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An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

The performance of an organic Rankine cycle (ORC) that recovers heat from the exhaust of a heavy-duty diesel engine was simulated. The work was an extension of a prior study that simulated the performance of an experimental ORC system developed and tested at Oak Ridge National laboratory (ORNL). The experimental data were used to set model parameters and validate the results of that simulation. For the current study the model was adapted to consider a 15 liter turbocharged engine versus the original 1.9 liter light-duty automotive turbodiesel studied by ORNL. Exhaust flow rate and temperature data for the heavy-duty engine were obtained from Southwest Research Institute (SwRI) for a range of steady-state engine speeds and loads without EGR. Because of the considerably higher exhaust gas flow rates of the heavy-duty engine, relative to the engine tested by ORNL, a different heat exchanger type was considered in order to keep exhaust pressure drop within practical bounds.

Exhaust pressures (P3) are hard parameters to measure and can be readily estimated, the cost of the sensors and the temperature in the exhaust system makes the implementation of an exhaust pressure sensor in a vehicle control system a costly endeavor. The contention with measured P3 is the accuracy required for proper engine and vehicle control can sometimes exceed the accuracy specification of market available sensors and existing models. A turbine inlet exhaust pressure observer model based on isentropic expansion and heat transfer across a turbocharger turbine was developed and investigated in this paper. The model uses 4 main components; an open loop P3 orifice flow model, a model of isentropic expansion across the turbine, a turbine and pipe heat transfer models and an integrator with the deviation in the downstream turbine outlet parameter.

The first 3 cycles in the cold crank-start process at 20°C are studied in a GDI engine. The focus is on the dependence of the HC and PM/PN emissions of each cycle on the injection strategy and combustion phasing of the current and previous cycles. The PM/PN emissions per cycle decrease by more than an order of magnitude as the crank-start progresses from the 1st to the 3rd cycle, while the HC emissions stay relatively constant. The wall heat transfer, as controlled by the combustion phasing, during the previous cycles has a more significant influence on the mixture formation process for the current cycle than the amount of residual fuel. The results show that the rise in HC emissions caused by the injection spray interacting with the intake valves and piston crown is reduced as the cranking process progresses. Combustion phasing retard significantly reduces the PM emission. The HC emissions, however, are relatively not sensitive to combustion phasing in the range of interest.

A task group within the SAE Automotive Corrosion and Protection (ACAP) Committee continues to pursue the goal of establishing a standard test method for in-laboratory cosmetic corrosion evaluations of finished aluminum auto body panels. The program is a cooperative effort with OEM, supplier, and consultant participation and is supported in part by USAMP (AMD 309) and the U.S. Department of Energy. Numerous laboratory corrosion test environments have been used to evaluate the performance of painted aluminum closure panels, but correlations between laboratory test results and in-service performance have not been established. The primary objective of this project is to identify an accelerated laboratory test method that correlates with in-service performance. In this paper the type, extent, and chemical nature of cosmetic corrosion observed in the on-vehicle exposures are compared with those from some of the commonly used laboratory tests

Internal combustion (IC) engines fueled by hydrogen are among the most efficient means of converting chemical energy to mechanical work. The exhaust has near-zero carbon-based emissions, and the engines can be operated in a manner in which pollutants are minimal. In addition, in automotive applications, hydrogen engines have the potential for efficiencies higher than fuel cells.[1] In addition, hydrogen engines are likely to have a small increase in engine costs compared to conventionally fueled engines. However, there are challenges to using hydrogen in IC engines. In particular, efficient combustion of hydrogen in engines produces nitrogen oxides (NOx) that generally cannot be treated with conventional three-way catalysts. This work presents the results of experiments which consider changes in direct injection hydrogen engine design to improve engine performance, consisting primarily of engine efficiency and NOx emissions.

In order to understand better the operation of spark-ignition engines during the warm-up period, a computer model had been developed which simulates the thermal processes of the engine. This model is based on lumped thermal capacitance methods for the major engine components, as well as the exhaust system. Coolant and oil flows, and their respective heat transfer rates are modeled, as well as friction heat generation relations. Piston-liner heat transfer is calculated based on a thermal resistance method, which includes the effects of piston and ring material and design, oil film thickness, and piston-liner crevice. Piston/liner crevice changes are calculated based on thermal expansion rates and are used in conjunction with a crevice-region unburned hydrocarbon model to predict the contribution to emissions from this source.

Over the past several years a task group within the SAE Automotive Corrosion and Protection (ACAP) Committee has conducted extensive on-vehicle field testing and numerous accelerated lab tests with the goal of establishing a standard accelerated test method for cosmetic corrosion evaluations of finished aluminum auto body panels. This project has been a cooperative effort with OEM, supplier, and consultant participation and was also supported in part by DOE through USAMP (AMD 309). The focus of this project has been the identification of a standardized accelerated cosmetic corrosion test that exhibits the same appearance, severity, and type of corrosion products that are exhibited on identical painted aluminum panels exposed to service relevant environments. Multi-year service relevant exposures were conducted by mounting panels on-vehicles in multiple locations in the US and Canada.

This paper presents engine dynamometer testing and modeling analysis of ethanol compared to gasoline at part load conditions where the engine was not knock-limited with either fuel. The purpose of this work was to confirm the efficiency improvement for ethanol reported in published papers, and to quantify the components of the improvement. Testing comparing E85 to E0 gasoline was conducted in an alternating back-to-back manner with multiple data points for each fuel to establish high confidence in the measured results. Approximately 4% relative improvement in brake thermal efficiency (BTE) was measured at three speed-load points. Effects on BTE due to pumping work and emissions were quantified based on the measured engine data, and accounted for only a small portion of the difference.

Engine oils formulated using molybdenum dialkyldithiocarbamate, Mo(dtc)2, additives can provide substantial friction reduction under mixed to boundary lubrication conditions. It has been previously shown that the effectiveness of Mo(dtc)2 is significantly affected by the presence of other additives and by additive interaction and depletion processes occurring during use. In this study, ligand exchange reactions in an additive system containing Mo(dtc)2 and zinc dialkyldithiophosphate, Zn(dtp)2, have been investigated during oxidation in hexadecane and various base oils at 160°C. Samples of different composition obtained from these studies were used in investigations of the effects of original additives and ligand exchange products on friction reducing capability at 45 and 105°C.

Oscillating heat transfer is a fundamental phenomenon occurring in Stirling machines and IC engines. A group of relevant dimensionless numbers which characterize this problem is identified by dimensional analysis. The convective heat transfer coefficient, or Nusselt number, is a function of the Reynolds number, the Prandtl number, plus the dynamic Reynolds number and the dimensionless amplitude, when compressibility is not considered. The case for compressible fluid is more complicated. An experiential study confirms above analysis and results in a nonlinear longitudinal fluid temperature distribution in the pipe. The history effect is found to affect the heat transfer rate remarkably. A correlation equation for Nusselt number is obtained by multivariate analysis.

Fuel-air mixing in a direct-injection SI engine was studied to further improve full-load torque output. The fuel-injection location of DI vs. PFI results in different heat sources for fuel evaporation, hence a DI engine has been found to exhibit higher volumetric efficiency and lower knocking tendency, resulting in higher full-load torque output [1]. The ability to change injection timing of the DI engine affects heat transfer and mixture temperature, hence later injection results in lower knocking tendency. Both the higher volumetric efficiency and the lower knocking tendency can improve engine torque output. Improving volumetric efficiency requires that the fuel is injected during the intake stroke. Reducing knocking tendency, in contrast, requires that the fuel is injected late during the compression stroke. Thus, a strategy of split injection was proposed to compromise the two competing requirements and further increase direct-injection SI engine torque output.

A rapid compression machine for chemical kinetic studies has been developed. The design objectives of the machine were to obtain: 1)uniform well-defined core gas; 2) laminar flow condition; 3) maximum ratio of cooling to compression time; 4) side wall vortex containment; and, 5) minimum mechanical vibration. A piston crevice volume was incorporated to achieve the side wall vortex containment. Tests with inert gases showed the post-compression pressure matched with the calculated laminar pressure indicating that the machine achieved these design objectives. Measurements of ignition delays for homogeneous PRF/O2/N2/Ar mixture in the rapid compression machine have been made with five primary reference fuels (ON 100, 90, 75, 50, and 0) at an equivalence ratio of 1, a diluent (s)/oxygen ratio of 3.77, and two initial pressures of 500 Torr and 1000 Torr. Post-compression temperatures were varied by blending Ar and N2 in different ratios.

Since 2000, an Aluminum Cosmetic Corrosion task group within the SAE Automotive Corrosion and Protection (ACAP) Committee has existed. The task group has pursued the goal of establishing a standard test method for in-laboratory cosmetic corrosion evaluations of finished aluminum auto body panels. A cooperative program uniting OEM, supplier, and consultants has been created and has been supported in part by USAMP (AMD 309) and the U.S. Department of Energy. Prior to this committee's formation, numerous laboratory corrosion test environments have been used to evaluate the performance of painted aluminum closure panels. However, correlations between these laboratory test results and in-service performance have not been established. Thus, the primary objective of this task group's project was to identify an accelerated laboratory test method that correlates well with in-service performance.

An electrochemical testing protocol for assessing the intrinsic corrosion-resistance of creep-resistant magnesium alloys in aqueous environments, and effects of passivating surface films anticipated to develop in the presence of engine coolants is under development. This work reports progress in assessing the relative corrosion resistance of the base metals (AMC-SC1, MRI-202S, MRI-230D, AM50 and 99.98% Mg) in a common test environment, based on a near-neutral pH buffered saline solution, found to yield particularly stable values for the open-circuit or corrosion potential. This approach was found to provide a platform for the eventual assessment of the durability of certain passivating layers expected to develop during exposure of the magnesium alloys to aqueous coolants.

In recent years, rapid and significant advances in fuel cell technology, together with advances in power electronics and control methodology, has enabled the development of high performance fuel cell powered electric vehicles. A key advance is that the low temperature (80°C) proton-exchange-membrane (PEM) fuel cell has become mature and robust enough to be used for automotive applications. Apart from the apparent advantage of lower vehicle emission, the overall fuel cell vehicle static and dynamic performance and power and energy efficiency are critically dependent on the intelligent design of the control systems and control methodologies. These include the control of: fuel cell heat and water management, fuel (hydrogen) and air (oxygen) supply and distribution, electric drive, main and auxiliary power management, and overall powertrain and vehicle systems.

Measurements of particulate matter (PM) from spark ignition (SI) engine exhaust using dilution tunnels will become more prevalent as emission standards are tightened. Hence, a study of the dilution process was undertaken in order to understand how various dilution related parameters affect the accuracy with which PM sizes and concentrations can be determined. A SI and a compression ignition (CI) engine were separately used to examine parameters of the dilution process; the present work discusses the results in the context of SI exhaust dilution. A Scanning Mobility Particle Sizer (SMPS) was used to measure the size distribution, number density, and volume fraction of PM. Temperature measurements in the exhaust pipe and dilution tunnel reveal the degree of mixing between exhaust and dilution air, the effect of flowrate on heat transfer from undiluted and diluted exhaust to the environment, and the minimum permissible dilution ratio for a maximum sample temperature of 52°C.

A lean-rich hydrothermal aging was used to study the deactivation of Cu-zeolite SCR catalyst that has enhanced stability. Impact of DOC upstream on the SCR catalyst during the lean-rich aging was also investigated. The LR hydrothermal aging was conducted with the presence of hydrocarbon, CO and H₂ at different O₂ levels. It was found that the SCR catalyst was active for the oxidation of CO, H₂ and hydrocarbon, resulting in significant exotherm across the catalyst. In addition to hydrothermal aging, reductive aging, especially the presence of H₂ in the aging gas stream without O₂ presence during the L-R aging, might also contribute to the Cu/zeolite SCR catalyst deactivation. The impacts of DOC upstream on Cu/zeolite SCR catalysts depended on the aging temperatures. At lower aging temperature, the uncompleted oxidation of hydrocarbon and CO on the DOC might cause steam reforming and water-gas shift reactions on the DOC to form reductive gas stream.

This paper presents the progress of an ongoing vehicle micro corrosion environment study. The goal of the study is to develop an improved method for estimating vehicle corrosion based on the Total Vehicle Accelerated Corrosion Test at the Arizona Proving Ground (APG). Although the APG test greatly accelerates vehicle corrosion compared to the field, the “acceleration factor” varies considerably from site-to-site around the vehicle. This method accounts for the difference in corrosivity of various local corrosion environments from site-to-site at APG and in the field. Correlations of vehicle microenvironments with the macroenvironment (weather) and the occurrence of various environmental conditions at microenvironments are essential to the study. A comparison of results from APG versus field measurements generated using a cold rolled steel based corrosion sensor is presented.

A simulated diesel exhaust is treated with a nonthermal plasma discharge under steady state conditions. The plasma effluent is then passed through a sodium zeolite-Y (NaY) catalyst followed by a platinum oxidation catalyst. Detailed FTIR measurements of gas composition are taken before, between, and after the treatment stages. The plasma discharge causes oxidation of NO primarily to NO2, with methyl nitrate and nitric acid byproducts. At the same time, HC is partially oxidized, creating species such as formaldehyde, acetaldehyde, CO and other partial oxidation products. When this mixture passes over the NaY catalyst, part of the NOx is reduced to N2, with the remainder primarily in the form of NO. Methyl nitrate decomposes to form methanol and NOx, and nitric acid is consumed. There is little HC conversion on this catalyst. Small quantities of HCN and N2O are formed. When the mixture then passes over the platinum catalyst, further NOx conversion occurs.