust valve phasing results in a deterioration of the HC and PM/PN emissions performance during cold crank-start. Nevertheless, early exhaust valve phasing slightly improves the HC emissions and substantially reduces the particulate emissions at cold fast-idle.

The increasing use of gasoline direct injection (GDI) engines coupled with the implementation of new particulate matter (PM) and particle number (PN) emissions regulations requires new emissions control strategies. Gasoline particulate filters (GPFs) present one approach to reduce particle emissions. Although primarily composed of combustible material which may be removed through oxidation, particle also contains incombustible components or ash. Over the service life of the filter the accumulation of ash causes an increase in exhaust backpressure, and limits the useful life of the GPF. This study utilized an accelerated aging system to generate elevated ash levels by injecting lubricant oil with the gasoline fuel into a burner system. GPFs were aged to a series of levels representing filter life up to 150,000 miles (240,000 km). The impact of ash on the filter pressure drop and on its sensitivity to soot accumulation was investigated at specific ash levels.

The present paper illustrates an investigation about the potentialities of injection rate shaping coupled with an after injection. A pilot shot can either be absent or present before the rate-shaped boot injection. The experimental tests have been performed on a partial PCCI Euro 5 diesel engine endowed with direct-acting piezoelectric injectors. Starting from optimized triple pilot-main-after injection strategies, boot injection was implemented by maintaining the direct-acting piezo injector needle open at part lift. The results of two steady state working conditions have been presented in terms of engine-out emissions, combustion noise and brake specific fuel consumption. In addition, in-cylinder analyses of the pressure, heat-release rate, temperature and emissions have been evaluated. Considering the in-cylinder pressure traces and the heat release rate curves, the injection rate shaping proved to influence combustion in the absence of a pilot injection to a great extent.

A model-based approach to control BMEP (Brake Mean Effective Pressure) and NOx emissions has been developed and assessed on a FPT F1C 3.0L Euro VI diesel engine for heavy-duty applications. The controller is based on a zero-dimensional real-time combustion model, which is capable of simulating the HRR (heat release rate), in-cylinder pressure, BMEP and NOx engine-out levels. The real-time combustion model has been realized by integrating and improving previously developed simulation tools. A new discretization scheme has been developed for the model equations, in order to reduce the accuracy loss when the computational step is increased. This has allowed the required computational time to be reduced to a great extent.

The gasoline direct injection (GDI) engine particulate emission sources are assessed under cold start conditions: the fast idle and speed/load combinations representative of the 1st acceleration in the US FTP. The focus is on the accumulation mode particle number (PN) emission. The sources are non-fuel, combustion of the premixed charge, and liquid fuel film. The non-fuel emissions are measured by operating the engine with premixed methane/air or hydrogen/air. Then the PN level is substantially lower than what is obtained with normal GDI operation; thus non-fuel contribution to PN is small. When operating with stoichiometric premixed gasoline/air, the PN level is comparable to the non-fuel level; thus premixed-stoichiometric mixture combustion does not significantly generate particulates. For fuel rich premixed gasoline/air, PN increases dramatically when lambda is less than 0.7 to 0.8.

To meet future particle mass and particle number standards, gasoline vehicles may require particle control, either by way of an exhaust gas filter and/or engine modifications. Soot levels for gasoline engines are much lower than diesel engines; however, non-combustible material (ash) will be collected that can potentially cause increased backpressure, reduced power, and lower fuel economy. The purpose of this work was to examine the ash loading of gasoline particle filters (GPFs) during rapid aging cycles and at real time low mileages, and compare the filter performances to both fresh and very high mileage filters. Current rapid aging cycles for gasoline exhaust systems are designed to degrade the three-way catalyst washcoat both hydrothermally and chemically to represent full useful life catalysts. The ash generated during rapid aging was low in quantity although similar in quality to real time ash. Filters were also examined after a low mileage break-in of approximately 3000 km.

In this study, a new EGR control technique, based on the estimate of the oxygen concentration in the intake manifold, was firstly investigated through numerical simulation and then experimentally tested, both under steady state and transient conditions. The robustness of the new control technique was also tested and compared with that of the conventional EGR control technique by means of both numerical simulation and experimental tests. Substantial reductions of the NOx emissions under transient operating conditions were achieved, and useful knowledge for controlling the EGR flow rate more accurately was obtained.

La1-xAxNi1-yByO3 nanostructured perovskite-type oxides catalysts (where A = Na, K, Rb and B = Cu; x = 0, 0.2 and y = 0, 0.05, 0.1), also supporting 2% in weight of gold, were prepared via the so-called “Solution Combustion Synthesis (SCS)” method, and characterized by means of XRD, BET, FESEM-EDS and TEM analyses. The performance of these catalysts towards the simultaneous oxidation of soot and CO was evaluated. The 2 wt.% Au-La0.8K0.2Ni0.9Cu0.1O3 showed the best performance with a peak carbon combustion temperature of 367 °C and the half conversion of CO reached at 141 °C. The same nanostructured catalyst, deposited by in situ SCS directly over a SiC filter and tested on real diesel exhaust gases, fully confirmed the encouraging results obtained on the powder catalyst.