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Fatty Acid Methyl Ester (FAME) products derived from vegetable oils and animal fats are now widely used in European diesel fuels and their use will increase in order to meet mandated targets for the use of renewable products in road fuels. As more FAME enters the diesel pool, understanding the impact of higher FAME levels on the performance and emissions of modern light-duty diesel vehicles is increasingly important. Of special significance to Well-to-Wheels (WTW) calculations is the potential impact that higher FAME levels may have on the vehicle's volumetric fuel consumption. The primary objective of this study was to generate statistically robust fuel consumption data on three light-duty diesel vehicles complying with Euro 4 emissions regulations. These vehicles were evaluated on a chassis dynamometer using four fuels: a hydrocarbon-only diesel fuel and three FAME/diesel fuel blends containing up to 50% v/v FAME. One FAME type, a Rapeseed Methyl Ester (RME), was used throughout.

Biodiesel is a renewable fuel which can be used as a direct replacement for fossil Diesel fuel as a calorific source in Diesel Engines. It consists of fatty acid mono-alkyl esters, which are produced by the trans-esterification reaction of plant oils with monohydric alcohols. The Plant oils and alcohols can both be derived from biomass, giving this fuel the potential for a sustainable carbon dioxide neutral life-cycle, which is an important quality with regard to avoiding the net emission of anthropogenic greenhouse gases. Depending on its fatty ester composition, Biodiesel can have varying physical and chemical properties which influence its combustion behaviour in a Diesel engine. It has been observed by many researchers that Biodiesel can sometimes lead to an increase in emissions of oxides of nitrogen (NOx) compared to fossil Diesel fuel, while emitting a lower amount of particulate mass.

Diesel fuels usually comprise a wide range of compounds having different molecular structures which can affect both the fuel's physical properties and combustion characteristics. In future, as synthetic fuels from fossil and sustainable sources become increasingly available, it could be possible to control the fuel's molecular structure to achieve clean and efficient combustion. This paper presents experimental results of combustion and emissions studies undertaken on a single cylinder diesel engine supplied with 18 different fuels each comprising a single, acyclic, non-oxygenated hydrocarbon molecule. These molecules were chosen to highlight the effect of straight carbon chain length, degree of saturation and the addition of methyl groups as branches to a straight carbon chain.

Chemiluminescence imaging has been applied to a parametric investigation of diesel autoignition. Time-resolved images of the natural light emission were made in an optically accessible DI diesel engine of the heavy-duty size class using an intensified CCD video camera. Measurements were obtained at a base operating condition, corresponding to a motored TDC temperature and density of 992 K and 16.6 kg/m3, and for TDC temperatures and densities above and below these values. Data were taken with a 42.5 cetane number blend of the diesel reference fuels for all conditions, and measurements were also made with no. 2 diesel fuel (D2) at the base condition. For each condition, temporal sequences of images were acquired from the time of first detectable chemiluminescence up through fully sooting combustion, and the images were analyzed to obtain quantitative measurements of the average emission intensity.

Non-petroleum based liquid fuels are essential for reducing oil dependence and greenhouse gas generation. Increased substitution of alcohol fuel for petroleum based fuels could be achieved by 1) use in high efficiency spark ignition engines that are employed for heavy duty as well as light duty operation and 2) use of methanol as well as ethanol. Methanol is the liquid fuel that is most efficiently produced from thermo-chemical gasification of coal, natural gas, waste or biomass. Ethanol can also be produced by this process but at lower efficiency and higher cost. Coal derived methanol is in limited initial use as a transportation fuel in China. Methanol could potentially be produced from natural gas at an economically competitive fuel costs, and with essentially the same greenhouse gas impact as gasoline. Waste derived methanol could also be an affordable low carbon fuel.

Research conducted at the Supercritical (SC) facility of MIT's Energy Laboratory provided visual confirmation of a single phase, homogeneous water/fuel mixture near the critical temperature and pressure of water. Equal volumes of water and diesel fuel were observed to be completely miscible, and high temperature polymerization of fuel molecules was not found. This is believed to be the first observation of a solution of diesel fuel and water. This mixture was subsequently burned under atmospheric spray conditions with very low NOx, smoke, CO, and HC. The results suggested that in-cylinder combustion in a compression ignition engine was warranted. Tests were conducted in a single cylinder, air-cooled, naturally aspirated, 3.5 horsepower Yanmar diesel engine. The compressibility of this new fuel composition necessitated a modified injector to provide smooth operation.

Long-haul and other heavy-duty trucks, presently almost entirely powered by diesel fuel, face challenges meeting worldwide needs for greatly reducing nitrogen oxide (NOx) emissions. Dual-fuel gasoline-alcohol engines could potentially provide a means to cost-effectively meet this need at large scale in the relatively near term. They could also provide reductions in greenhouse gas emissions. These spark ignition (SI) flexible fuel engines can provide operation over a wide fuel range from mainly gasoline use to 100% alcohol use. The alcohol can be ethanol or methanol. Use of stoichiometric operation and a three-way catalytic converter can reduce NOx by around 90% relative to emissions from diesel engines with state of the art exhaust treatment.

The effect of fuel additives based on the alkali metals sodium and lithium on the regeneration behaviour of diesel particulate filters was studied. For this purpose the diesel fuel was doped with the lithium and sodium salts of an aliphatic alcohol. The efficiency of these additives was assessed by comparing it to ferrocene, which is, at present, the best studied additive for particulate filter regeneration. The additives were tested on an engine test bench under steady state conditions, on a transient dynamometer and finally in a real driving test. As a result of the addition of the alkali metal salts, the ignition temperature of the soot trapped in the particulate filter is considerably lower than the ignition temperature without additives. The results with the alkali metal additives are similar to those of ferrocene or other additives with transition metals like manganese or copper.

Blendings of methanol and diesel fuel can only be produced in form of emulsions. The stability of those emulsions strongly depends on the concentration of surface active agents. It is shown that observed changes in mixture formation of emulsions in comparison to pure diesel fuel conditions can be explained by a theory of spontaneous evaporation. Several feasible droplet models are discussed. Emulsion droplets evaporate spontaneously if the droplet temperature exceeds the superheating limit of the disperse phase. The superheating limit is only exceeded at the outer zone of the injection jet.