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Pre-chamber combustion (PCC) is a promising engine combustion concept capable of extending the lean limit at part load. The engine experiments in the literature showed that the PCC could achieve higher engine thermal efficiency and much lower NOx emission than the spark-ignition engine. Improved understanding of the detailed flow and combustion physics of PCC is important for optimizing the PCC combustion. In this study, we investigated the gas exchange and flame jet from a narrow throat pre-chamber (PC) by only fueling the PC with methane in an optical engine. Simultaneous negative acetone planar laser-induced fluorescence (PLIF) imaging and OH* chemiluminescence imaging were applied to visualize the PC jet and flame jet from the PC, respectively. Results indicate a delay of the PC gas exchange relative to the built-up of the pressure difference (△ P) between PC and the main chamber (MC). This should be due to the gas inertia inside the PC and the resistance of the PC nozzle.

Pre-chamber combustion (PCC) allows an extension on the lean limit of an internal combustion engine (ICE). This combustion mode provides lower NOx emissions and shorter combustion durations that lead to a higher indicated efficiency. In the present work, a narrow throat pre-chamber was tested, which has a unique nozzle area distribution in two rows of six nozzle holes each. Tests were carried out in a modified heavy-duty engine for optical visualization. Methane was used as fuel for both the pre-chamber and the main chamber. Seven operating points were tested, including passive pre-chamber mode as a limit condition, to study the effect of pre- and main-chamber fuel addition on the pre-chamber jets and the main chamber combustion via chemiluminescence imaging. A typical cycle of one of the tested conditions is explained through the captured images. Observations of the typical cycle reveal a predominant presence of only six jets (from the lower row), with well-defined jet structures.

To provide insights into the fundamental characteristics of pre-chamber combustion engines, the ignition of lean premixed CH4/air due to hot gas jets initiated by a passive narrow throated pre-chamber in a heavy-duty engine was studied computationally. A twelve-hole pre-chamber geometry was investigated using CONVERGETM software. The numerical model was validated against the experimental results. To elucidate the main-chamber ignition mechanism, the spark plug location and spark timing were varied, resulting in different pressure gradient during turbulent jet formation. Different ignition mechanisms were observed for turbulent jet ignition of lean premixed CH4/air, based on the geometry effect. Ignition behavior was classified into the flame and jet ignition depending on the significant presence of hot active radicals. The jet ignition, mainly due to hot product gases was found to be advanced by the addition of a small concentration of radicals.

Gasoline compression ignition (GCI) technology shows the potential to obtain high thermal efficiencies while maintaining low soot and NOx emissions in light-duty engine applications. Recent experimental studies and numerical simulations have indicated that high reactivity gasoline-like fuels can further enable the benefits of GCI combustion. However, there is limited empirical data in the literature studying the gasoline compression ignition process at relevant in-cylinder conditions, which are required for further optimizing combustion system designs. This study investigates the temporal and spatial evolution of the compression ignition process of various high reactivity gasoline fuels with research octane numbers (RON) of 71, 74 and 82, as well as a conventional RON 97 E10 gasoline fuel. A ten-hole prototype gasoline injector specifically designed for GCI applications capable of injection pressures up to 450 bar was used.

Blending gasoline with oxygenates like ethanol, MTBE or ETBE has a proven potential to increase the thermodynamic efficiency by enhancing knock resistance. The present research focuses on assessing the capability of a 2- and tert-butanol mixture as a possible alternative to state-of-the-art oxygenates. The butanol mixture was blended into a non-oxygenated reference gasoline with a research octane number (RON) of 97. The butanol blending ratios were 15% and 30% by mass. Both the thermodynamic potential and the impact on emissions were investigated. Tests are performed on a highly boosted single-cylinder gasoline engine with high load capability and a direct injecting fuel system using a solenoid-actuated multi-hole injector. The engine is equipped with both intake and exhaust cam phasers. The engine has been chosen for the fuel investigation, as it represents the SI technology with a strongly increasing market share.

Owing to environmental and health concerns, tetraethyl lead was gradually phased out from the early 1970's to mid-1990's in most developed countries. Advances in refining, leading to more aromatics (via reformate) and iso-paraffins such as iso-octane, along with the introduction of (bio) oxygenates such as MTBE, ETBE and ethanol, facilitated the removal of lead without sacrificing RON and MON. In recent years, however, legislation has been moving in the direction of curbing aromatic and olefin content in gasoline, owing to similar concerns as was the case for lead. Meanwhile, concerns over global warming and energy security have motivated research into renewable fuels. Amongst which are those derived from biomass. The feedstock of interest in this study is lignin, which, together with hemicellulose and cellulose, is amongst the most abundant organic compounds on the planet.

As SI engines strive for higher efficiency they are more likely to encounter knock and fuel anti-knock quality, which is currently measured by RON and MON, becomes more important. However, the RON and MON scales are based on primary reference fuels (PRF) - mixtures of iso-octane and n-heptane - whose autoignition chemistry is significantly different from that of practical fuels. Hence RON or MON alone can truly characterize a gasoline for its knock behavior only at their respective test conditions. The same gasoline will match different PRF fuels at different operating conditions. The true anti-knock quality of a fuel is given by the octane index, OI = RON −KS where S = RON − MON, is the sensitivity. K depends on the pressure and temperature evolution in the unburned gas during the engine cycle and hence is different at different operating conditions and is negative in modern engines.

An experimental study of a glow plug engine combustion process has been performed by applying chemiluminescence imaging. The major intent was to understand what kind of combustion is present in a glow plug engine and how the combustion process behaves in a small volume and at high engine speed. To achieve this, images of natural emitted light were taken and filters were applied for isolating the formaldehyde and hydroxyl species. Images were taken in a model airplane engine, 4.11 cm3, modified for optical access. The pictures were acquired using a high speed camera capable of taking one photo every second or fourth crank angle degree, and consequently visualizing the progress of the combustion process. The images were taken with the same operating condition at two different engine speeds: 9600 and 13400 rpm. A mixture of 65% methanol, 20% nitromethane and 15% lubricant was used as fuel.

It has been known from multi-zone simulations that HCCI combustion can be significantly affected by temperature stratification of the in-cylinder gas. With the same combustion timing (i.e. crank angles at 50% heat release, denoted as CA50), large temperature stratification tends to prolong the combustion duration and lower down the in-cylinder pressure-rise-rate. With low pressure-rise-rate HCCI engines can be operated at high load, therefore it is of practical importance to look into more details about how temperature stratification affects the auto-ignition process. It has been realized that multi-zone simulations can not account for the effects of spatial structures of the stratified temperature field, i.e. how the size of the hot and cold spots in the temperature field could affect the auto-ignition process. This question is investigated in the present work by large eddy simulation (LES) method which is capable of resolving the in-cylinder turbulence field in space and time.

In-cylinder flow measurements, conventional swirl measurements and CFD-simulations have been performed and then compared. The engine studied is a single cylinder version of a Scania D12 that represents a modern heavy-duty truck size engine. Bowditch type optical access and flat piston is used. The cylinder head was also measured in a steady-flow impulse torque swirl meter. From the two-dimensional flow-field, which was measured in the interval from -200° ATDC to 65° ATDC at two different positions from the cylinder head, calculations of the vorticity, turbulence and swirl were made. A maximum in swirl occurs at about 50° before TDC while the maximum vorticity and turbulence occurs somewhat later during the compression stroke. The swirl centre is also seen moving around and it does not coincide with the geometrical centre of the cylinder. The simulated flow-field shows similar behaviour as that seen in the measurements.

Although there seems to be a consensus regarding the low emission potential of DME, there are still different opinions about why the low NOx emissions can be obtained without negative effects on thermal efficiency. Possible explanations are: The physical properties of DME affecting the spray and the mixture formation Different shape and duration of the heat release in combination with reduced heat losses In this paper an attempt is made to increase the knowledge of DME in relation to diesel fuel with respect to heat release and NOx formation. The emphasis has been to create injection conditions as similar as possible for both fuels. For that purpose the same injection system (CR), injection pressure (270 bar), injection timing and duration have been used for the two fuels. The only differences were the diameters of the nozzle holes, which were chosen to give the same fuel energy supply, and the physical properties of the fuels.

Laser-Rayleigh imaging has been employed to measure the relative fuel concentration in the gaseous jet region of DME sprays. The measurements were performed in an optically accessible diesel truck engine equipped with a common rail injection system. A one-hole nozzle was used to guarantee that the recorded pressure history was associated with the heat release in the imaged spray. To compensate for the low compression ratio in the modified engine the inlet air was preheated. Spray development was studied for two levels of preheating, from the start of injection to the point where all fuel was consumed. The results indicate that there is a strong correlation between the amount of unburned fuel present in the cylinder and the rate of heat release at a given time. The combustion can not be described as purely premixed or purely mixing-controlled at any time, but always has an element of both. After all fuel appears to have vanished there is still an extended period of heat release.

The blending behavior of ethanol in five different hydrocarbon base fuels with octane numbers of approximately 70 and 84 was examined under Spark-Ignited (SI) and Homogeneous Charge Compression Ignited (HCCI) operating conditions. The Blending octane number (BON) was used to characterize the blending behavior on both a volume and molar basis. Previous studies have shown that the blending behavior of ethanol generally follows several well-established rules. In particular, non-linear blending effects are generally observed on a volume basis (i.e. BON > RON or MON of pure ethanol; 108 and 89, respectively), while linear blending effects are generally observed on a molar basis (i.e. BON = RON or MON of pure ethanol). This work firstly demonstrates that the non-linear volumetric blending effects traditionally observed under SI operating conditions are also observed under HCCI operating conditions.

This paper is the first of a two part study which investigates the use of advanced combustion modes as a means of improving the efficiency and environmental impact of conventional light-duty vehicles. This first study focuses on the application of so-called Octane-on-Demand combustion, whereby the fuel anti-knock quality is customized to match the real-time requirements of an otherwise conventional spark-ignition engine. Methanol is utilized as the high octane fuel, while three alternative petroleum-derived fuels with Research octane numbers (RONs) ranging from 61 to 90 are examined as candidates for the lower octane fuel. Experimental engine calibration maps are first developed to quantify the minimum amount of methanol that must be added to each lower octane fuel in order to reproduce the baseline engine performance attained on a market gasoline (RON 95). The properties of the lower octane fuel are shown to affect the engine performance significantly.

This paper presents a large eddy simulation study of the liquid spray mixing with hot ambient gas in a constant volume vessel under engine-like conditions with the injection pressure of 1500 bar, ambient density 22.8 kg/m₃, ambient temperature of 900 K and an injector nozzle of 0.09 mm. The simulation results are compared with the experiments carried out by Pickett et al., under similar conditions. Under modern direct injection diesel engine conditions, it has been argued that the liquid core region is small and the droplets after atomization are fine so that the process of spray evaporation and mixing with the air is controlled by the heat and mass transfer between the ambient hot gas and central fuel flow. To examine this hypothesis a simple spray breakup model is tested in the present LES simulation. The simulations are performed using an open source compressible flow solver, in OpenFOAM.

Gasoline-ethanol-methanol (GEM) blends, with constant stoichiometric air-to-fuel ratio (iso-stoichiometric blending rule) and equivalent to binary gasoline-ethanol blends (E2, E5, E10 and E15 in % vol.), were defined to investigate the effect of methanol and combined mixtures of ethanol and methanol when blended with three FACE (Fuels for Advanced Combustion Engines) Gasolines, I, J and A corresponding to RON 70.2, 73.8 and 83.9, respectively, and their corresponding Primary Reference Fuels (PRFs). A Cooperative Fuel Research (CFR) engine was used under Spark Ignition and Homogeneous Charge Compression Ignited modes. An ignition quality tester was utilized in the Compression Ignition mode. One of the promising properties of GEM blends, which are derived using the iso-stoichiometric blending rule, is that they maintain a constant octane number, which has led to the introduction of methanol as a drop-in fuel to supplement bio-derived ethanol.

In earlier research, a new class of bio-fuels, so-called cyclic oxygenates, was reported to have a favorable impact on the soot-NOx trade-off experience in diesel engines. In this paper, the soot-NOx trade-off is compared for two types of cyclic oxygenates. 2-phenyl ethanol has an aromatic and cyclohexane ethanol a saturated or aliphatic ring structure. Accordingly, the research is focused on the effect of aromaticity on the aforementioned emissions trade-off. This research is relevant because, starting from lignin, a biomass component with a complex poly-aromatic structure, the production of 2-phenyl ethanol requires less hydrogen and can therefore be produced at lower cost than is the case for cyclohexane ethanol.

Styrene, or ethylbenzene, is mainly used as a monomer for the production of polymers, most notably Styrofoam. In the synthetis of styrene, the feedstock of benzene and ethylene is converted into aromatic oxygenates such as benzaldehyde, 2-phenyl ethanol and acetophenone. Benzaldehyde and phenyl ethanol are low value side streams, while acetophenone is a high value intermediate product. The side streams are now principally rejected from the process and burnt for process heat. Previous in-house research has shown that such aromatic oxygenates are suitable as diesel fuel additives and can in some cases improve the soot-NOx trade-off. In this study acetophenone, benzaldehyde and 2-phenyl ethanol are each added to commercial EN590 diesel at a ratio of 1:9, with the goal to ascertain whether or not the lower value benzaldehyde and 2-phenyl ethanol can perform on par with the higher value acetophenone. These compounds are now used in pure form.

Typical automotive emission testing systems usually employ Flame Ionization Detection (FID) analyzers to measure unburned fuel species in the exhaust, but the technique is not suitable for engines operating on alcohol fuels. The FID method is not sensitive to measuring unburned alcohol fuels due to the presence of oxygen bonds in the fuel molecule. Other techniques, such as Fourier Transform Infrared (FTIR), can provide accurate unburned fuel measurements with alcohol fuel. However, these techniques are expensive and are less accessible compared to FID analyzers. In this study, the unburned fuel emissions from the engine exhaust were measured simultaneously with FID and FTIR analyzers, with the engine operating on pure alcohols, which are methanol, ethanol, and n-butanol. While most previous work focuses on stoichiometric air-fuel mixtures, a wide range of lean operating conditions between global-λ 1.6 to 2.8 will be tested in this study.

Turbulent premixed natural gas - air flame velocities have been measured in a stationary axi-symmetric burner using LDA. The flame was stabilized by letting the flow retard toward a stagnation plate downstream of the burner exit. Turbulence was generated by letting the flow pass through a plate with drilled holes. Three different hole diameters were used, 3, 6 and 10 mm, in order to achieve different turbulent length scales. Turbulent integral length scales were measured using two-point LDA and the stretching in terms of the Karlovitz number could be estimated from these measurements. The results support previous studies indicating that stretching reduces the flame speed.