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Diesel fuels usually comprise a wide range of compounds having different molecular structures which can affect both the fuel's physical properties and combustion characteristics. In future, as synthetic fuels from fossil and sustainable sources become increasingly available, it could be possible to control the fuel's molecular structure to achieve clean and efficient combustion. This paper presents experimental results of combustion and emissions studies undertaken on a single cylinder diesel engine supplied with 18 different fuels each comprising a single, acyclic, non-oxygenated hydrocarbon molecule. These molecules were chosen to highlight the effect of straight carbon chain length, degree of saturation and the addition of methyl groups as branches to a straight carbon chain.

The effects of Exhaust Gas Recirculation (EGR) on diesel engine exhaust emissions were isolated and studied in earlier investigations (1,2,3,4,5). This paper analyses the heat release patterns during the combustion process and co-relates the results with the exhaust emissions. The EGR effects considered include the dilution of the inlet charge with CO2 or water vapour, the increase in the inlet charge temperature, and the thermal throttling arising from the use of hot EGR. The use of diluents (CO2 and H2O), which are the principal constituents of EGR, caused an increase in ignition delay and a shift in the location of start of combustion. As a consequence of this shift, the whole combustion process was also shifted further towards the expansion stroke. This resulted in the products of combustion spending shorter periods at high temperatures which lowered the NOx formation rate.

This paper is a complementary to previous investigations by the authors (1,2,3,4) on the different effects of EGR on combustion and emissions in DI diesel engine. In addition to the several effects that cold EGR has on combustion and emissions the application of hot EGR results in increasing the inlet charge temperature, thereby, for naturally aspirated engines, lowering the inlet charge mass due to thermal throttling. An associated consequence of thermal throttling is the reduction in the amount of oxygen in the inlet charge. Uncooled EGR, therefore, affects combustion and emissions in two ways: through the reduction in the inlet charge mass and through the increase in inlet charge temperature. The effect on combustion and emissions of increasing the inlet charge temperature (without reducing the inlet charge mass) has been dealt with in ref. (1).