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Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

Gaseous and particle emissions from a gasoline direct injection (GDI) and a port fuel injection (PFI) vehicle were measured at various ambient temperatures (22°C, -7°C, -18°C). These vehicles were driven over the U.S. Federal Test Procedure 75 (FTP-75) and US06 Supplemental Federal Test Procedure (US06) on Tier 2 certification gasoline (E0) and 10% by volume ethanol (E10). Emissions were analyzed to determine the impact of ambient temperature on exhaust emissions over different driving conditions. Measurements on the GDI vehicle with a gasoline particulate filter (GPF) installed were also made to evaluate the GPF particle filtration efficiency at cold ambient temperatures. The GDI vehicle was found to have better fuel economy than the PFI vehicle at all test conditions. Reduction in ambient temperature increased the fuel consumption for both vehicles, with a much larger impact on the cold-start FTP-75 drive cycle observed than for the hot-start US06 drive cycle.

This study reports gaseous and particle (ultrafine and black carbon (BC)) emissions from a turbofan engine core on standard Jet A-1 and three alternative fuels, including 100% hydrothermolysis synthetic kerosene with aromatics (CH-SKA), 50% Hydro-processed Esters and Fatty Acid paraffinic kerosene (HEFA-SPK), and 100% Fischer Tropsch (FT-SPK). Gaseous emissions from this engine for various fuels were similar but significant differences in particle emissions were observed. During the idle condition, it was observed that the non-refractory mass fraction in the emitted particles were higher than during higher engine load condition. This observation is consistent for all test fuels. The 100% CH-SKA fuel was found to have noticeable reductions in BC emissions when compared to Jet A-1 by 28-38% by different BC instruments (and 7% in refractory particle number (PN) emissions) at take-off condition.

The exhaust emissions from small engines in general and marine engines in particular have come under scrutiny over the past few years as new exhaust emission regulations have been proposed and put into force. The standard method for exhaust emission sampling of outboard marine engines is to analyze raw exhaust in the exhaust manifold of the engine. In this study a total dilution sampling system for the gaseous emissions, similar to what is used for light and heavy duty vehicles and engines, and a separate water sampling method were used to evaluate the exhaust emissions from stock two and four stroke outboard marine engines.

This paper presents the emission characteristics of a HCCI engine operation using n-heptane. The experiments were conducted in a single cylinder Co-operative Fuel Research (CFR) engine equipped with an air-assist port fuel injector. The effects of intake temperature, air/fuel ratio, compression ratio, turbo-charging, and EGR rate on exhaust emissions were explored. The analysis of the exhaust gases included oxides of nitrogen (NOx), nitrous oxide (N2O), carbon monoxide (CO), total hydrocarbon (THC), and soot. The hydrocarbon species present in exhaust gases and their concentrations at several operating conditions were also characterized. The strategies to obtain low HC, CO and NOx emissions are presented and discussed. The approaches to effectively retard HCCI combustion phase without deteriorating combustion efficiency are examined. It was found that HCCI combustion produces extremely low soot and NOx emissions.

Selective catalytic reduction (SCR) technology is being considered as the potential strategy for significant reduction of NOx emissions from diesel engines. Many challenges exist in the development of an On-Road SCR retrofit system in terms of system integration and optimization of control strategy in order to achieve highest NOx reduction given the diversity of duty cycles. The main considered challenges are: - The development of a generic control strategy that would work for a broad range of engines, - Development of a reliable and durable injection system that would be able to withstand the harsh environments on a heavy-duty vehicle, - Packaging of the system to be able to fit on a number of vehicles with different configurations, - Controlling ammonia slip and assurance of reducing agent (Urea) availability and quality. In this study a prototype SCR system was evaluated over engine and chassis dynamometer test cycles.

For this work, a methodology of modeling and predicting fuel consumption in a hybrid vehicle as a function of the engine operating temperature has been developed for cold ambient operation (-7°C, 266°K). This methodology requires two steps: 1) development of a temperature dependent engine brake specific fuel consumption (BSFC) map, and, 2) a data-fitting technique for predicting engine temperature to be used as an input to the temperature dependent BSFC maps. For the first step, response surface methodology (RSM) techniques were applied to generate brake specific fuel consumption (BSFC) maps as a function of the engine thermal state. For the second step, data fitting techniques were also used to fit a simplified lumped capacitance heat transfer model using several experimental datasets. Utilizing these techniques, an analysis of fuel consumption as a function of thermal state across a broad range of engine operating conditions is presented.

Particulate emission from diesel engines is one of the most important pollutants in urban areas. As a result, particulate emission control from urban bus diesel engines using particle filter technology is being evaluated at several locations in the US. A project entitled “Clean Diesel Demonstration Program” has been initiated by NY City Transit under the supervision of NY State DEC and with active participation from several industrial partners. Under this program, several NY City transit buses with DDC Series 50 engines have been equipped with continuously regenerating diesel particulate filter system and are operating with ultra low sulfur diesel (< 30 ppm S) in transit service in Manhattan since February 2000. These buses are being evaluated over a 8-9 month period for operations, maintainability and durability of the particulate filter.

This paper will present emissions durability data from an underground mining vehicle equipped with diesel particulate filter technology, which was followed over 4000 hrs on a Detroit Diesel Series 60 engine. The twin particulate filter system is catalyzed using a base metal formulation on cordierite wall flow monoliths. After the durability accumulation, the recovered filters were individually emissions tested on a Detroit Diesel Series 50 engine over the ISO 8178 test cycle. Performance, maintenance and emissions issues pertaining to base metal catalysts will be discussed.

In urban areas, particulate emission from diesel engines is one of the pollutants of most concern. As a result, particulate emission control from urban bus diesel engines using particle filter technology is being evaluated at several locations in the US. A project entitled, “Clean Diesel Vehicle Air Quality Project” has been initiated by NY City Transit under the supervision of NYSDEC and with active participation from several industry partners. Under this program, 25 NY City transit buses with DDC Series 50 engines have been equipped with continuously regenerating diesel particulate filter systems and have been operating with ultra low sulfur diesel (< 30 ppm S) in transit service in Manhattan since February 2000. These buses were evaluated over a 9 month period for operations, maintainability and durability of the particulate filter.

KOMATSU achieved the first practical application in the world of the nodular cast iron piston to high speed four stroke diesel engines with a bore of 125mm, and since then this application has expanded to larger engines. In order to improve the casting quality and productivity we also developed the permanent mold casting process for the nodular cast iron pistons. In this paper, aims in the development of the nodular cast iron pistons and its design features and casting technology are presented.

The New York City Metropolitan Transit Authority (MTA) has initiated a program to utilize various diesel emission control, alternative fuel, and hybrid electric drive technologies as part of its ongoing effort to provide environmentally friendly bus service. The New York State Department of Environmental Conservation (DEC) has joined with the MTA and Environment Canada in evaluating this program, and has established a protocol for measuring both regulated and unregulated emissions, as well as other operational parameters. This paper compares and contrasts the emissions of buses powered by Detroit Diesel Series 50 diesel engines and Series 50G Compressed Natural Gas (CNG) engines. All buses have been tested for regulated emissions at the Emissions Research and Measurement Division of Environment Canada, in Ottawa, Ontario. Unregulated emissions measurements, including particle size distributions and chemical analysis, have been supported by DEC staff.

The recent tightening of emission standards for new heavy duty engines has lead to the development and implementation of alternative fuel engines, particularly for urban transit bus applications. Alternative fuels are intended to offer a potential emissions benefit with regards to the regulated emissions, and especially the particulate matter, which has received the greatest degree of regulatory action. However, the entire composition of the engine emissions should be considered when evaluating the environmental benefits of these new fuels, and also the continued performance of these engines in actual fleet service. In this study the exhaust emissions from methanol, ethanol, and diesel - powered buses were determined during transient operation of the vehicles on a heavy duty chassis dynamometer. The tests of the alcohol fuelled buses, and a control diesel bus were conducted as the buses accumulated mileage in revenue generating service.

As more stringent vehicle emission standards are introduced worldwide, there is an increased need to provide a thorough assessment of the environmental impact of alternative fuels. With the advent of CNG as a viable transportation fuel, the development of advanced computer controlled fuel delivery systems is imperative in order to ensure acceptable emission performance. At present, the majority of light and medium duty engines operating on natural gas are primarily gasoline automotive engines which have been retrofitted to allow for the use of CNG. The Mobile Sources Emissions Division of Environment Canada and the Canadian Gas Association have conducted a joint test program in order to develop a database of exhaust emissions from vehicles typically converted for operation on either gasoline or natural gas at various operating temperatures.

This updated paper presents chassis dynamometer emissions testing of various heavy duty vehicles with and without retrofitted diesel oxidation catalyst technology. Analysis is provided into both the vehicle emissions baselines and emissions with retrofitted catalyst technology over the New York Composite and Central Business District cycles. The vehicles studied include four urban buses, two school buses and four heavy duty trucks. Some of these vehicles in this study have been followed for up to two years. The paper will discuss in-use heavy duty vehicle emissions issues and the use of diesel oxidation catalyst technologies.

The focus of this study was the characterization and comparison of power-specific exhaust emission rates from a closed-loop small spark-ignited engine fuelled with ethanol and isobutanol gasoline blends. A 4-cycle Kohler ECH-630 engine certified to the Phase 3 emissions standards was operated over the G2 test cycle, a six-mode steady-state test cycle, in its original configuration. This engine was equipped with electronic ignition, electronic fuel injection and an oxygen sensor. Certification gasoline fuel was splash-blended by percent volume with ethanol and isobutanol to result in the test blend levels of E10, E15, iB16 and iB8-E10. Reductions in emission rates of carbon monoxide (up to 12.0% with the ethanol blends and up to 11.4% with the isobutanol blends) were achieved along with a reduction in total hydrocarbons (up to 10.9% with the ethanol blends and up to 8.2% with the isobutanol blends). Nitrogen oxide emissions were decreased by up to 9.8% with the ethanol blends.

This study reported black carbon (BC) mass and solid particle number emissions from a gasoline direct injection (GDI) vehicle and a port fuel injection (PFI) vehicle on splash blended E10 and iB16 fuels over the FTP-75 and US06 drive cycles at standard and cold ambient temperatures. For the FTP-75 drive cycle, the GDI vehicle had lower solid particle number and BC mass emissions from E10 (5.1×1012 particles/mile; 4.2 mg/mile) and iB16 (5.2×1012 particles/mile; 3.9 mg/mile) compared to E0 (7.2×1012 particles/mile; 7.0 mg/mi). Most of the reductions were attributed to the statistically significant reductions during the phases 1 and 2 of the FTP-75 drive cycle. iB16 was also observed to have statistically significant reduction on BC emissions when compared to E0 at cold ambient temperature but E10 did not show such BC reduction. For the PFI vehicle, most of the solid particle number and BC mass emissions were emitted primarily during phase 1 of the FTP-75 drive cycle.